RU93049735A - Method of producing cyclohexylhydroperoxide - Google Patents

Method of producing cyclohexylhydroperoxide

Info

Publication number
RU93049735A
RU93049735A RU93049735/04A RU93049735A RU93049735A RU 93049735 A RU93049735 A RU 93049735A RU 93049735/04 A RU93049735/04 A RU 93049735/04A RU 93049735 A RU93049735 A RU 93049735A RU 93049735 A RU93049735 A RU 93049735A
Authority
RU
Russia
Prior art keywords
producing
cyclohexylhydroperoxide
cyclohexane
cyclohexyl hydroperoxide
cyclohexanol
Prior art date
Application number
RU93049735/04A
Other languages
Russian (ru)
Other versions
RU2121996C1 (en
Inventor
Герардус Мария де Ван Мусдэйк Корнелис
Original Assignee
Дсм Н.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from NL9201269A external-priority patent/NL9201269A/en
Application filed by Дсм Н.В. filed Critical Дсм Н.В.
Publication of RU93049735A publication Critical patent/RU93049735A/en
Application granted granted Critical
Publication of RU2121996C1 publication Critical patent/RU2121996C1/en

Links

Claims (1)

Изобретение относится к способу получения циклогексилгидропероксида путем превращения циклогексана в смесь, состоящую, главным образом, из 0,5 - 8,0 мас. % циклогексилгидропероксида и 0,1 - 4,0 мас. % циклогексанола и циклогексанона в циклогексане, что осуществляют, используя кислородсодержащий газ при 130 - 200°С и 4 - 50 бар в течение 0,05 до 14,0 ч без катализатора и в случае необходимости подвергая полученную после реакции смесь частичному расширению, причем в начале процесса окисления в циклогексане присутствует 0,1 - 3 мас. % оксидных продуктов с линейными или циклическими цепями, содержащими 1 - 6 атомов углерода.The invention relates to a method for producing cyclohexyl hydroperoxide by converting cyclohexane into a mixture consisting mainly of 0.5 - 8.0 wt. % cyclohexyl hydroperoxide and 0.1 - 4.0 wt. % cyclohexanol and cyclohexanone in cyclohexane, which is carried out using oxygen-containing gas at 130–200 ° C and 4–50 bar for 0.05 to 14.0 h without a catalyst and, if necessary, subjecting the mixture obtained after the reaction to partial expansion, and At the beginning of the oxidation process, 0.1 to 3 wt. % oxide products with linear or cyclic chains containing 1 to 6 carbon atoms.
RU93049735A 1992-07-15 1993-07-14 Method of preparing cyclohexylhydroperoxide RU2121996C1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL9201269 1992-07-15
NL92-01269 1992-07-15
NL9201269A NL9201269A (en) 1992-07-15 1992-07-15 PROCESS FOR THE PREPARATION OF CYCLOHEXYL HYDROPEROXIDE.

Publications (2)

Publication Number Publication Date
RU93049735A true RU93049735A (en) 1996-06-20
RU2121996C1 RU2121996C1 (en) 1998-11-20

Family

ID=19861062

Family Applications (1)

Application Number Title Priority Date Filing Date
RU93049735A RU2121996C1 (en) 1992-07-15 1993-07-14 Method of preparing cyclohexylhydroperoxide

Country Status (20)

Country Link
EP (1) EP0579323B1 (en)
JP (1) JP3599758B2 (en)
KR (1) KR100278129B1 (en)
CN (1) CN1051763C (en)
AT (1) ATE143358T1 (en)
BR (1) BR9302860A (en)
CZ (1) CZ288373B6 (en)
DE (1) DE69305015T2 (en)
ES (1) ES2093914T3 (en)
GE (1) GEP19971110B (en)
HU (1) HU218302B (en)
MX (1) MX9304248A (en)
MY (1) MY108925A (en)
NL (1) NL9201269A (en)
PL (1) PL178142B1 (en)
RU (1) RU2121996C1 (en)
SG (1) SG49325A1 (en)
SK (1) SK281678B6 (en)
TW (1) TW321635B (en)
UA (1) UA44214C2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU4658199A (en) * 1998-06-26 2000-01-17 Dsm N.V. Diesel mixture containing cycloalkylhydroperoxide
JP4601805B2 (en) * 2000-11-24 2010-12-22 ダイセル化学工業株式会社 Cyclohexane oxidation method
US7091365B2 (en) 2004-03-08 2006-08-15 Abb Lummus Global Inc. Process for olefin epoxidation and co-production of nylon precursor
JP2008518001A (en) * 2004-10-27 2008-05-29 ディーエスエム アイピー アセッツ ビー．ブイ． Process for producing cyclohexanol and cyclohexanone
ATE486054T1 (en) * 2004-12-22 2010-11-15 Dsm Ip Assets Bv METHOD FOR DECOMPOSITING CYCLOHEXYL HYDROPEROXIDE
JP5160048B2 (en) * 2006-05-15 2013-03-13 旭化成ケミカルズ株式会社 Method for producing allyl alcohol
CN101417968B (en) * 2007-10-26 2013-09-11 环球油品公司 Method for preparing hydroperoxide
FR2954314B1 (en) * 2009-12-17 2012-01-27 Rhodia Operations PROCESS FOR HYDROCARBON OXIDATION BY OXYGEN
CN103987452B (en) 2011-12-07 2016-02-24 Capiii有限公司 Comprise the preparation method of the mixture of cyclohexanol and cyclohexanone
WO2013083513A1 (en) 2011-12-07 2013-06-13 Dsm Ip Assets B.V. Process for the production of a mixture comprising cyclohexanol and cyclohexanone
RU2673541C1 (en) * 2017-10-13 2018-11-28 Открытое акционерное общество "Щекиноазот" Method for producing cyclohexanone, cyclohexanol and cyclohexyl hydroperoxide, installation for its implementation and a device for the adsorption of reactive gases and preliminary cyclohexane oxidation
RU2747484C1 (en) * 2020-10-27 2021-05-05 Публичное акционерное общество "КуйбышевАзот" Method for producing cyclohexyl hydroperoxide

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH467230A (en) * 1964-03-03 1969-01-15 Wallace & Tiernan Inc Process for the preparation of alkanedicarboxylic acids from cycloalkanes
FR1506296A (en) * 1966-03-11 1967-12-22 Charbonnages De France Continuous oxidation process of organic compounds

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