RU95106775A - Каталитическая композиция для карбонилирования - Google Patents
Каталитическая композиция для карбонилированияInfo
- Publication number
- RU95106775A RU95106775A RU95106775/04A RU95106775A RU95106775A RU 95106775 A RU95106775 A RU 95106775A RU 95106775/04 A RU95106775/04 A RU 95106775/04A RU 95106775 A RU95106775 A RU 95106775A RU 95106775 A RU95106775 A RU 95106775A
- Authority
- RU
- Russia
- Prior art keywords
- catalytic composition
- composition according
- catalytic
- polymer
- iodide
- Prior art date
Links
- 230000003197 catalytic Effects 0.000 title claims 12
- 229920000642 polymer Polymers 0.000 claims 5
- HSZCZNFXUDYRKD-UHFFFAOYSA-M Lithium iodide Chemical group [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N 2-Pyrrolidone Chemical group O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N Methyl iodide Chemical group IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 claims 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinylpyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims 1
- 150000001351 alkyl iodides Chemical class 0.000 claims 1
- 238000005810 carbonylation reaction Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
Claims (8)
1. Каталитическая композиция для карбонилирования, отличающаяся тем, что содержит полимер, имеющий боковые пирролидоновые группы, и является подложкой для частиц родия, и каталитический промотор, содержащий алкилиодид.
2. Каталитическая композиция по п.1, отличающаяся тем, что полимер является твердым.
3. Каталитическая композиция по п.1, отличающаяся тем, что полимер является производным винилпирролидона.
4. Каталитическая композиция по п.2, отличающаяся тем, что полимером является сшитый поливинилпирролидон.
5. Каталитическая композиция по п.1, отличающаяся тем, что полимер является жидким.
6. Каталитическая композиция по п.1, отличающаяся тем, что каталитическим промотором является метилиодид.
7. Каталитическая композиция по п.1, отличающаяся тем, что дополнительно включает иодидную соль, отличную от указанного каталитического промотора.
8. Каталитическая композиция по п.7, отличающаяся тем, что иодидной солью является литийиодид.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/938,787 US5281359A (en) | 1992-08-31 | 1992-08-31 | Polymeric carbonylation catalyst system |
| US07/938,787 | 1992-08-31 | ||
| US07/938787 | 1992-08-31 | ||
| PCT/US1993/007989 WO1994005423A1 (en) | 1992-08-31 | 1993-08-25 | Polymeric carbonylation catalyst system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU95106775A true RU95106775A (ru) | 1997-08-10 |
| RU2103064C1 RU2103064C1 (ru) | 1998-01-27 |
Family
ID=25471957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU95106775A RU2103064C1 (ru) | 1992-08-31 | 1993-08-25 | Каталитическая композиция для карбонилирования |
Country Status (20)
| Country | Link |
|---|---|
| US (2) | US5281359A (ru) |
| EP (1) | EP0656811B1 (ru) |
| JP (1) | JP3320728B2 (ru) |
| KR (1) | KR100278950B1 (ru) |
| CN (1) | CN1044572C (ru) |
| AU (1) | AU663666B2 (ru) |
| BR (1) | BR9306934A (ru) |
| CA (1) | CA2141944C (ru) |
| DE (1) | DE69301828T2 (ru) |
| ES (1) | ES2085170T3 (ru) |
| MX (1) | MX9305274A (ru) |
| MY (1) | MY109437A (ru) |
| NO (1) | NO306660B1 (ru) |
| RU (1) | RU2103064C1 (ru) |
| SA (1) | SA93140194B1 (ru) |
| SG (1) | SG48904A1 (ru) |
| TR (1) | TR27222A (ru) |
| TW (1) | TW429162B (ru) |
| WO (1) | WO1994005423A1 (ru) |
| ZA (1) | ZA936316B (ru) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5892110A (en) * | 1996-05-21 | 1999-04-06 | Air Products And Chemicals, Inc. | Heterogeneous catalyst for the production of acetic anhydride from methyl acetate |
| GB9712601D0 (en) | 1997-06-16 | 1997-08-20 | Bp Chem Int Ltd | Chemical process |
| GB9712596D0 (en) * | 1997-06-16 | 1997-08-20 | Bp Chem Int Ltd | Chemical process |
| US6153792A (en) * | 1997-12-18 | 2000-11-28 | Uop Llc | Carbonylation process using a flash step with washing |
| DE10003317A1 (de) * | 2000-01-27 | 2001-08-02 | Degussa | Verfahren zur Durchführung homogen katalysierter Umsetzungen |
| US6458995B1 (en) | 2000-03-31 | 2002-10-01 | Celanese International Corporation | Catalytic composition for carbonylation including iridium and pyridine polymers |
| US6420304B1 (en) * | 2000-04-20 | 2002-07-16 | China Petrochemical Development Corporation | Polymer-supported carbonylation catalyst and its use |
| US6627770B1 (en) * | 2000-08-24 | 2003-09-30 | Celanese International Corporation | Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process |
| US6657078B2 (en) | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
| JP4326838B2 (ja) * | 2003-05-29 | 2009-09-09 | 独立行政法人産業技術総合研究所 | ポリカーボネート製造用触媒及びポリカーボネートの製造方法 |
| WO2004106406A1 (ja) * | 2003-05-29 | 2004-12-09 | National Institute Of Advanced Industrial Science And Technology | ポリカーボネート製造用触媒及びポリカーボネートの製造方法 |
| CN100361746C (zh) * | 2005-06-24 | 2008-01-16 | 上海焦化有限公司 | 噻唑磺酸盐助催化的羰基合成均相铑催化剂及其应用 |
| US7902398B2 (en) | 2007-04-25 | 2011-03-08 | Celanese International Corporation | Method and apparatus for carbonylation with reduced catalyst loss |
| KR101584387B1 (ko) * | 2008-04-29 | 2016-01-13 | 셀라니즈 인터내셔날 코포레이션 | 다수의 용매 옵션을 가진 흡수 장치를 갖는 메탄올 카보닐화 시스템 |
| US7884237B2 (en) * | 2008-11-07 | 2011-02-08 | Celanese International Corp. | Methanol carbonylation with improved aldehyde removal |
| DE102010040921A1 (de) | 2010-09-16 | 2012-03-22 | Basf Se | Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure |
| US8653303B2 (en) * | 2012-01-26 | 2014-02-18 | Celanese International Corporation | Processes for preparing acetic anhydride |
| US20140121403A1 (en) | 2012-10-31 | 2014-05-01 | Celanese International Corporation | Integrated Process for the Production of Acrylic Acids and Acrylates |
| US9120743B2 (en) | 2013-06-27 | 2015-09-01 | Celanese International Corporation | Integrated process for the production of acrylic acids and acrylates |
| CN105268486B (zh) * | 2014-07-11 | 2017-11-21 | 中国石油化工股份有限公司 | 双醋酸亚乙酯催化剂及其应用 |
| RS59574B1 (sr) | 2014-10-02 | 2019-12-31 | Celanese Int Corp | Proces za proizvodnju sirćetne kiseline |
| KR101667222B1 (ko) * | 2014-12-29 | 2016-10-18 | 한국화학연구원 | 카보닐화 반응에 의한 초산 제조용 Rh-C3N4 불균일 촉매 |
| KR101667223B1 (ko) * | 2014-12-29 | 2016-10-18 | 한국화학연구원 | 카보닐화 반응에 의한 초산 제조용 Ｒｈ/ＷｘＣ 불균일 촉매 |
| US9487464B2 (en) | 2015-01-30 | 2016-11-08 | Celanese International Corporation | Processes for producing acetic acid |
| MX2017009867A (es) | 2015-01-30 | 2017-11-15 | Celanese Int Corp | Procedimientos para producir acido acetico. |
| US9561994B2 (en) | 2015-01-30 | 2017-02-07 | Celanese International Corporation | Processes for producing acetic acid |
| US9505696B2 (en) | 2015-02-04 | 2016-11-29 | Celanese International Corporation | Process to control HI concentration in residuum stream |
| CN109453815B (zh) * | 2017-09-06 | 2021-09-07 | 中国科学院大连化学物理研究所 | 有机含膦聚合物载体负载的铑基催化剂及其制备和应用 |
| CN111116436B (zh) * | 2020-01-17 | 2021-07-13 | 信阳师范学院 | 一种含1,4-萘醌结构的硫醚类化合物的合成方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3855307A (en) * | 1967-02-20 | 1974-12-17 | Monsanto Co | Catalysis |
| US3769329A (en) * | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
| US4066705A (en) * | 1975-10-22 | 1978-01-03 | Celanese Corporation | Polybenzimidazole fiber supported catalyst |
| US4183872A (en) * | 1978-02-13 | 1980-01-15 | Conoco, Inc. | Polymer bound (pentahaptocyclopentadienyl)biscarbonyl rhodium hydroformylation catalyst |
| US4183825A (en) * | 1978-07-14 | 1980-01-15 | Conoco, Inc. | Method for the activation of polymer-bound bis(triphenylphosphine)rhodium carbonyl halide hydroformylation catalysts |
| DE2966350D1 (en) * | 1978-08-17 | 1983-12-01 | Heyl Chem Pharm | Polymeric hydrogenation catalysts, process for preparing these catalysts and their use for catalytic hydrogenations |
| US4301090A (en) * | 1978-10-30 | 1981-11-17 | Standard Oil Company | Carbonylation of olefinically unsaturated compounds |
| SU1108088A1 (ru) * | 1982-12-07 | 1984-08-15 | Ордена Ленина Институт Химической Физики Ан Ссср | Способ получени уксусной кислоты |
| US5001259A (en) * | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
| CA1228867A (en) * | 1984-05-03 | 1987-11-03 | G. Paull Torrence | Methanol carbonylation process |
| US5026908A (en) * | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US4667053A (en) * | 1986-06-30 | 1987-05-19 | Texaco Inc. | Process for oxidative carbonylation using a catalyst having a novel support |
| US5155261A (en) * | 1987-02-05 | 1992-10-13 | Reilly Industries, Inc. | Process for acetic acid preparation and heterogenous catalyst for same |
| DE3889233T2 (de) * | 1987-02-05 | 1994-08-11 | Reilly Ind Inc | Verfahren zur Herstellung von Essigsäure und heterogener Katalysator dafür. |
| DE3727704A1 (de) * | 1987-08-19 | 1989-03-02 | Heyl Chem Pharm | Verwendung polymerer loeslicher hydrierkatalysatoren zur positionsselektiven hydrierung von fetten und oelen |
| US5250489A (en) * | 1990-11-26 | 1993-10-05 | Catalytica, Inc. | Catalyst structure having integral heat exchange |
| US5259754A (en) * | 1990-11-26 | 1993-11-09 | Catalytica, Inc. | Partial combustion catalyst of palladium on a zirconia support and a process for using it |
| US5258349A (en) * | 1990-11-26 | 1993-11-02 | Catalytica, Inc. | Graded palladium-containing partial combustion catalyst |
| US5131943A (en) * | 1990-12-11 | 1992-07-21 | Conoco Inc. | Process for the separation of precious group VIII a metals from cyano complexes of such metals and other metals |
| US5334755A (en) * | 1992-04-24 | 1994-08-02 | Chiyoda Corporation | Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst |
-
1992
- 1992-08-31 US US07/938,787 patent/US5281359A/en not_active Expired - Lifetime
-
1993
- 1993-08-10 TW TW082106411A patent/TW429162B/zh not_active IP Right Cessation
- 1993-08-24 US US08/110,999 patent/US5466874A/en not_active Expired - Lifetime
- 1993-08-25 WO PCT/US1993/007989 patent/WO1994005423A1/en active IP Right Grant
- 1993-08-25 DE DE69301828T patent/DE69301828T2/de not_active Expired - Lifetime
- 1993-08-25 BR BR9306934A patent/BR9306934A/pt not_active IP Right Cessation
- 1993-08-25 AU AU50910/93A patent/AU663666B2/en not_active Ceased
- 1993-08-25 ES ES93920330T patent/ES2085170T3/es not_active Expired - Lifetime
- 1993-08-25 RU RU95106775A patent/RU2103064C1/ru not_active IP Right Cessation
- 1993-08-25 EP EP93920330A patent/EP0656811B1/en not_active Expired - Lifetime
- 1993-08-25 TR TR00709/93A patent/TR27222A/xx unknown
- 1993-08-25 JP JP50728194A patent/JP3320728B2/ja not_active Expired - Fee Related
- 1993-08-25 SG SG1996003600A patent/SG48904A1/en unknown
- 1993-08-25 KR KR1019950700841A patent/KR100278950B1/ko not_active IP Right Cessation
- 1993-08-25 CA CA002141944A patent/CA2141944C/en not_active Expired - Fee Related
- 1993-08-27 MY MYPI93001743A patent/MY109437A/en unknown
- 1993-08-27 ZA ZA936316A patent/ZA936316B/xx unknown
- 1993-08-30 MX MX9305274A patent/MX9305274A/es unknown
- 1993-08-30 CN CN93117071A patent/CN1044572C/zh not_active Expired - Lifetime
- 1993-10-19 SA SA93140194A patent/SA93140194B1/ar unknown
-
1995
- 1995-02-27 NO NO950735A patent/NO306660B1/no not_active IP Right Cessation
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