RU2734252C1 - Hair conditioning agents compositions and hair coloring compositions - Google Patents

Abstract

FIELD: cosmetic industry.

SUBSTANCE: disclosed hair conditioning compositions for use in hair coloring compositions based on cationic polymers and/or cationic surfactants, contain Bis (C_13-15 Alkoxy) PG Amodimethicone, Amodimethicone in combination with Polyquaternium-7, or Quaternium-70, or Polyquaternium-7 and Quaternium-70. Invention also relates to hair dye compositions containing such compositions of hair conditioning agents, and to use of such combinations of hair conditioning agents. When using exactly cationic surfactants and polymers it is possible to achieve absence of loosening of hair structure, which is characterized by greater smoothness of hair flakes and correspondingly lower relative force at combing.

EFFECT: technical result is hair conditioning during staining, maintaining aesthetic beauty of hair during dyeing and after it, maintaining smoothness of hair during dyeing and after it.

9 cl, 4 ex, 7 tbl, 1 dwg

Description

FIELD OF TECHNOLOGY

The invention relates to the cosmetic industry, namely the production of compositions for dyeing hair, incl. containing agents for hair conditioning. The proposed compositions of agents for hair conditioning, intended for use in compositions for hair coloring based on cationic polymers and / or cationic surfactants, contain Bis (C13-15 Alkoxy) PG Amodimethicone (Bis (C13-15 Alkoxy) PG Amodimethicone), Amodimethicone (Amodimethicone ) in combination with Polyquaternium-7, or Quaternium-70, or with Polyquaternium-7 and Quaternium-70. The invention also relates to hair-dyeing compositions containing such hair conditioning agent compositions and to the use of such hair conditioning agent combinations.

PRIOR ART

Creamy hair dye formulations are more comfortable to use. Thickening is carried out using various polymers: nonionic (US7204859B2 publ. 17.04.2007 L'OREAL SA; EP1813263A1 publ. 01.08.2007 WELLA AKTIENGESELLSCHAFT), cationic (EP3173356A1 publ. 05/31/2017 PROCTER & GAMBLE7300 and anionic (published 27/05/2017 PROCTER & GAMBLE) and anionic (USB2 2007 L'OREAL SA). In addition, the formulations contain surfactants (surfactants) as conditioning agents, emulsifiers, dispersants, etc. As studies of recent years have shown, cationic polymers and cationic surfactants (RU2367408C1 publ. 09/20/2009 L'OREAL) have proven themselves best in such compositions. This can be explained by the fact that in addition to the effective conditioning effect - giving the hair smoothness, elasticity and shine, they also act as compensation ions. When hair comes into contact with water, a negative potential arises on the surface of keratin. Due to the fact that it absorbs hydroxyl anions and protons from water at different rates, hydroxyls are absorbed much faster. The consequence of this is that anionic dyes, and these include various phenols and aminophenols in an alkaline medium, will repel from the keratin surface of the same name. The action of the negative potential extends over a distance of 10 nm, while for the interaction of the dye with the hair, it must approach a distance of 0.2-0.5 nm. It is cationic polymers and cationic surfactants that neutralize the negative charge of the hair keratin surface and promote the penetration of dyes into the hair.

However, cationic polymers and cationic surfactants interact not only with hair keratin, but also with dye anions in the emulsion, forming labile, inactive complexes. The consequence of this is a decrease in the substance of the dyes to the hair and a slight slowdown in the speed of dyeing, which leads to more even colors. But an increase in the dyeing time leads to a decrease in the alkalinity of the dye composition due to the volatility of ammonia in aqueous solutions of ammonium hydroxide, especially at elevated temperatures, and this worsens the intensity and depth of hair dyeing.

Oxidation dyes (FR2870733B1 publ. 07.07.2006 L'OREAL SOCIETE ANONYME; US7044986B2 publ. 16.05.2006 KAO CORPORATION; US7056497B2 publ. 06/06/2006 are proposed to be used as dyes for deep and long-lasting (persistent) hair dyeing; US7056497B2 publ. THE PROCTER & GAMBLE COMPANY). This is determined by the following generally known requirements for hair dyes: 1) dyeing should take place for a short period of time at room temperature and should not cause damage to the hair shaft or scalp; 2) dyes should give hair a natural color and paint over the scalp to a minimum; 3) a short dyeing time requires the use of formulations with a high concentration of dye; 4) the diffusion of the dye into human hair is much slower than into the keratin of the wool, therefore, dyes of small sizes with a low molecular weight are required. Only oxidation dyes meet these requirements.

Direct-acting dyes, such as nitro-, acidic, basic (cationic), active, dispersed, are added to dye compositions to give the required shade, but they are retained mainly on the hair surface due to the formation of hydrogen bonds, van der forces Waals and London, without penetrating deep inside due to the large size of the molecules and the low diffusion rate, as a result of which they are quickly washed off.

To loosen the hair structure, ammonia in the form of an aqueous solution (ammonium hydroxide) has been and continue to be used as an alkaline agent for many decades (FR2856292B1 publ. 26.08.2005 L'OREAL; FR2883737B1 published 12.06.2009 L'OREAL SOCIETE ANONYME). This gives the most durable and effective hair coloring, especially problematic.

Therefore, along with the improvement of dye compositions, the production of hair conditioners has been intensively developing in recent decades, designed to at least slightly mitigate the harmful effects of dyes.

The history of using air conditioners goes back several centuries. Since ancient times, people have treated their hair with oils and fats to give it shine, protect it from environmental factors (sunlight). Many of these conditioning additives are still used today, such as vegetable oils, essential oils, and beeswax. Modern air conditioners include not only natural components, but also various chemically synthesized substances. These are various silicones, carbon polymers with heat-protective, smoothing and reflective properties, which make hair easier to comb and prevent tangling.

From the publication of the European patent application EP2022481A1 (publ. 11.02.2009; KPSS-KAO PROFESSIONAL SALON SERVICES GMBH) an aqueous composition for conditioning keratin fibers, especially human hair, is known, containing at least one cationic cellulose polymer and at least one cationic or convertible into cation silicone compound. Said cationic cellulose polymer can be selected from Polyqauternium 4, Polyqauternium 10, Polyqauternium 24, Polyqauternium 67, and Polyqauternium 72. Said silicone compound can be selected from Amodimethicone, Quaternium-80, quaternized grafted polymers of organopolysiloxane and polyxykois C13 PG-amodimethicone. Quaternium-8, Quaternium-14, Quaternium-15 Quaternium-18, Quaternium-22, Quaternium-24, Quaternium-26, Quaternium-27, Quaternium-30, Quaternium-33, Quaternium-53, Quaterntum-60, Quaternium-61, Quaternium-72, Quaternium-78, Quaternium-81, Quaternium-82, Quaternium-83, Quaternium-84. The composition may additionally contain Behentrimonuim chloride.

From the publication of the international patent application WO2004108099A2 (publ. 03/15/2008; THE PROCTER & GAMBLE COMPANY) a conditioning composition for hair or skin is known, which may contain, inter alia, the nanoemulsion Amodimethicone (XS65-B6413), Bis (C13-15 Alkoxy) PG Amodimethicone (DC2-8500), Polyquaternium 7, Quaternium-8, Quaternium-14, Quaternium-18, Quaternium-18 Methosulfate, Quaternium-24.

From the publication of the Korean patent application WO2005063175A1 (publ. 14.07.2005; UNILEVER PLC) a hair conditioning mousse is known which may contain, among others, Amodimethicone, Quaternium-16, Quaternium-24, Polyquaternium-5, Polyquaternium-6, Polyquaternium-7 , Polyquaternium-10, Polyquaternium-11, Behentrimonium chloride, Cetearyl methicone.

A shampoo containing Polyquaternium-10, Polyquatemium-7, Dimethicone, Bis (C13-14 Alkoxy) PGA Amodimethicone), Amodimethicone / Trideteth-12 is known from Korean patent application publication KR20090055760A (publ. 06/03/2009, CENTELLA CO., LTD). The invention is directed to solving the problem of additional hair conditioning when washing hair.

From the publication of international patent application WO2009090114A1 (publ. 23.07.2009; HENKEL AG & CO. KGAA) powder compositions for imparting shape and shine to keratin fibers are known, which may contain, inter alia, Polyquaternium-1, Polyquaternium-2, Polyquaternium-4, Polyquaternium-5, Polyquaternium-6, Polyquaternium-7, Polyquaternium-8, Polyquaternium-9, Polyquaternium-10, Polyquaternium-11, Polyquaternium-12, Polyquaternium-13, Polyquaternium-14, Polyquaternium-15, Polyquaternium-16, 17, Polyquaternium-18, Polyquaternium-19, Polyquaternium-20, Polyquaternium-22, Polyquaternium-24, Polyquaternium-27, Polyquaternium-28, Polyquaternium-29, Polyquaternium-30, Polyquaternium-31, Polyquaternium-32, Polyquaternium-33 Polyquaternium-34, Polyquaternium-35, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-45, Polyquaternium-46, Polyquaternium-47, Polyquaternium-48, Polyquaternium-49, Polyquaternium50, Polyquaternium-55, Polyquaternium-50 Quaternium-27, Quaternium-83, Amodimethicone, Bis (C13-15 Alkoxy) PG Amodimethicone. The invention is aimed at solving the problem of additional conditioning of hair and is mainly in the form of a powder.

From the publication of the RF patent RU2367408C1 (publ. 20.09.2009; L'OREAL) a composition for dyeing keratin fibers is known, which includes at least one dye for direct dyeing, at least one bioheteropolysaccharide, at least one cationic surfactant and at least one amphoteric surfactant. The composition may contain, but is not limited to, Amodimethicone, Quaternium-27, Quaternium-70, Quaternium-83, Quaternium-87.

From the publication of the European patent application EP3173356A1 (publ. 05/31/2017; THE PROCTER & GAMBLE COMPANY) a set for hair dyeing is known and it is disclosed that, among other things, Bis (C13-15 Alkoxy) can be used in a hair dyeing system with various traditional purposes PG Amodimethicone (DC 8500), AEC Polyquaternium-7, Quaternium 80, Quaternium-27 (CTFA 1997) or Quaternium-83 (CTFA 1997), Behentrimonium chloride.

From the publication of the international patent application WO2014137739A1 (publ. 09/12/2014; AVON PRODUCTS, INC) a method for restoring damaged hair is known. The description of the application indicates that in the implementation of the invention can be used Amodimethicone, Cetearyl Methicone, Polyquaternium-4, Polyquaternium-6, Polyquaternium-7, Polyquaternium-10, Polyquaternium-11, Polyquaternium-16, Polyquaternium-22, Polyquaternium-28, Polyquaternium- 32, Polyquaternium-37, Quaternium-18, Quaternium-80, Bentrimonium chloride.

From the publication of the RF patent RU2541811C1 (publ. 02/20/2015; UNICOSMETIC LLC), a composition for dyeing hair is known, characterized in that it consists of 2 phases - Phase A and Phase B, placed separately from each other and mixed immediately before use, where Phase B is an oxidizing agent in the form of an aqueous solution containing hydrogen peroxide, pH 3.5; a Phase A, containing cationic polymers and cationic surfactants, includes a mixture of alkaline agents of ammonium hydroxide, 25% solution, and a non-volatile aminomethylpropanol base, creating a pH of 9.2-10.8 during the entire staining time (40-50 minutes), which leads to the receipt of intense, deep and long-lasting colors, introduced into a creamy emulsion, which contains oxidation dyes as coloring components, and / or their salts with inorganic acids, and / or dyes of direct action; as a thickening agent carnauba wax, rose wax; as an emulsifier ceteareth-30, PEG-40 hydrogenated castor oil, lanolin; as a solvent propylene glycol, ethoxydiglycol; as conditioning agents cetearylmethicone, dimethiconol; as cationic polymers polyquaternium-16, polyquaternium-7; as cationic surfactants quaternium-70, behentrimonium chloride; as nonionic surfactants cocamide MEA; as reducing agents - sodium sulfite, sodium erythorbate, sodium hydrosulfite; as a water softener, tetrasodium salt of ethylenediaminetetraacetic acid; as preservatives methylparaben, ethylparaben, propylparaben in phenoxyethanol; perfume composition and water with the following ratios of components in the specified emulsion, in wt%:

thickening agent: carnauba wax, rose wax 0.6-5.5%, emulsifier: ceteareth-30, lanolin, PEG-40 hydrogenated castor oil 2.0-24.0%, organic solvent: propylene glycol ethoxydiglycol 1.5-14.0%, coloring component 0.0001-10.0%, conditioning agent: cetearylmethicone dimethiconol 1.0-10.0%, cationic polymer: polyquaternium-16 polyquaternium-7 1.0-9.0%, cationic surfactant: quaternium-70 behentrimonium chloride 2.0-30.0%, nonionic surfactant: cocamide MEA 1.0-15.0%, reducing agent: sodium sulfite, sodium erythorbate sodium hydrogen sulfite 0.31-3.5%, perfume composition 0.1-1.2%, preservative: methylparaben, propylparaben ethylparaben in phenoxyethanol 0.1-1.0%, complex - tetrasodium salt ethylenediaminetetraacetic acid 0.1-1.0%, mica, titanium dioxide 0.1-1.0%, water up to 100%.

Based on the problem indicated in the publication, the technical solution is aimed at solving the problem of maintaining a constant alkalinity of the medium and, as a result, intense, deep and persisting for a long time hair coloring.

This document discloses a solution to the problem of conditioning hair, maintaining its aesthetic beauty after dyeing with oxidation dyes, which takes place in an alkaline environment, which greatly loosens the hair.

The claimed invention is aimed at overcoming the disadvantages that exist in this field at the time of the creation of the invention, and solving the following problems: conditioning the hair during dyeing, maintaining the aesthetic beauty of the hair during and after dyeing, maintaining smoothness of the hair during and after dyeing. When using cationic surfactants and polymers, it is possible to achieve the absence of loosening of the hair structure, which is characterized by a greater smoothness of the hair scales and, accordingly, a decrease in the relative total effort when combing, and other negative effects known to specialists in this field that appear with permanent and semi-permanent hair dyeing.

In the course of research, it was found that the addition of Begentrimonium chloride has a positive effect on dry combing, further reducing the effort by 3-5%. Introduction Cetearyl methicone has a positive effect on wet brushing, further reducing the effort by 2-4.

SUMMARY OF THE INVENTION

In one aspect, the claimed invention relates to a hair conditioning composition for use in hair dyeing compositions based on cationic polymers and / or cationic surfactants, comprising a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Polyquaternium-7 in a ratio of approximately 1: 1: 10 to approximately 10: 10: 1.

In one aspect, the claimed invention relates to a hair conditioning composition for use in hair dye formulations based on cationic polymers and / or cationic surfactants comprising a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Quaternium-70 in a ratio of approximately 1: 1: 30 to approximately 10: 10: 1.

In one aspect, the claimed invention relates to a hair conditioning composition for use in hair dye formulations based on cationic polymers and / or cationic surfactants comprising a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone, Polyquaternium-7 and Quaternium- 70 in a ratio from about 1: 1: 10: 30 to about 10: 10: 1: 1.

The composition of the invention may additionally contain Begentrimonium chloride such that Bis (C13-15 Alkoxy) PG Amodimethicone and Begentrimonium chloride are in a ratio of from about 1:30 to about 10: 1, respectively.

The composition of the invention may further comprise Cetearyl methicone such that Bis (C13-15 Alkoxy) PG Amodimethicone and Cetearyl methicone are in a ratio of from about 1: 5 to about 5: 1, respectively.

In another aspect, the claimed invention relates to a hair dyeing composition based on cationic polymers and / or cationic surfactants comprising the hair conditioning composition of the invention.

The composition according to the invention may be a multiphase hair dyeing composition containing two or more phases placed separately from each other and mixed immediately prior to use, said hair conditioning composition being included in one of the phases of said multiphase composition.

The composition according to the invention may contain a hair conditioning composition according to the invention and further comprise cationic polymers and / or cationic surfactants selected from the group consisting of Quaternium-8, Quaternium-14, Quaternium-15, Quaternium-18, Quaternium-22, Quaternium-24 , Quaternium-26, Quaternium-27, Quaternium-30, Quaternium-33, Quaternium-53, Quaternium-60, Quaternium-61, Quaternium-72, Quaternium-78, Quaternium-81, Quaternium-82, Quaternium-83 -84, Polyquaternium-1, Polyquaternium-2, Polyquaternium-4, Polyquaternium-5, Polyquaternium-6, Polyquaternium-8, Polyquaternium-9, Polyquaternium-10, Polyquaternium-11, Polyquaternium-12-13, Polyquaternium , Polyquaternium-15, Polyquaternium-16, Polyquaternium-17, Polyquaternium-18, Polyquaternium-19, Polyquaternium-20, Polyquaternium-22, Polyquaternium-24, Polyquaternium-27, Polyquaternium-28, Polyquaternium-30, Poliquaternium -31, Polyquaternium-32, Polyquaternium-33, Polyquaternium-34, Polyquaternium-35, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-45, Polyquaternium-46, Polyquaternium-47, Polyquaternium-48, Polyquaternium-49, Polyquaternium 50, Polyquaternium-55, Poliquaternium-55 Chloride, Lauroyl PG-Trimonium chloride, Begenoil PG-Trimonium chloride, quaternized silicones, quaternized xanthan gum or guar gum.

The composition of the invention may be in a creamy form.

In yet another aspect, the claimed invention relates to the use of a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Polyquaternium-7 for conditioning hair in hair coloring compositions based on cationic polymers and / or cationic surfactants. Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Polyquaternium-7 can be in a ratio of from about 1: 1: 10 to about 10: 10: 1.

In yet another aspect, the claimed invention relates to the use of a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Quaternium-70 for conditioning hair in hair dye compositions based on cationic polymers and / or cationic surfactants. Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Quaternium-70 can be in a ratio of from about 1: 1: 30 to about 10: 10: 1.

In yet another aspect, the claimed invention relates to the use of a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone, Polyquaternium-7 and Quaternium-70 for conditioning hair in hair dye formulations based on cationic polymers and / or cationic surfactants. Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone, Polyquaternium-7 and Quaternium-70 can be in a ratio of from about 1: 1: 10: 30 to about 10: 10: 1: 1.

The claimed invention provides the following technical results: hair conditioning during dyeing, maintaining the aesthetic beauty of hair during and after dyeing, maintaining hair smoothness during dyeing and after it. In addition, from the essence of the present disclosure, including the following detailed description of the invention and examples containing data obtained during experiments, specialists in this field will be obvious additional advantages provided by the claimed invention, even if they were not specifically indicated, but unambiguously follow from the analysis the results obtained.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 shows the results of the study in percent.

DETAILED DESCRIPTION OF THE INVENTION

The invention relates to the cosmetic industry, namely the production of compositions for hair dyeing.

In one aspect, the claimed invention relates to a hair conditioning composition (s) for use in hair dye formulations based on cationic polymers and / or cationic surfactants containing a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Polyquaternium-7 in a ratio of approximately 1: 1: 10 to 10: 10: 1 or from 1: 1: 10 to 10: 10: 1. In this case, the ratio of Bis (C13-15 Alkoxy) PG Amodimethicone and Amodimethicone can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8 , 1: 9, 1:10, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10:10, or any intermediate value within the specified range. In this case, the ratio of Amodimethicone and Polyquaternium-7 can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8, 1: 9, 1 : 10, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10:10, or any value in between in the specified range. In this case, the ratio of Bis (C13-15 Alkoxy) PG Amodimethicone and Polyquaternium-7 can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1 : 8, 1: 9, 1:10, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10: 10, or any intermediate value within the specified range.

Bis (C13-15 Alkoxy) PG Amodimethicone (INCI: Bis (C13-15 Alkoxy) PG Amodimethicone) is a commercially available product and can be provided, for example, under the trade name DOWSIL ™ 8500 from the manufacturer DOW.

Amodimethicone (INCI: Amodimethicone) is a commercially available product and can be provided, for example, under the trade name DOW CORNING® 2-8566 from the manufacturer DOW.

Polyquaternium-7 (INCI: Polyquaternium-7) is a commercially available product and can be provided, for example, under the trade name PQ-7 from the manufacturer Zhejiang Xinhaitian Bio-Teachnology

Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Polyquaternium-7 may be present in a percentage, preferably about 19:19:62 or 19:19:62, based on the sum of their weights.

In one aspect, the claimed invention relates to a hair conditioning composition (s) for use in hair dyeing compositions based on cationic polymers and / or cationic surfactants containing a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Quaternium-70 in a ratio of approximately 1: 1: 30 to 10: 10: 1 or from 1: 1: 30 to 10: 10: 1. In this case, the ratio of Bis (C13-15 Alkoxy) PG Amodimethicone and Amodimethicone can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8 , 1: 9, 1:10, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10:10, or any intermediate value within the specified range. In this case, the ratio of Amodimethicone and Quaternium-70 can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8, 1: 9, 1 : 10, and so on until 1:30, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10: 10, and so on up to 10:30, or any value in between. In this case, the ratio of Bis (C13-15 Alkoxy) PG Amodimethicone and Quaternium-70 can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1 : 8, 1: 9, 1:10, and so on up to 1:30, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10:10, and so on up to 10:30, or any value in between.

Quaternium-70 (INCI: Quaternium-70) is a commercially available product and can be provided, for example, under the trade name Ceraphyl ™ 70 from the manufacturer Ashland.

Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Quaternium-70 may be present in a percentage, preferably about 33:33:34 or 33:33:34 based on the sum of their weights.

In one aspect, the claimed invention relates to a hair conditioning composition (s) for use in hair dyeing compositions based on cationic polymers and / or cationic surfactants containing a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone, Polyquaternium-7 and Quaternium-70 in a ratio of approximately 1: 1: 10: 30 to 10: 10: 1: 1. In this case, the ratio of Bis (C13-15 Alkoxy) PG Amodimethicone and Amodimethicone can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8 , 1: 9, 1:10, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10:10, or any intermediate value within the specified range. In this case, the ratio of Amodimethicone and Polyquaternium-7 can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8, 1: 9, 1 : 10, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10:10, or any value in between in the specified range. In this case, the ratio of Polyquaternium-7 and Quaternium-70 can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8, 1: 9 , 1:10 and so on up to 1:30, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10:10, and so on up to 10:30, or any value in between. In this case, the ratio of Amodimethicone and Quaternium-70 can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8, 1: 9, 1 : 10, and so on until 1:30, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10: 10, and so on up to 10:30, or any value in between. In this case, the ratio of Bis (C13-15 Alkoxy) PG Amodimethicone and Quaternium-70 can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1 : 8, 1: 9, 1:10, and so on up to 1:30, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8, 10: 9, 10:10, and so on up to 10:30, or any value in between.

Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone, Polyquaternium-7 and Quaternium-70 can be present in a percentage, preferably about 16: 16: 51: 17 or 16: 16: 51: 17, based on the sum of their weights.

The claimed invention also relates to a composition further comprising Behentrimonium chloride such that Bis (C13-15 Alkoxy) PG Amodimethicone and Behentrimonium chloride are in a ratio of approximately or exactly from 1:30 to 10: 1, respectively. In this case, the ratio of Bis (C13-15 Alkoxy) PG Amodimethicone and Begentrimonium chloride can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8, 1: 9, 1:10 and so on up to 1:30, or 10: 1, 10: 2, 10: 3, 10: 4, 10: 5, 10: 6, 10: 7, 10: 8 , 10: 9, 10:10, and so on up to 10:30, or any value in between.

Behentrimonium Chloride (Behentrimonium Chloride, Behentrimonium Chloride; INCI: Behentrimonium Chloride) is a commercially available product and can be provided, for example, under the trade name QUARTAMIN® AB from the manufacturer KAO Chemicals.

The claimed invention also relates to a composition further comprising Cetearyl methicone such that Bis (C13-15 Alkoxy) PG Amodimethicone and Cetearyl methicone are in a ratio of approximately or exactly from 1: 5 to 5: 1, respectively. In this case, the ratio of Bis (C13-15 Alkoxy) PG Amodimethicone and Cetearyl methicone can be approximately or exactly 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, or 5: 1, 5: 2, 5 : 3, 5: 4, 5: 5, or any value in between within the specified range.

Cetearyl Methicone (Cetearylmethicone, INCI: Cetearyl Methicone) is a commercially available product and can be provided, for example, under the trade name SF1632 from the manufacturer Momentive Performance Materials.

In another aspect, the claimed invention relates to a hair coloring composition, such as a hair coloring composition based on cationic polymers and / or cationic surfactants, or another type of hair coloring composition, comprising the hair conditioning composition of the invention.

The hair conditioning composition according to the invention may be present in the hair dyeing composition in an amount of 17.5% by weight. relative to the weight of the finished product.

The claimed invention also relates to a composition for dyeing hair, which may further comprise:

• Fatty alcohols, for example, cetyl, stearyl alcohols and others, as well as their mixtures;

• Fatty acids, their amides and esters, for example, stearic, oleic acids, their functional derivatives and others, as well as their mixtures;

• Anionic surfactants, for example, sodium lauryl sulfate, sodium laureth sulfate and others, as well as mixtures thereof;

• Nonionic surfactants, for example, glyceryl laurate, oxyethylated fatty alcohols and others, as well as mixtures thereof;

• Amphoteric surfactants, for example, cocamidopropyl betaine, cocamidopropyl laurate and others, as well as mixtures thereof;

• Hydrophilic and hydrophobic silicones and polymers based on them;

• Vegetable oils, for example, almond, peach, mustard and others, as well as their mixtures;

• Waxes, eg beeswax, rose wax and others, as well as mixtures thereof;

• Gelling and structuring agents, for example xanthan, gellan, guar gums, starch, modified polysaccharides and others, as well as mixtures thereof;

• Preservatives common for cosmetic use;

• Antioxidants, for example, sodium sulfite, isoascorbate atrium, sodium dithionite and others, as well as mixtures thereof;

• Dyes, both direct and precursors of oxidation dyes, and pigments common to hair dyes;

• Alkalizing agents such as ammonia, aminomethylpropanol, secondary and tertiary amines, mono-, di- and triethanolamine and others, as well as mixtures thereof;

• Fragrances and aromatic compositions common in the cosmetic industry;

• Polymers for styling and other decorative purposes, for example, polyvinylpyrrolidone, acrylate polymers of various structures and others, as well as their mixtures;

• Means that improve the condition of hair during coloring, for example, 1,2-ethylenediamine, 1,6-hexanediamine and others, as well as their mixtures;

• Organic oils such as mineral oil, isopropyl myristate, isopropyl palmitate and others, and mixtures thereof.

The hair dye composition can be in the form of a cream, cream gel, direct or inverse emulsion, gel, spray, aerosol spray, aerosol mousse, etc.

The claimed invention also relates to a hair dyeing composition, wherein said composition is a multiphase hair dyeing composition containing two or more phases, placed separately from each other and mixed immediately before use, said hair conditioning composition being included in one of the phases of such a multiphase composition.

The claimed invention also relates to a hair dyeing composition containing a hair conditioning composition according to the invention and additionally containing cationic polymers and / or cationic surfactants selected from the group consisting of Quaternium-8, Quaternium-14, Quaternium-15 Quaternium-18, Quaternium -22, Quaternium-24, Quaternium-26, Quaternium-27, Quaternium-30, Quaternium-33, Quaternium-53, Quaternium-60, Quaternium-61, Quaternium-72, Quaternium-78, Quaternium-81, Quaternium-81 , Quaternium-83, Quaternium-84, Polyquaternium-1, Polyquaternium-2, Polyquaternium-4, Polyquaternium-5, Polyquaternium-6, Polyquaternium-8, Polyquaternium-9, Polyquaternium-10, Poliquaternium-11 -13, Polyquaternium-14, Polyquaternium-15, Polyquaternium-16, Polyquaternium-17, Polyquaternium-18, Polyquaternium-19, Polyquaternium-20, Polyquaternium-22, Polyquaternium-24, Polyquaternium-29, Polyquaternium-29 , Polyquaternium-30, Polyquaternium-31, Polyquate Rnium-32, Polyquaternium-33, Polyquaternium-34, Polyquaternium-35, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-45, Polyquaternium-46, Polyquaternium-47, Poliquaternium-48, Poliquaternium-49 Polyquaternium-55, Polyquaternium-56, Cetrimonium chloride, Steatrimonium Chloride, Lauroyl PG-Trimonium chloride, Begenoyl PG-Trimonium chloride, quaternized silicones quaternized with xanthan gum or guar gum, Quaternium-14 Quaternium-22, Quaternium-24, Quaternium-26, Quaternium-27, Quaternium-30, Quaternium-33, Quaternium-53, Quaternium-60, Quaternium-61, Quaternium-72, Quaternium-78, Quaternium-81, Quaternium- 82, Quaternium-83, Quaternium-84, Polyquaternium-1, Polyquaternium-2, Polyquaternium-4, Polyquaternium-5, Polyquaternium-6, Polyquaternium-7, Polyquaternium-8, Polyquaternium-9, Polyquaternium-10, Polyquaternium-11, Polyquaternium-12, Polyquaternium-13, Polyquaternium-14, Polyquaternium-15, Polyquaternium-16, Polyquaternium-17, Polyquaternium-18, Polyquaternium-19, Polyquaternium-20, Polyquaternium-22, Polyquaternium-24, Polyquaternium-27, Polyquaternium-28, Polyquaternium-29, Polyquaternium-30, Polyquaternium-31, Polyquaternium-30, Polyquaternium-31, Polyquaternium-30 32, Polyquaternium-33, Polyquaternium-34, Polyquaternium-35, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-45, Polyquaternium-46, Polyquaternium-47, Polyquaternium-48, Polyquaternium-49, Polyquaternium- 55, Polyquaternium-56, Cetrimonium Chloride, Steartrimonium Chloride, Lauroyl PG-Trimonium Chloride, Behenoil PG-Trimonium Chloride).

The claimed invention also relates to a composition for dyeing hair, characterized in that it is in a creamy form.

In yet another aspect, the claimed invention relates to the use of a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Polyquaternium-7 for conditioning hair in hair coloring compositions based on cationic polymers and / or cationic surfactants.

The claimed invention also relates to the use of a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Polyquaternium-7 for hair conditioning in compositions (agents, compositions, preparations) for dyeing hair (hair dyes) based on cationic polymers and / or cationic Surfactant, where Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Polyquaternium-7 are in a ratio from about 1: 1: 10 to about 10: 10: 1. Such a hair conditioning composition can be purposefully incorporated into hair coloring compositions, such as hair coloring compositions based on cationic polymers and / or cationic surfactants, in order to achieve the results described in the present disclosure.

In yet another aspect, the claimed invention relates to the use of a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Quaternium-70 for conditioning hair in hair dye compositions based on cationic polymers and / or cationic surfactants.

The claimed invention also relates to the use of a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Quaternium-70 for hair conditioning in formulations (agents, compositions, preparations) for dyeing hair (hair dyes) based on cationic polymers and / or cationic Surfactant, where Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Quaternium-70 are in a ratio of from about 1: 1: 30 to about 10: 10: 1. Such a hair conditioning composition can be purposefully incorporated into hair coloring compositions, such as hair coloring compositions based on cationic polymers and / or cationic surfactants, in order to achieve the results described in the present disclosure.

In yet another aspect, the claimed invention relates to the use of a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone, Polyquaternium-7 and Quaternium-70 for conditioning hair in compositions (agents, compositions, preparations) for dyeing hair (hair dyes) on based on cationic polymers and / or cationic surfactants.

The claimed invention also relates to the use of a combination of Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone, Polyquaternium-7 and Quaternium-70 for hair conditioning in hair dye compositions based on cationic polymers and / or cationic surfactants, where Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone, Polyquaternium-7 and Quaternium-70 are in a ratio of about 1: 1: 10: 30 to about 10: 10: 1: 1. Such a hair conditioning composition can be purposefully incorporated into hair coloring compositions, such as hair coloring compositions based on cationic polymers and / or cationic surfactants, in order to achieve the results described in the present disclosure.

The invention is aimed at providing solutions that have certain advantages in relation to the solutions of the prior art and related to: 1) solving the problems of conditioning hair during coloring, and / or 2) maintaining the aesthetic beauty of hair during and after coloring, and / or 3) maintaining smoothness of hair during and after dyeing, and / or the achievement of the absence of "fluffing" hair and other known to specialists in this field of negative effects manifested when dyeing hair permanent and semi-permanent, if cationic surfactants and polymers are used. In addition, the proposed solution is designed to 4) expand the range of products available to the end consumer.

Examples of

Example 1 General Method for Preparing Hair Conditioning Compositions of the Invention

Polyquaternium-7 is dispersed in the estimated minimum amount of water. Quaternium-70, behentrimonium chloride, cetearylmethicone, Bis (C13-15 Alkoxy) PG Amodimethicone, Amodimethicone are mixed, heated until melted and stirred for 75 minutes. Add a dispersion of polyquaternium-7, mix for 30 minutes. Then, to the resulting hair conditioning composition according to the invention, cocamide MEA, lanolin, PEG-40 hydrogenated castor oil, ceteareth-30, rose wax, carnauba wax are added, mixed until complete homogenization and a fat phase is obtained.

Example 2. General method of preparation of compositions for dyeing hair based on cationic polymers and / or cationic surfactants

The calculated amount of water is heated to 45-50 ° C, salts are added - sodium erythorbate, sodium sulfite, sodium hydrosulfite, tetrasodium salt of ethylenediaminetetraacetic acid. The solution is stirred at this temperature for 30 minutes, after which ethoxydiglycol, propylene glycol, dyes, mica, titanium dioxide are loaded, argon is supplied, heated to 75 ° C and held for 60 minutes.

The fat phase is mixed with an aqueous solution of dyes at a temperature of 65-75 ° C, kept for 30 minutes, then cooled to a temperature of 40 ° C and a perfume composition, a preservative, ammonium hydroxide, a 25% solution and aminomethylpropanol are added. The composition is stirred for 30 minutes, after which a sample is taken for analysis. In case of positive results of the analysis for compliance with the regulatory and technical documentation, the finished product is packaged in tubes.

Example 3.

3.1 10 grams of Polyquaternium-7 is dispersed in the estimated minimum amount of water. Mix 1 gram of Bis (C13-15 Alkoxy) PG Amodimethicone and 1 gram of Amodimethicone, heat to 45 ° C and stir for 75 minutes. The dispersion of Polyquaternium-7 is added, stirred for 30 minutes, and cooled.

The results of combing hair test are presented in Table 1. As a control, a hair dye without a composition according to the invention was used.

Table 1

° Dry combing Wet combing Composition according to the invention 0.72 N 0.96H The control 1.13 N 1.61 N

3.2 1 gram of Polyquaternium-7 is dispersed in the estimated minimum amount of water. 10 grams of Bis (C13-15 Alkoxy) PG Amodimethicone and 10 grams of Amodimethicone are mixed, heated to 45 ° C and stirred for 75 minutes. The dispersion of Polyquaternium-7 is added, stirred for 30 minutes, and cooled.

The results of combing hair test are presented in Table 2. As a control, a hair dye without a composition according to the invention was used.

table 2

° Dry combing Wet combing Composition according to the invention 0.69 N 0.81 N The control 1.13 N 1.64 N

3.3 30 grams of Quaternium-70, 1 gram of Bis (C13-15 Alkoxy) PG of Amodimethicone and 1 gram of Amodimethicone are mixed, heated to 65 ° C and stirred for 65 minutes, cooled.

The results of combing hair test are presented in Table 3. As a control, a hair dye was used without the composition according to the invention.

Table 3

° Dry combing Wet combing Composition according to the invention 0.88 N 1.01 N The control 1.13 N 1.61 N

3.4 1 gram of Quaternium-70, 10 grams of Bis (C13-15 Alkoxy) PG of Amodimethicone and 10 grams of Amodimethicone are mixed, heated to 65 ° C and stirred for 65 minutes, cooled.

The results of combing hair test are presented in Table 4. As a control, a hair dye was used without the composition according to the invention.

Table 4

° Dry combing Wet combing Composition according to the invention 0.76 N 0.94 N The control 1.13 N 1.64 N

3.5 10 grams of Polyquaternium-7 is dispersed in the estimated minimum amount of water. 30 grams of Quaternium-70, 1 gram of Bis (C13-15 Alkoxy) PG of Amodimethicone and 1 gram of Amodimethicone are mixed, heated to 65 ° C and stirred for 75 minutes. The dispersion of Polyquaternium-7 is added, stirred for 30 minutes, and cooled.

The results of combing hair test are presented in Table 5. As a control, a hair dye without a composition according to the invention was used.

Table 5

° Dry combing Wet combing Composition according to the invention 0.68 N 0.77 N The control 1.13 N 1.61 N

3.6 1 gram of Polyquaternium-7 is dispersed in the estimated minimum amount of water. 1 gram of Quaternium-70, 10 grams of Bis (C13-15 Alkoxy) PG of Amodimethicone and 10 grams of Amodimethicone are mixed, heated to 65 ° C and stirred for 75 minutes. The dispersion of Polyquaternium-7 is added, stirred for 30 minutes, and cooled.

The results of combing hair test are presented in Table 6. As a control, a hair dye was used without the composition according to the invention.

Table 6

° Dry combing Wet combing Composition according to the invention 0.63 N 0.77 N The control 1.13 N 1.64 N

Example 4 Typical Formulation Examples of Hair Conditioning Compositions of the Invention (see Table 7).

Table 7

Composition No. 1 Composition No. 2 Composition No. 3 Option 1 2 3 1 2 3 1 2 3 Bis (C13-15 alkoxy) PG Amodimethicone 19 40 7 fifteen 45 33 fourteen sixteen 22 Amodimethicone 19 40 35 45 45 33 17 sixteen 4 Polyquaternium-7 62 20 58 - - - 52 51 50 Quaternium-70 - - - 40 ten 34 eighteen 17 24

The quantitative characteristic of hair conditioning is the relative brushing effort - peak and total effort. The peak load is used in multiple tests and is the maximum total load in the series, so to confirm the results we limited the total load averaged over 20 experiments.

Determination of brushing forces for dry hair (total load) was performed using a Dia-Stron MTT-160 load analyzer at room temperature and a constant 65% relative humidity. The determination of the forces when brushing wet hair (total load) was carried out at room temperature.

The base coloring composition was used as a control, without the composition according to the invention being included therein. Composition 1 - Option 1 of Composition 1; composition 2 - option 3 of composition 2, composition 3 - option 2 of composition 3. The result of the study is shown in FIG. 1 in percent, relative to shampooed hair without the use of a coloring composition. This is the industry standard: do a calibration test on hair washed with shampoo and take the force, measured in Newtons, as the base. Then, the hair treated with the sample compositions is tested and the percentage of control is calculated:

OU = (UO-UK) / UK * 100%,

where OU is the relative effort when combing,%

UO - sample force, N,

UK - control effort, N.

Claims (9)

1. Application of a combination of Bis (C _13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Polyquaternium-7 in a mass ratio of 1: 1: 10 to approximately 10: 10: 1 for hair conditioning in hair dye compositions based on cationic polymers and / or cationic surfactants. 2. Use according to claim 1, wherein the combination further comprises Cetearyl methicone such that Bis (C _13-15 Alkoxy) PG Amodimethicone and Cetearyl methicone are in a weight ratio of 1: 5 to 5: 1. 3. Use according to claim 1 or 2, wherein the combination further comprises Begentrimonium chloride, so that Bis (C _13-15 Alkoxy) PG Amodimethicone and Begentrimonium chloride are in a weight ratio of 1:30 to 10: 1. 4. Application of a combination of Bis (C _13-15 Alkoxy) PG Amodimethicone, Amodimethicone and Quaternium-70 in a mass ratio from 1: 1: 30 to 10: 10: 1 for hair conditioning in hair dye compositions based on cationic polymers and / or cationic surfactants. 5. Use according to claim 4, wherein the combination further comprises Cetearyl methicone such that Bis (C _13-15 Alkoxy) PG Amodimethicone and Cetearyl methicone are in a weight ratio of 1: 5 to 5: 1. 6. Use according to claim 4 or 5, wherein the combination further comprises Behentrimonium chloride such that Bis (C _13-15 Alkoxy) PG Amodimethicone and Begentrimonium chloride are in a weight ratio of 1:30 to 10: 1. 7. Application of a combination of Bis (C _13-15 Alkoxy) PG Amodimethicone, Amodimethicone, Polyquaternium-7 and Quaternium-70 in a mass ratio from 1: 1: 10: 30 to 10: 10: 1: 1 for conditioning hair in dye formulations hair based on cationic polymers and / or cationic surfactants. 8. Use according to claim 7, wherein the combination further comprises Cetearyl methicone such that Bis (C _13-15 Alkoxy) PG Amodimethicone and Cetearyl methicone are in a weight ratio of 1: 5 to 5: 1. 9. Use according to claim 7 or 8, wherein the combination further comprises Behentrimonium chloride such that Bis (C _13-15 Alkoxy) PG Amodimethicone and Begentrimonium chloride are in a weight ratio of 1:30 to 10: 1.

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