RU94013070A - METHOD FOR OBTAINING PHENOL AND ITS DERIVATIVES - Google Patents

METHOD FOR OBTAINING PHENOL AND ITS DERIVATIVES

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Publication number
RU94013070A
RU94013070A RU94013070/04A RU94013070A RU94013070A RU 94013070 A RU94013070 A RU 94013070A RU 94013070/04 A RU94013070/04 A RU 94013070/04A RU 94013070 A RU94013070 A RU 94013070A RU 94013070 A RU94013070 A RU 94013070A
Authority
RU
Russia
Prior art keywords
derivatives
increases
aromatic compounds
nitrous oxide
catalytic oxidation
Prior art date
Application number
RU94013070/04A
Other languages
Russian (ru)
Other versions
RU2058286C1 (en
Inventor
Г.И. Панов
А.С. Харитонов
Г.А. Шевелева
Original Assignee
Институт катализа им.Г.К.Борескова СО РАН
Filing date
Publication date
Application filed by Институт катализа им.Г.К.Борескова СО РАН filed Critical Институт катализа им.Г.К.Борескова СО РАН
Priority claimed from RU9494013070A external-priority patent/RU2058286C1/en
Priority to RU9494013070A priority Critical patent/RU2058286C1/en
Priority to EP95916877A priority patent/EP0755371B1/en
Priority to AT95916877T priority patent/ATE182873T1/en
Priority to PL95316873A priority patent/PL179735B1/en
Priority to AU23768/95A priority patent/AU684948B2/en
Priority to US08/727,398 priority patent/US5756861A/en
Priority to PCT/RU1995/000066 priority patent/WO1995027691A1/en
Priority to CA002187656A priority patent/CA2187656C/en
Priority to DE69511256T priority patent/DE69511256T2/en
Priority to JP7526267A priority patent/JP2961128B2/en
Priority to CN95193219A priority patent/CN1071729C/en
Priority to UA96114345A priority patent/UA44891C2/en
Priority to BR9507370A priority patent/BR9507370A/en
Priority to KR1019960705723A priority patent/KR100231872B1/en
Priority to DK95916877T priority patent/DK0755371T3/en
Priority to ES95916877T priority patent/ES2136288T3/en
Priority to MXPA/A/1996/004822A priority patent/MXPA96004822A/en
Publication of RU94013070A publication Critical patent/RU94013070A/en
Publication of RU2058286C1 publication Critical patent/RU2058286C1/en
Application granted granted Critical
Priority to FI964102A priority patent/FI117628B/en

Links

Claims (1)

Изобретение относится к области органического синтеза, более конкретно к способу получения фенола и его производных путем парциального каталитического окисления бензола и его производных закисью азота
Figure 00000001

где X = H, OH, F, Cl, CH3, C2H5 или любой другой радикал, замещающий атом водорода в молекуле бензола. Настоящее изобретение решает задачу упрощения процесса и повышения его эффективности. Для решения этой задачи процесс каталитического окисления ароматических соединений ведут при температуре 250 - 500°С в избытке окисляемого вещества, которое одновременно играет роль компонента, повышающего теплоемкость реакционной смеси. Высокая концентрация ароматического соединения способствует снижению адиабатического разогрева, повышению селективности реакции и увеличению производительности катализатора. Это позволяет также обеспечить полное превращение закиси азота, исключая таким образом стадию ее выделения.The invention relates to the field of organic synthesis, more specifically to a method for producing phenol and its derivatives by means of partial catalytic oxidation of benzene and its derivatives with nitrous oxide
Figure 00000001

where X = H, OH, F, Cl, CH 3 , C 2 H 5 or any other radical replacing the hydrogen atom in the benzene molecule. The present invention solves the problem of simplifying the process and increasing its efficiency. To solve this problem, the process of catalytic oxidation of aromatic compounds is carried out at a temperature of 250 - 500 ° C in an excess of the oxidized substance, which simultaneously plays the role of a component that increases the heat capacity of the reaction mixture. A high concentration of aromatic compounds reduces adiabatic heating, increases the selectivity of the reaction and increases catalyst productivity. It also allows for the complete conversion of nitrous oxide, thus eliminating the stage of its release.
RU9494013070A 1994-04-12 1994-04-12 Method for production of phenol or its derivatives RU2058286C1 (en)

Priority Applications (18)

Application Number Priority Date Filing Date Title
RU9494013070A RU2058286C1 (en) 1994-04-12 1994-04-12 Method for production of phenol or its derivatives
DE69511256T DE69511256T2 (en) 1994-04-12 1995-04-12 METHOD FOR PRODUCING PHENOL AND ITS DERIVATIVES
CN95193219A CN1071729C (en) 1994-04-12 1995-04-12 method for production of phenol and its derivatives
PL95316873A PL179735B1 (en) 1994-04-12 1995-04-12 Method of obtaining phenol and derivatives thereof
AU23768/95A AU684948B2 (en) 1994-04-12 1995-04-12 Method for production of phenol and its derivatives
US08/727,398 US5756861A (en) 1994-04-12 1995-04-12 Method for production for phenol and its derivatives
PCT/RU1995/000066 WO1995027691A1 (en) 1994-04-12 1995-04-12 Method for production of phenol and its derivatives
CA002187656A CA2187656C (en) 1994-04-12 1995-04-12 Method for production of phenol and its derivatives
EP95916877A EP0755371B1 (en) 1994-04-12 1995-04-12 Method for production of phenol and its derivatives
JP7526267A JP2961128B2 (en) 1994-04-12 1995-04-12 Method for producing phenol and its derivatives
AT95916877T ATE182873T1 (en) 1994-04-12 1995-04-12 METHOD FOR PRODUCING PHENOL AND ITS DERIVATIVES
UA96114345A UA44891C2 (en) 1994-04-12 1995-04-12 METHOD OF OXIDATION OF AROMATIC COMPOUND USING NITROGEN OXIDE
BR9507370A BR9507370A (en) 1994-04-12 1995-04-12 Process for the production of phenol and its derivatives
KR1019960705723A KR100231872B1 (en) 1994-04-12 1995-04-12 Method for production of phenol and its derivatives
DK95916877T DK0755371T3 (en) 1994-04-12 1995-04-12 Process for the preparation of phenol and its derivatives
ES95916877T ES2136288T3 (en) 1994-04-12 1995-04-12 PROCEDURE FOR THE PRODUCTION OF PHENOL AND ITS DERIVATIVES.
MXPA/A/1996/004822A MXPA96004822A (en) 1994-04-12 1995-04-12 Method for the production of phenol and its deriva
FI964102A FI117628B (en) 1994-04-12 1996-10-11 A process for preparing phenol and phenol derivatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU9494013070A RU2058286C1 (en) 1994-04-12 1994-04-12 Method for production of phenol or its derivatives

Publications (2)

Publication Number Publication Date
RU94013070A true RU94013070A (en) 1995-12-27
RU2058286C1 RU2058286C1 (en) 1996-04-20

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU9494013070A RU2058286C1 (en) 1994-04-12 1994-04-12 Method for production of phenol or its derivatives

Country Status (17)

Country Link
US (1) US5756861A (en)
EP (1) EP0755371B1 (en)
JP (1) JP2961128B2 (en)
KR (1) KR100231872B1 (en)
CN (1) CN1071729C (en)
AT (1) ATE182873T1 (en)
AU (1) AU684948B2 (en)
BR (1) BR9507370A (en)
CA (1) CA2187656C (en)
DE (1) DE69511256T2 (en)
DK (1) DK0755371T3 (en)
ES (1) ES2136288T3 (en)
FI (1) FI117628B (en)
PL (1) PL179735B1 (en)
RU (1) RU2058286C1 (en)
UA (1) UA44891C2 (en)
WO (1) WO1995027691A1 (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5874646A (en) * 1996-08-07 1999-02-23 Solutia Inc. Preparation of phenol or phenol derivatives
US5892132A (en) * 1996-08-08 1999-04-06 Solutia Inc. Transport hydroxylation reactor
US5808167A (en) * 1996-08-20 1998-09-15 Solutia Inc. Selective introduction of active sites for hydroxylation of benzene
US5874647A (en) * 1996-08-20 1999-02-23 Solutia Inc. Benzene hydroxylation catalyst stability by acid treatment
WO1998015514A1 (en) 1996-10-07 1998-04-16 Solutia Inc. Process for the hydroxylation of benzene
US6156938A (en) * 1997-04-03 2000-12-05 Solutia, Inc. Process for making phenol or phenol derivatives
RU2127721C1 (en) 1997-07-29 1999-03-20 Институт органической химии им.Зелинского РАН Process for preparing phenol and derivatives thereof
ES2167106T3 (en) * 1998-04-30 2002-05-01 Creavis Tech & Innovation Gmbh PROCEDURE TO PREPARE AROMATIC COMPOUNDS CONTAINING HYDROXYL GROUPS.
US6080226A (en) * 1998-09-30 2000-06-27 Uop Llc Nitrous oxide purification by pressure swing adsorption
AU2509400A (en) * 1999-01-20 2000-08-07 Solutia Inc. Hydroxylation of aromatic compounds at elevated pressures
US6265622B1 (en) 1999-02-26 2001-07-24 General Electric Company Method and composition for hydroxylation of aromatic substrates
US6232510B1 (en) 1999-02-26 2001-05-15 General Electric Company Method and composition for hydroxylation of aromatic substrates
DE10009639A1 (en) * 1999-03-16 2000-09-21 Phenolchemie Gmbh & Co Kg Production of dinitrogen monoxide (laughing gas) by catalytic reduction of nitrogen monoxide with a reducing agent in the gas phase with heterogenic catalysis
RU2155181C1 (en) 1999-04-05 2000-08-27 Кустов Леонид Модестович Method of oxidation of toluene into phenol, and/or cresols
US6437197B1 (en) 2000-04-27 2002-08-20 Shell Oil Company Process for catalytic hydroxylation of aromatic hydrocarbons
US6548718B2 (en) 2000-04-27 2003-04-15 Shell Oil Company Process for catalytic hydroxylation of, saturated or unsaturated, aliphatic compounds
DE10133067A1 (en) * 2001-07-07 2003-01-16 Phenolchemie Gmbh & Co Kg Hydroxylation of aromatic hydrocarbons, useful for the hydroxylation of benzene to phenol, comprises use of nitrous oxide gas, prepared by reaction of ammonia with nitric acid
RU2228326C2 (en) * 2002-05-24 2004-05-10 Институт катализа им. Г.К. Борескова СО РАН Method for production of dihydroxybenzenes
RU2220947C1 (en) * 2002-06-25 2004-01-10 Институт катализа им. Г.К. Борескова СО РАН Method for preparing bicyclic and polycyclic ketones and their derivatives
RU2219160C1 (en) * 2002-06-25 2003-12-20 Институт катализа им. Г.К.Борескова СО РАН Method for production of carbonyl compounds from di- and polyene cyclic hydrocarbons and derivatives thereof
ITMI20050062A1 (en) * 2005-01-20 2006-07-21 Polimeri Europa Spa PROCESS FOR THE PREPARATION OF PHENOL
JP5579183B2 (en) * 2008-08-29 2014-08-27 ビーエーエスエフ ソシエタス・ヨーロピア Method for producing cyclic ketone
CN102020535B (en) * 2009-09-17 2014-04-02 北京化工大学 Method for producing phenol by oxidizing benzene through nitrous oxide
CZ201091A3 (en) 2010-02-05 2010-08-04 Výzkumný ústav anorganické chemie, a. s. Process for preparing zeolites of pentasil structure with controlled distribution of aluminium ions within skeleton
US10550063B2 (en) 2014-10-02 2020-02-04 Monsanto Technology Llc Processes for preparing 2,5-dichlorophenol
CN106588577B (en) * 2015-10-19 2019-08-06 江苏福瑞康泰药业有限公司 The synthetic method of Pentafluorophenol

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4429176A (en) * 1982-02-08 1984-01-31 Mobil Oil Corporation Active zeolite catalysts of improved stability
IT1150699B (en) * 1982-03-19 1986-12-17 Anic Spa PROCEDURE FOR THE OXIDRILATION OF AROMATIC HYDROCARBONS
US4559314A (en) * 1982-03-22 1985-12-17 Mobil Oil Corporation Zeolite activation
US5098687A (en) * 1984-04-26 1992-03-24 Uop Substituted aluminosilicate compositions and process for preparing same
US4952385A (en) * 1987-03-02 1990-08-28 Georgia Tech Research Corp. Ferrisilicate molecular sieve and use as a catalyst
FR2630733B1 (en) * 1988-05-02 1990-07-20 Rhone Poulenc Chimie PROCESS FOR THE PREPARATION OF PHENOL
FR2630734B1 (en) * 1988-05-02 1990-07-27 Rhone Poulenc Chimie PROCESS FOR THE PREPARATION OF DIHYDROXYBENZENES
FR2648810B1 (en) * 1989-06-22 1992-02-28 Rhone Poulenc Chimie PROCESS FOR THE PREPARATION OF PHENOLS
RU2010790C1 (en) * 1989-08-11 1994-04-15 Институт катализа СО РАН Method of phenol and its derivatives synthesis
US5110995A (en) * 1991-03-12 1992-05-05 Institute Of Catalysis Preparation of phenol or phenol derivatives
DE4117511A1 (en) * 1991-05-29 1992-12-03 Vaw Ver Aluminium Werke Ag METHOD FOR MODIFYING A PURE-TYPE PURE-SYNTHETIZED ZEOLITE OF PURE-TYPE
JPH07110825B2 (en) * 1993-02-03 1995-11-29 旭化成工業株式会社 Phenol manufacturing method
US5367099A (en) * 1993-05-28 1994-11-22 Mobil Oil Corp. Selective toluene disproportionation process (STDP) with ex situ selectivated zeolite catalyst
RU2074164C1 (en) * 1994-04-12 1997-02-27 Институт катализа им.Г.К.Борескова СО РАН Method of producing phenol and derivatives thereof

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