JPH0365811B2 - - Google Patents
Info
- Publication number
- JPH0365811B2 JPH0365811B2 JP14061185A JP14061185A JPH0365811B2 JP H0365811 B2 JPH0365811 B2 JP H0365811B2 JP 14061185 A JP14061185 A JP 14061185A JP 14061185 A JP14061185 A JP 14061185A JP H0365811 B2 JPH0365811 B2 JP H0365811B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- epoxy resin
- manufactured
- weight
- prepreg
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003822 epoxy resin Substances 0.000 claims description 24
- 229920000647 polyepoxide Polymers 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 12
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 10
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 8
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 6
- AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical compound NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004918 carbon fiber reinforced polymer Substances 0.000 description 14
- 229920000049 Carbon (fiber) Polymers 0.000 description 12
- 239000004917 carbon fiber Substances 0.000 description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
- 238000005452 bending Methods 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920003319 Araldite® Polymers 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- 229920006231 aramid fiber Polymers 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- VAGOJLCWTUPBKD-UHFFFAOYSA-N 3-(oxiran-2-ylmethoxy)-n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1COC(C=1)=CC=CC=1N(CC1OC1)CC1CO1 VAGOJLCWTUPBKD-UHFFFAOYSA-N 0.000 description 1
- AHIPJALLQVEEQF-UHFFFAOYSA-N 4-(oxiran-2-ylmethoxy)-n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1COC(C=C1)=CC=C1N(CC1OC1)CC1CO1 AHIPJALLQVEEQF-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 etc. can be used Chemical class 0.000 description 1
- XXOYNJXVWVNOOJ-UHFFFAOYSA-N fenuron Chemical compound CN(C)C(=O)NC1=CC=CC=C1 XXOYNJXVWVNOOJ-UHFFFAOYSA-N 0.000 description 1
- 239000003733 fiber-reinforced composite Substances 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 239000011208 reinforced composite material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Description
【発明の詳細な説明】
産業上の利用分野
本発明は繊維強化複合材料（以下FRPと略記
する）、特に炭素繊維強化複合材料（以下CFRP
と略記する）のマトリツクス樹脂として有用なエ
ポキシ樹脂組成物に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to fiber reinforced composite materials (hereinafter abbreviated as FRP), particularly carbon fiber reinforced composite materials (hereinafter referred to as CFRP).
The present invention relates to an epoxy resin composition useful as a matrix resin.
従来の技術
近年、FRP、特にCFRPはスポーツ・レジヤー
用品や航空機の分野に広く使用されており、その
需要も年々増大している。Prior Art In recent years, FRP, especially CFRP, has been widely used in the fields of sports and leisure products and aircraft, and the demand for it is increasing year by year.
FRP，CFRPは一般に、ガラス繊維、アラミド
繊維、ボロン繊維、炭素繊維などの繊維基材にマ
トリツクス樹脂を含浸してプリプレグとなし、こ
れらを積層して適当な温度で硬化させることによ
り得られる。 FRP and CFRP are generally obtained by impregnating a fiber base material such as glass fiber, aramid fiber, boron fiber, or carbon fiber with a matrix resin to form a prepreg, which is then laminated and cured at an appropriate temperature.
CFRPのマトリツクス樹脂として炭素繊維に対
する接着性に優れるエポキシ樹脂が採用されてい
る。しかしながら従来より主に用いられているビ
スフエノールＡ型エポキシ樹脂は耐熱性に劣り、
さらにコンポジツト物性、特に層間せん断強度
（以下ILSSと略記する）が低いという欠点を有し
ている。一方、多管能のエポキシ樹脂を用いるこ
とによりこれらの欠点を改良することが提案され
ているが、反面マトリツクス樹脂の伸びが減少
し、そのため耐熱衝撃性の低下が起こるという問
題点を有している。 Epoxy resin, which has excellent adhesion to carbon fibers, is used as the matrix resin for CFRP. However, the bisphenol A type epoxy resin that has been mainly used has poor heat resistance.
Furthermore, it has the disadvantage of low composite physical properties, particularly interlaminar shear strength (hereinafter abbreviated as ILSS). On the other hand, it has been proposed to improve these drawbacks by using a multi-tubular epoxy resin, but on the other hand, it has the problem that the elongation of the matrix resin decreases, resulting in a decrease in thermal shock resistance. There is.
発明が解決しようとする問題点
本発明はこれらの欠点を解決するとともに、繊
維基材、特に炭素繊維に対する含浸性が良好で、
かつプリプレグとした場合に適度なドレープ性、
タツクネスを有するエポキシ樹脂組成物を提供す
るものである。Problems to be Solved by the Invention The present invention solves these drawbacks, and also has good impregnation properties for fiber base materials, especially carbon fibers, and
And when used as prepreg, it has moderate drape properties.
The present invention provides an epoxy resin composition having toughness.
問題点を解決するための手段
本発明は、(A)ビスフエノールＦ型エポキシ樹脂
５〜30重量部、(B)ビスフエノールＡ型エポキシ樹
脂20〜80重量部、(C)グリシジルアミン型エポキシ
樹脂15〜50重量部、および(D)ジシアンジアミドお
よび硬化促進剤よりなるエポキシ樹脂組成物に関
する。Means for Solving the Problems The present invention provides (A) 5 to 30 parts by weight of a bisphenol F type epoxy resin, (B) 20 to 80 parts by weight of a bisphenol A type epoxy resin, and (C) a glycidylamine type epoxy resin. 15 to 50 parts by weight, and an epoxy resin composition comprising (D) dicyandiamide and a curing accelerator.
本発明で用いられる(A)ビスフエノールＦ型エポ
キシ樹脂の例としては、具体的にはエピコート
807（油化シエルエポキシ社製）、YDF170（東都化
成社製）、エピクロン830（大日本インキ化学工業
社製）などが挙げられる。 As an example of (A) bisphenol F type epoxy resin used in the present invention, specifically, Epicoat
Examples include 807 (manufactured by Yuka Ciel Epoxy Co., Ltd.), YDF170 (manufactured by Toto Kasei Co., Ltd.), and Epicron 830 (manufactured by Dainippon Ink Chemical Industries, Ltd.).
(B)ビスフエノールＡ型エポキシ樹脂の例として
は、具体的にはエピコート828、エピコート834、
エピコート827、エピコート1001、エピコート
1002、エピコート1004、エピコート1007、エピコ
ート1009（油化シエルエポキシ社製）、アラルダイ
トCY205、CY230、CY232、CY221、GY257、
GY252、GY255、GY250、GY260、GY280、ア
ラルダイト6071、アラルダイト7071、アラルダイ
ト7072（チバ・ガイギー社製）、ダウエポキシ
DER331、DER332、DER662、DER663U、
DER662U（ダウケミカル社製）、エピクロン840、
850、855、860、1050、3050、4050、7050（大日本
インキ化学工業社製）、エポトートYD−115、
YD115−CA、YD−117、YD−121、YD−127、
YD−128、YD−128CA、YD−128S、YD−134、
YD−001Z、YD−011、YD−012、YD−014、
YD−014ES、YD−017、YD−019、YD−020、
YD−002（東都化成社製）等が挙げられる。 (B) Examples of bisphenol A type epoxy resins include Epicote 828, Epicote 834,
Epicote 827, Epicote 1001, Epicote
1002, Epicote 1004, Epicote 1007, Epicote 1009 (manufactured by Yuka Ciel Epoxy Co., Ltd.), Araldite CY205, CY230, CY232, CY221, GY257,
GY252, GY255, GY250, GY260, GY280, Araldite 6071, Araldite 7071, Araldite 7072 (manufactured by Ciba Geigy), Dowepoxy
DER331, DER332, DER662, DER663U,
DER662U (manufactured by Dow Chemical), Epicron 840,
850, 855, 860, 1050, 3050, 4050, 7050 (manufactured by Dainippon Ink and Chemicals), Epotote YD-115,
YD115−CA, YD−117, YD−121, YD−127,
YD-128, YD-128CA, YD-128S, YD-134,
YD−001Z, YD−011, YD−012, YD−014,
YD−014ES, YD−017, YD−019, YD−020,
Examples include YD-002 (manufactured by Toto Kasei Co., Ltd.).
これらビスフエノールＡ型エポキシ樹脂として
は、液状のもの（例えばエピコート828，YD−
128）と固形状のものがあるが、本発明において
は液状のものと固形状のものをそれぞれ10〜
90wt％の範囲内で混合することにより粘度を調
節することが好ましく行われる。 These bisphenol A type epoxy resins include liquid ones (e.g. Epicote 828, YD-
There are 128) and solid forms, but in the present invention, liquid and solid forms are each
The viscosity is preferably controlled by mixing within a range of 90 wt%.
(C)グリシジルアミン型エポキシ樹脂としては、
Ｎ，Ｎ，Ｏ−トリグリシジル−ｍ−アミノフエノ
ール、Ｎ，Ｎ，Ｏ−トリグリシジル−ｐ−アミノ
フエノール等の３管能のもの、Ｎ，Ｎ，N′，N′，
−テトラグリシジルジアミノジフエニルメタン、
Ｎ，Ｎ，N′，N′，−テトラグリシジル−ｍ−キシ
リレンジアミン等の４管能のものが用いられる
が、４管能のものが好ましい。特にＮ，Ｎ，N′，
N′，−テトラグリシジルジアミノジフエニルメタ
ンが本発明において好ましく使用される。 (C) As glycidylamine type epoxy resin,
N,N,O-triglycidyl-m-aminophenol, N,N,O-triglycidyl-p-aminophenol, etc., N,N,N',N',
-tetraglycidyldiaminodiphenylmethane,
A 4-tube compound such as N,N,N',N'-tetraglycidyl-m-xylylene diamine is used, and a 4-tube compound is preferred. Especially N, N, N′,
N',-tetraglycidyldiaminodiphenylmethane is preferably used in the present invention.
Ｎ，Ｎ，N′，N′，−テトラグリシジルジアミノ
ジフエニルメタンとしては、具体的にはMY720
（チバ・ガイギー社製）、YH−434（東都化成社
製）、ELM−434（住友化学工業社製）、エピクロ
ン430（大日本インキ化学工業社製）、Ｅ−604（油
化シエルエポキシ社製）等が挙げられる。 Specifically, the N,N,N′,N′,-tetraglycidyldiaminodiphenylmethane is MY720
(manufactured by Ciba Geigy), YH-434 (manufactured by Toto Kasei), ELM-434 (manufactured by Sumitomo Chemical), Epicron 430 (manufactured by Dainippon Ink and Chemicals), E-604 (manufactured by Yuka Ciel Epoxy) (manufactured by), etc.
本発明において成分(D)としてジシアンジアミド
および硬化促進剤が用いられる。硬化促進剤とし
てはウレア化合物、イミダゾール類などが使用す
ることができ、特に下記一般式で示されるウレア
化合物が好ましく使用される。 In the present invention, dicyandiamide and a curing accelerator are used as component (D). As the curing accelerator, urea compounds, imidazoles, etc. can be used, and urea compounds represented by the following general formula are particularly preferably used.
（式中、X1およびX2はそれぞれＨ，Cl，NO2，
OCH3のいずれかの基を示す）
これらの化合物の例としては、３−（３，４−
ジクロロフエニル）−１，１−ジメチルウレア、
３−フエニル−１，１−ジメチルウレア等が挙げ
られる。 (In the formula, X 1 and X 2 are H, Cl, NO 2 ,
Examples of these compounds include 3- (3,4-
dichlorophenyl)-1,1-dimethylurea,
Examples include 3-phenyl-1,1-dimethylurea.
本発明は前記成分(A)〜(C)を、(A)５〜30重量部、
好ましくは５〜15重量部、(B)20〜80重量部、好ま
しくは40〜60重量部および(C)15〜50重量部、好ま
しくは20〜40重量部の割合で配合するのが望まし
い。 The present invention comprises the components (A) to (C), (A) 5 to 30 parts by weight,
Preferably, the proportions are 5 to 15 parts by weight, (B) 20 to 80 parts by weight, preferably 40 to 60 parts by weight, and (C) 15 to 50 parts by weight, preferably 20 to 40 parts by weight.
ジシアンジアミドの使用量は、成分(A)〜(C)の合
計量100重量部に対して、通常３〜７重量部用い
られる。また硬化促進剤の使用量は、成分(A)〜(C)
の合計量100重量部に対し、通常３〜７重量部用
いられる。 The amount of dicyandiamide used is usually 3 to 7 parts by weight per 100 parts by weight of the total amount of components (A) to (C). In addition, the amount of curing accelerator used is as follows: Components (A) to (C)
It is usually used in an amount of 3 to 7 parts by weight per 100 parts by weight of the total amount.
本発明においては成分(A)〜(C)を所定の割合にて
配合することが本発明の目的を達成するために極
めて重要である。すなわち、成分(A)〜(C)を本発明
の所定の割合に配合することにより、繊維基材に
対する含浸性がきわめて良好となり、プリプレグ
とした場合に適度なタツクネスとドレープ性を有
し、そしてFRPあるいはCFRPとした場合の物
性、特にILSSの高いものが得られる。本発明の
所定の割合からはずれた場合にはこれらの優れた
効果が期待できない。 In the present invention, it is extremely important to mix components (A) to (C) in a predetermined ratio in order to achieve the object of the present invention. That is, by blending components (A) to (C) in the predetermined proportions of the present invention, the impregnating property to the fiber base material is extremely good, and when it is made into a prepreg, it has appropriate tackiness and drapability, and When used as FRP or CFRP, high physical properties, especially ILSS, can be obtained. If the ratio is deviated from the predetermined ratio of the present invention, these excellent effects cannot be expected.
本発明のエポキシ樹脂組成物は炭素繊維プリプ
レグ用マトリツクス樹脂として好適に用いられる
ばかりでなく、アラミド繊維、ガラス繊維、ボロ
ン繊維などの各種繊維のFRP用マトリツクス樹
脂としても用いられる。 The epoxy resin composition of the present invention is not only suitably used as a matrix resin for carbon fiber prepregs, but also as a matrix resin for FRP of various fibers such as aramid fibers, glass fibers, and boron fibers.
実施例
以下に実施例を挙げ本発明を説明するが、本発
明はこれらに制限されるものではない。なお実施
例中の“部”は“重量部”を意味する。Examples The present invention will be explained below with reference to Examples, but the present invention is not limited thereto. Note that "parts" in the examples mean "parts by weight."
実施例 １
YDF−170（東都化成社製）80部、YD−128（東
都化成社製）300部、エピコート1009（油化シエル
エポキシ社製）300部、YH−434（（東都化成社
製）320部を加熱ニーダーに入れて、撹拌混合し
たのち、ジシアンジアミド40部および３−（３，
４−ジクロロフエニル）−１，１−ジメチルウレ
ア（以下DCMUと略記する）30部を添加して、
十分に撹拌混合を行い、プリプレグ用エポキシ樹
脂組成物を得た。Example 1 80 parts of YDF-170 (manufactured by Toto Kasei Co., Ltd.), 300 parts of YD-128 (manufactured by Toto Kasei Co., Ltd.), 300 parts of Epicote 1009 (manufactured by Yuka Ciel Epoxy Co., Ltd.), YH-434 (manufactured by Toto Kasei Co., Ltd.) After putting 320 parts into a heating kneader and stirring and mixing, add 40 parts of dicyandiamide and 3-(3,
Adding 30 parts of 4-dichlorophenyl)-1,1-dimethylurea (hereinafter abbreviated as DCMU),
The mixture was thoroughly stirred and mixed to obtain an epoxy resin composition for prepreg.
次に市販の高強度炭素繊維（引張強さ310Kg／
mm2，弾性率23t／mm2）を一方向に引き揃えたのち
このプリプレグ用エポキシ樹脂組成物を加熱溶融
して含浸させて一方向プリプレグを得た。得られ
たプリプレグは適度なタツクネスとドレープ性を
有しており、20℃で1.5ケ月保管した後のプリプ
レグのタツクネスとドレープ性に変化はなく良好
な貯蔵安定性を有していた。 Next, commercially available high-strength carbon fiber (tensile strength 310Kg/
mm 2 and elastic modulus of 23 t/mm 2 ) in one direction, the epoxy resin composition for prepreg was heated and melted to impregnate the prepreg to obtain a unidirectional prepreg. The obtained prepreg had appropriate toughness and drapeability, and had good storage stability with no change in the toughness and drapability of the prepreg after being stored at 20°C for 1.5 months.
このプリプレグを長さ30cm、巾15cmに裁断した
ものを繊維方向が同一方向になるように積層し、
テドラーフイルムで包み、120℃に加熱されたプ
レスに入れて７Kg／cm2に加圧して60分間硬化させ
た。ついで130℃のオーブン中に入れ２時間のア
フターキユアを行い、完全硬化させて厚み２mmの
CFRP板を得た。 This prepreg is cut into pieces of 30cm long and 15cm wide, and then stacked so that the fibers are in the same direction.
It was wrapped in Tedlar film, placed in a press heated to 120°C, and cured for 60 minutes under pressure of 7 kg/cm 2 . Then, put it in an oven at 130℃ for 2 hours after-cure to completely cure it and make it 2mm thick.
A CFRP board was obtained.
得られたCFRP板の炭素繊維の体積含有率は60
％であつた。このCFRP板の曲げ強度および
ILSSをASTM Ｄ−790およびASTM Ｄ−2344
に準じて測定した。得られた結果は曲げ強さ176
Kg／mm2、曲げ弾性率12.3t／mm2、ILSS10.4Kg／mm2
で優秀な物性を有していた。 The volume content of carbon fiber in the obtained CFRP board is 60
It was %. The bending strength of this CFRP plate and
ILSS to ASTM D-790 and ASTM D-2344
Measured according to. The result obtained is a bending strength of 176
Kg/mm 2 , flexural modulus 12.3t/mm 2 , ILSS 10.4Kg/mm 2
It had excellent physical properties.
実施例 ２
YDF−170、YD128、エピコート1002（油化シ
エルエポキシ社製）、YH−434をそれぞれ100部、
300部、400部および200部の割合にて加熱ニーダ
ーに入れ撹拌混合したのち、さらにジシアンジア
ミド50部およびDCMU40部を添加して十分に撹
拌混合を行い、エポキシ樹脂組成物を得た。Example 2 100 parts each of YDF-170, YD128, Epicote 1002 (manufactured by Yuka Ciel Epoxy Co., Ltd.) and YH-434,
After stirring and mixing in a heating kneader at a ratio of 300 parts, 400 parts, and 200 parts, 50 parts of dicyandiamide and 40 parts of DCMU were further added and thoroughly stirred and mixed to obtain an epoxy resin composition.
このエポキシ樹脂組成物を実施例１で用いた炭
素繊維に実施例１と同様の方法で含浸させ一方向
プリプレグを得た。得られたプリプレグは適度な
タツクネトとドレープ性を有しておりまた貯蔵安
定性も満足のいくものであつた。 The carbon fiber used in Example 1 was impregnated with this epoxy resin composition in the same manner as in Example 1 to obtain a unidirectional prepreg. The obtained prepreg had appropriate tackiness and drapability, and also had satisfactory storage stability.
このプリプレグを実施例１と同様の方法にて積
層硬化させてCFRP板を得た。このCFRP板の曲
げ強さは170Kg／mm2、曲げ弾性率12.3t／mm2、
ILSS9.8Kg／mm2であつた。このときの炭素繊維の
体積含有率は60％であつた。 This prepreg was laminated and cured in the same manner as in Example 1 to obtain a CFRP board. The bending strength of this CFRP plate is 170Kg/mm 2 , the bending elastic modulus is 12.3t/mm 2 ,
ILSS was 9.8Kg/ mm2 . The volume content of carbon fiber at this time was 60%.
実施例 ３
YDF−170、YD128、エピコート1001（油化シ
エルエポキシ社製）、YH−434をそれぞれ100部、
100部、400部および400部の割合にて加熱ニーダ
ーに入れ撹拌混合したのち、さらにジシアンジア
ミド50部およびDCMU50部を添加して十分に撹
拌混合を行い、エポキシ樹脂組成物を得た。Example 3 100 parts each of YDF-170, YD128, Epicote 1001 (manufactured by Yuka Ciel Epoxy Co., Ltd.), YH-434,
After stirring and mixing in a heating kneader at a ratio of 100 parts, 400 parts, and 400 parts, 50 parts of dicyandiamide and 50 parts of DCMU were further added and thoroughly stirred and mixed to obtain an epoxy resin composition.
このエポキシ樹脂組成物を実施例１で用いた炭
素繊維に実施例１と同様の方法で含浸させ一方向
プリプレグを得た。得られたプリプレグは適度な
タツクネトとドレープ性を有しておりまた貯蔵安
定性も満足のいくものであつた。 The carbon fiber used in Example 1 was impregnated with this epoxy resin composition in the same manner as in Example 1 to obtain a unidirectional prepreg. The obtained prepreg had appropriate tackiness and drapability, and also had satisfactory storage stability.
このプリプレグを実施例１と同様の方法にて積
層硬化させてCFRP板を作製した。このCFRP板
の曲げ強さは182Kg／mm2、曲げ弾性率12.3t／mm2、
ILSS10.6Kg／mm2であつた。このときの炭素繊維
の体積含有率は60％であつた。 This prepreg was laminated and cured in the same manner as in Example 1 to produce a CFRP board. The bending strength of this CFRP plate is 182Kg/mm 2 , the bending elastic modulus is 12.3t/mm 2 ,
ILSS was 10.6Kg/ mm2 . The volume content of carbon fiber at this time was 60%.
比較例 １
YDF−170、YD−128、エピコート1009、YH
−434、ジシアンジアミド、およびDCMUをそれ
ぞれ200部、200部、500部、100部、40部および30
部の割合にて用いた以外は、実施例１と同様の方
法にてCFRP板を作製した。Comparative example 1 YDF-170, YD-128, Epicote 1009, YH
−434, dicyandiamide, and DCMU at 200, 200, 500, 100, 40, and 30 parts, respectively.
A CFRP board was produced in the same manner as in Example 1, except that the same proportions were used as in Example 1.
このCFRP板の曲げ強さは165Kg／mm2、曲げ弾
性率12.3t／mm2、ILSS9.0Kg／mm2であつた。このと
きの炭素繊維の体積含有率は60％であつた。 The bending strength of this CFRP plate was 165 Kg/mm 2 , the bending modulus was 12.3 t/mm 2 , and the ILSS was 9.0 Kg/mm 2 . The volume content of carbon fiber at this time was 60%.
Claims (1)
５〜30重量部 (B) ビスフエノールＡ型エポキシ樹脂
20〜80重量部 (C) グリシジルアミン型エポキシ樹脂
15〜50重量部 および (D) ジシアンジアミドおよび硬化促進剤 よりなるエポキシ樹脂組成物。[Claims] 1 (A) Bisphenol F type epoxy resin
5-30 parts by weight (B) Bisphenol A type epoxy resin
20-80 parts by weight (C) Glycidylamine type epoxy resin
15 to 50 parts by weight, and (D) an epoxy resin composition comprising dicyandiamide and a curing accelerator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14061185A JPS621717A (en) | 1985-06-28 | 1985-06-28 | Epoxy resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14061185A JPS621717A (en) | 1985-06-28 | 1985-06-28 | Epoxy resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS621717A JPS621717A (en) | 1987-01-07 |
| JPH0365811B2 true JPH0365811B2 (en) | 1991-10-15 |
Family
ID=15272732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14061185A Granted JPS621717A (en) | 1985-06-28 | 1985-06-28 | Epoxy resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS621717A (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3689783T2 (en) * | 1985-09-27 | 1994-08-25 | Sumitomo Chemical Co | Low viscosity epoxy resin, this resin-containing composition and fiber-containing composite based on this hardened composition. |
| JPH0751616B2 (en) * | 1987-06-05 | 1995-06-05 | 三菱レイヨン株式会社 | Epoxy resin composition |
| JPH0751615B2 (en) * | 1987-06-05 | 1995-06-05 | 三菱レイヨン株式会社 | Epoxy resin composition |
| US8278389B2 (en) | 2007-05-16 | 2012-10-02 | Toray Industries, Ltd. | Epoxy resin composition, prepreg, fiber-reinforced composite material |
| TWI435887B (en) | 2008-02-26 | 2014-05-01 | Toray Industries | Epoxy resin composition, prepreg and fiber-reinforced composite material |
| WO2012039456A1 (en) | 2010-09-24 | 2012-03-29 | 東レ株式会社 | Epoxy resin composition for fiber-reinforced composite material, prepreg, and fiber-reinforced composite material |
| JP5747762B2 (en) * | 2010-09-28 | 2015-07-15 | 東レ株式会社 | Epoxy resin composition, prepreg and fiber reinforced composite material |
| RU2013119741A (en) * | 2010-09-28 | 2014-11-10 | Торэй Индастриз, Инк. | COMPOSITION OF EPOXY RESIN, PREGREG AND FIBER REINFORCED COMPOSITE MATERIALS |
| JP5747763B2 (en) * | 2010-09-28 | 2015-07-15 | 東レ株式会社 | Epoxy resin composition, prepreg and fiber reinforced composite material |
| US9765194B2 (en) | 2012-07-25 | 2017-09-19 | Toray Industries, Inc. | Prepreg and carbon fiber-reinforced composite material |
-
1985
- 1985-06-28 JP JP14061185A patent/JPS621717A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS621717A (en) | 1987-01-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6771883B2 (en) | Epoxy resin compositions, prepregs and fiber reinforced composites | |
| KR0166977B1 (en) | Epoxy resin composition for fiber reinforced plastic | |
| JP6771885B2 (en) | Epoxy resin compositions, prepregs and fiber reinforced composites | |
| JPH0365811B2 (en) | ||
| JPH0365812B2 (en) | ||
| US4550129A (en) | Toughening reinforced epoxy composites with brominated polymeric additives | |
| JPH11171974A (en) | Epoxy resin composition for fiber-reinforced composite material, prepreg and fiber-reinforced composite material | |
| JPH0365813B2 (en) | ||
| JPH0365814B2 (en) | ||
| JP2604778B2 (en) | Matrix resin composition | |
| JPS6236421A (en) | Epoxy resin composition for prepreg | |
| JP2003002953A (en) | Epoxy resin composition and fiber-reinforced resin composite material | |
| JPS6143616A (en) | Epoxy resin composition | |
| JPS6338049B2 (en) | ||
| US4588778A (en) | Toughening reinforced epoxy composites with brominated polymeric additives | |
| JPH11279261A (en) | Heat-resistant epoxy resin composition for fiber-reinforced composite material | |
| JPH07228716A (en) | Prepreg | |
| JPS6017288B2 (en) | Heat-resistant epoxy resin composition | |
| JPS624405B2 (en) | ||
| JPS59174616A (en) | Epoxy resin composition and prepreg | |
| JPS621718A (en) | Epoxy resin composition | |
| JPS6313444B2 (en) | ||
| JPH03227316A (en) | Heat-resistant epoxy resin composition | |
| JPS60202116A (en) | Epoxy resin composition | |
| JPS6338048B2 (en) |