RU94006783A - Твердый предшественник каталитической системы для полимеризации олефинов, способ его получения, каталитическая система для полимеризации олефинов и способ полимеризации олефинов - Google Patents
Твердый предшественник каталитической системы для полимеризации олефинов, способ его получения, каталитическая система для полимеризации олефинов и способ полимеризации олефиновInfo
- Publication number
- RU94006783A RU94006783A RU94006783/04A RU94006783A RU94006783A RU 94006783 A RU94006783 A RU 94006783A RU 94006783/04 A RU94006783/04 A RU 94006783/04A RU 94006783 A RU94006783 A RU 94006783A RU 94006783 A RU94006783 A RU 94006783A
- Authority
- RU
- Russia
- Prior art keywords
- polymerization
- olefins
- catalytic system
- solid precursor
- production
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title claims 5
- 230000003197 catalytic Effects 0.000 title claims 5
- 238000006116 polymerization reaction Methods 0.000 title claims 5
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 title claims 4
- 239000007787 solid Substances 0.000 title claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 230000001264 neutralization Effects 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 150000002902 organometallic compounds Chemical class 0.000 claims 1
- 230000000737 periodic Effects 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
Claims (1)
- Предложены твердый предшественник каталитической системы для полимеризации олефинов, содержащий по крайней мере один галогенированный нейтральный металлоцен - производный переходного металла, причем этот металл связан по крайней мере с одним атомом галогена, и по крайней мере один ионизирующий агент. В способе получения этого твердого предшественника соединение на основе нейтрального галогенированного металлоцена смешивают с соединением на основе ионизирующего агента в гетерогенной среде. Предложены также каталитическая система, включающая металлоорганическое соединение - производное металла, выбираемого среди элементов групп IА, IIА, IIБ, IIIА и IVА периодической системы, и твердый предшественник, описанный выше, способ полимеризации олефинов, в котором используют эту каталитическую систему.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9300191A BE1006880A3 (fr) | 1993-03-01 | 1993-03-01 | Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique. |
BE09300191 | 1993-03-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
RU94006783A true RU94006783A (ru) | 1995-09-27 |
RU2141972C1 RU2141972C1 (ru) | 1999-11-27 |
Family
ID=3886874
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU94006783A RU2141972C1 (ru) | 1993-03-01 | 1994-02-28 | Твердый предшественник каталитической системы для полимеризации олефинов, способ его получения, каталитическая система для полимеризации олефинов и способ полимеризации олефинов |
Country Status (14)
Country | Link |
---|---|
US (2) | US5763349A (ru) |
EP (2) | EP0838476B1 (ru) |
JP (1) | JP3492749B2 (ru) |
KR (1) | KR100300486B1 (ru) |
CN (1) | CN1044372C (ru) |
AT (2) | ATE206141T1 (ru) |
BE (1) | BE1006880A3 (ru) |
BR (1) | BR9400684A (ru) |
CA (1) | CA2116404A1 (ru) |
DE (2) | DE69428464T2 (ru) |
ES (2) | ES2122142T3 (ru) |
PT (1) | PT838476E (ru) |
RU (1) | RU2141972C1 (ru) |
TW (1) | TW332210B (ru) |
Families Citing this family (36)
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US5498582A (en) * | 1993-12-06 | 1996-03-12 | Mobil Oil Corporation | Supported metallocene catalysts for the production of polyolefins |
DE4431838A1 (de) * | 1994-09-07 | 1996-03-14 | Basf Ag | Geträgerte Metallocen-Katalysatorsysteme |
BE1009186A3 (fr) * | 1995-03-13 | 1996-12-03 | Solvay | Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene. |
US6451725B1 (en) * | 1995-04-12 | 2002-09-17 | Borealis Technology Oy | Method for preparing catalyst components |
DE19606166A1 (de) | 1996-02-20 | 1997-08-21 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alkenen durch Suspensionspolymerisation |
DE19606165A1 (de) | 1996-02-20 | 1997-08-21 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alkenen durch Gasphasenpolymerisation |
DE19606167A1 (de) | 1996-02-20 | 1997-08-21 | Basf Ag | Geträgerte Katalysatorsysteme |
US5965477A (en) * | 1997-02-21 | 1999-10-12 | Council Of Scientific & Industrial Research | Process for the preparation of supported metallocene catalyst |
US5955554A (en) * | 1997-03-27 | 1999-09-21 | Council Of Scientific Industrial Research | Process for polymerization and copolymerization of olefins |
AU702218B2 (en) * | 1997-03-31 | 1999-02-18 | Kyushu-Taiyoukasei., Ltd. | Liner film for bulk container and container liner |
EP0878485B1 (en) * | 1997-05-14 | 2006-04-26 | Council of Scientific and Industrial Research | A process for polymerization of olefins |
GB9712663D0 (en) * | 1997-06-16 | 1997-08-20 | Borealis As | Process |
DE19811934A1 (de) | 1998-03-19 | 1999-09-23 | Basf Ag | Ethylencopolymere mit enger Comonomerverteilung |
BE1012364A3 (fr) * | 1998-12-22 | 2000-10-03 | Solvay | Procede pour la preparation d'une composition catalytique pour la polymerisation des alpha-olefines, composition catalytique obtenue et procede de polymerisation utilisant une telle composition catalytique |
EP2261292B1 (en) * | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
US7618913B2 (en) * | 2006-08-31 | 2009-11-17 | Formosa Plastics Corporation, U.S.A. | Highly active alpha-olefin copolymerization catalyst system |
ES2549693T3 (es) * | 2006-11-14 | 2015-10-30 | Univation Technologies, Llc | Sistemas catalizadores y procesos de polimerización |
JP6042347B2 (ja) | 2011-01-28 | 2016-12-14 | クレーン アンド カンパニー インコーポレイテッド | レーザマーキングされたデバイス |
CN104024921B (zh) | 2011-08-19 | 2018-09-21 | 光学物理有限责任公司 | 具有减小的厚度的任选地可转移光学系统 |
CA2760264C (en) | 2011-12-05 | 2018-08-21 | Nova Chemicals Corporation | Passivated supports for use with olefin polymerization catalysts |
EP4282665A1 (en) | 2012-08-17 | 2023-11-29 | Visual Physics, LLC | A process for transferring microstructures to a final substrate |
CN105339180B (zh) | 2013-03-15 | 2018-05-11 | 光学物理有限责任公司 | 光学安全性设备 |
US9873281B2 (en) | 2013-06-13 | 2018-01-23 | Visual Physics, Llc | Single layer image projection film |
BR112015031644B1 (pt) * | 2013-07-09 | 2021-09-21 | Dow Global Technologies Llc | Composição compreendendo um interpolímero de etileno/alfaolefina e artigo |
JP2017522602A (ja) | 2014-03-27 | 2017-08-10 | ビジュアル フィジクス エルエルシー | フリッカー状の光学効果を生成する光学デバイス |
US10766292B2 (en) | 2014-03-27 | 2020-09-08 | Crane & Co., Inc. | Optical device that provides flicker-like optical effects |
BR112017000914B1 (pt) | 2014-07-17 | 2022-03-03 | Visual Physics, Llc. | Material de lâmina polimérica aprimorada para uso na produção de documentos de segurança poliméricos, tais como notas bancárias |
AU2015317844B2 (en) | 2014-09-16 | 2019-07-18 | Crane Security Technologies, Inc. | Secure lens layer |
US9303106B1 (en) * | 2014-10-17 | 2016-04-05 | Chevron Phillips Chemical Company Lp | Processes for preparing solid metallocene-based catalyst systems |
EP3256642A1 (en) | 2015-02-11 | 2017-12-20 | Crane & Co., Inc. | Method for the surface application of a security device to a substrate |
BR112019005673B1 (pt) * | 2016-09-29 | 2023-02-14 | Dow Global Technologies Llc | Catalisador melhorado, método de preparação de um catalisador melhorado, método de polimerização de uma olefina com o uso de um catalisador melhorado, prócatalisador de titânio suportado por haleto de magnésio,catalisador de titânio suportado por haleto de magnésio e método de polimerização de uma olefina com o uso de um catalisador de titânio suportado por haleto de magnésio |
CN110582412B (zh) | 2017-02-10 | 2022-08-30 | 克瑞尼股份有限公司 | 机器可读光学安全器件 |
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US4242480A (en) * | 1977-12-13 | 1980-12-30 | Phillips Petroleum Company | Catalyst and process of polymerization of alpha monoolefins |
US5077255A (en) * | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
PL276385A1 (en) * | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
CA2027145C (en) * | 1989-10-10 | 2002-12-10 | Michael J. Elder | Metallocene catalysts with lewis acids and aluminum alkyls |
CA2027122C (en) * | 1989-10-30 | 2002-12-10 | John A. Ewen | Making metallocene catalysts using aluminum alkyls for controlled polymerization of olefins |
US5387568A (en) * | 1989-10-30 | 1995-02-07 | Fina Technology, Inc. | Preparation of metallocene catalysts for polymerization of olefins |
US5266544A (en) * | 1989-12-29 | 1993-11-30 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for the polymerization of olefins |
WO1992001723A1 (en) * | 1990-07-24 | 1992-02-06 | Mitsui Toatsu Chemicals, Incorporated | CATALYST FOR α-OLEFIN POLYMERIZATION AND PRODUCTION OF POLY-α-OLEFIN THEREWITH |
JP2895199B2 (ja) * | 1990-10-02 | 1999-05-24 | 三井化学株式会社 | オレフィンの重合触媒 |
US5369196A (en) * | 1990-11-30 | 1994-11-29 | Idemitsu Kosan Co., Ltd. | Production process of olefin based polymers |
EP0522581B1 (en) * | 1991-07-11 | 1997-10-15 | Idemitsu Kosan Company Limited | Process for producing olefin based polymers and olefin polymerization catalyst |
FR2686675B1 (fr) * | 1992-01-24 | 1995-06-16 | Sicmo | Clapet de detendeur pour pistolet a peinture. |
BE1005957A5 (fr) * | 1992-06-05 | 1994-04-05 | Solvay | Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine. |
JP3153000B2 (ja) * | 1992-06-11 | 2001-04-03 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
US5710222A (en) * | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
BE1006438A3 (fr) * | 1992-12-17 | 1994-08-30 | Solvay | Systeme catalytique, utilisation de ce systeme catalytique pour la (co)polymerisation d'olefines, procede de preparation de ce systeme catalytique et procede de (co)polymerisation d'olefines. |
WO1995018836A1 (en) * | 1994-01-11 | 1995-07-13 | Exxon Chemical Patents Inc. | Alumoxanes and catalysts comprising alumoxanes |
-
1993
- 1993-03-01 BE BE9300191A patent/BE1006880A3/fr not_active IP Right Cessation
-
1994
- 1994-02-17 EP EP97120938A patent/EP0838476B1/fr not_active Expired - Lifetime
- 1994-02-17 AT AT97120938T patent/ATE206141T1/de not_active IP Right Cessation
- 1994-02-17 EP EP94200399A patent/EP0613908B1/fr not_active Expired - Lifetime
- 1994-02-17 AT AT94200399T patent/ATE169033T1/de not_active IP Right Cessation
- 1994-02-17 DE DE69428464T patent/DE69428464T2/de not_active Expired - Fee Related
- 1994-02-17 DE DE69411968T patent/DE69411968T2/de not_active Expired - Fee Related
- 1994-02-17 ES ES94200399T patent/ES2122142T3/es not_active Expired - Lifetime
- 1994-02-17 ES ES97120938T patent/ES2164979T3/es not_active Expired - Lifetime
- 1994-02-17 PT PT97120938T patent/PT838476E/pt unknown
- 1994-02-24 CA CA002116404A patent/CA2116404A1/fr not_active Abandoned
- 1994-02-25 BR BR9400684A patent/BR9400684A/pt not_active IP Right Cessation
- 1994-02-28 RU RU94006783A patent/RU2141972C1/ru active
- 1994-02-28 TW TW083101682A patent/TW332210B/zh active
- 1994-03-01 CN CN94104084A patent/CN1044372C/zh not_active Expired - Fee Related
- 1994-03-01 JP JP03124794A patent/JP3492749B2/ja not_active Expired - Fee Related
- 1994-03-02 KR KR1019940003953A patent/KR100300486B1/ko not_active IP Right Cessation
-
1996
- 1996-02-15 US US08/606,686 patent/US5763349A/en not_active Expired - Fee Related
-
1998
- 1998-04-13 US US09/058,962 patent/US6214948B1/en not_active Expired - Fee Related
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