RU2687947C1 - Фильтрующая среда для защиты органов дыхания, содержащая допированный железом оксид марганца - Google Patents
Фильтрующая среда для защиты органов дыхания, содержащая допированный железом оксид марганца Download PDFInfo
- Publication number
- RU2687947C1 RU2687947C1 RU2018105344A RU2018105344A RU2687947C1 RU 2687947 C1 RU2687947 C1 RU 2687947C1 RU 2018105344 A RU2018105344 A RU 2018105344A RU 2018105344 A RU2018105344 A RU 2018105344A RU 2687947 C1 RU2687947 C1 RU 2687947C1
- Authority
- RU
- Russia
- Prior art keywords
- iron
- manganese
- manganese oxide
- material based
- range
- Prior art date
Links
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 title claims abstract description 114
- 230000000241 respiratory effect Effects 0.000 title claims abstract description 23
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 111
- 239000000463 material Substances 0.000 claims abstract description 63
- 238000000034 method Methods 0.000 claims abstract description 53
- 229910052742 iron Inorganic materials 0.000 claims abstract description 50
- 239000007864 aqueous solution Substances 0.000 claims abstract description 15
- 231100001261 hazardous Toxicity 0.000 claims abstract description 11
- 239000011148 porous material Substances 0.000 claims abstract description 8
- 238000004438 BET method Methods 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 37
- 239000008187 granular material Substances 0.000 claims description 36
- 239000002244 precipitate Substances 0.000 claims description 34
- 150000003839 salts Chemical class 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims description 18
- 238000001914 filtration Methods 0.000 claims description 18
- 239000011572 manganese Substances 0.000 claims description 16
- FFSSRHVDYWHLLV-UHFFFAOYSA-J iron(2+) manganese(2+) oxalate Chemical compound C(C(=O)[O-])(=O)[O-].[Fe+2].[Mn+2].C(C(=O)[O-])(=O)[O-] FFSSRHVDYWHLLV-UHFFFAOYSA-J 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 claims description 8
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 7
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 4
- 239000007789 gas Substances 0.000 abstract description 28
- 238000005979 thermal decomposition reaction Methods 0.000 abstract description 5
- 238000000975 co-precipitation Methods 0.000 abstract description 4
- 150000003891 oxalate salts Chemical group 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 16
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 229910021529 ammonia Inorganic materials 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000010949 copper Substances 0.000 description 7
- 239000002250 absorbent Substances 0.000 description 6
- 230000002745 absorbent Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000011833 salt mixture Substances 0.000 description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- -1 for example Substances 0.000 description 2
- UXKUODQYLDZXDL-UHFFFAOYSA-N fulminic acid Chemical compound [O-][N+]#C UXKUODQYLDZXDL-UHFFFAOYSA-N 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- CESXSDZNZGSWSP-UHFFFAOYSA-L manganese(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Mn+2].CC([O-])=O.CC([O-])=O CESXSDZNZGSWSP-UHFFFAOYSA-L 0.000 description 2
- ISPYRSDWRDQNSW-UHFFFAOYSA-L manganese(II) sulfate monohydrate Chemical compound O.[Mn+2].[O-]S([O-])(=O)=O ISPYRSDWRDQNSW-UHFFFAOYSA-L 0.000 description 2
- 230000002572 peristaltic effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052594 sapphire Inorganic materials 0.000 description 2
- 239000010980 sapphire Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 239000005749 Copper compound Substances 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- VDNXILQBKLFION-UHFFFAOYSA-N [K].[Cu] Chemical compound [K].[Cu] VDNXILQBKLFION-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- PUFKGWVZPFANLN-UHFFFAOYSA-N dioxomanganese oxocopper Chemical compound O=[Cu].O=[Mn]=O PUFKGWVZPFANLN-UHFFFAOYSA-N 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- SZQUEWJRBJDHSM-UHFFFAOYSA-N iron(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O SZQUEWJRBJDHSM-UHFFFAOYSA-N 0.000 description 1
- YHGPYBQVSJBGHH-UHFFFAOYSA-H iron(3+);trisulfate;pentahydrate Chemical compound O.O.O.O.O.[Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O YHGPYBQVSJBGHH-UHFFFAOYSA-H 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000005078 molybdenum compound Substances 0.000 description 1
- 150000002752 molybdenum compounds Chemical class 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B19/00—Cartridges with absorbing substances for respiratory apparatus
- A62B19/02—Cartridges with absorbing substances for respiratory apparatus with oxidising agents
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B19/00—Cartridges with absorbing substances for respiratory apparatus
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B23/00—Filters for breathing-protection purposes
- A62B23/02—Filters for breathing-protection purposes for respirators
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D9/00—Composition of chemical substances for use in breathing apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B01J20/0229—Compounds of Fe
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
- B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3007—Moulding, shaping or extruding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3021—Milling, crushing or grinding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3028—Granulating, agglomerating or aggregating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3035—Compressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/02—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
- B01D2253/1124—Metal oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/25—Coated, impregnated or composite adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/306—Surface area, e.g. BET-specific surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/308—Pore size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/704—Solvents not covered by groups B01D2257/702 - B01D2257/7027
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4541—Gas separation or purification devices adapted for specific applications for portable use, e.g. gas masks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0415—Beds in cartridges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/42—Materials comprising a mixture of inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Pulmonology (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Separation Of Gases By Adsorption (AREA)
- Compounds Of Iron (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562201691P | 2015-08-06 | 2015-08-06 | |
| US62/201,691 | 2015-08-06 | ||
| PCT/US2016/045514 WO2017024116A2 (en) | 2015-08-06 | 2016-08-04 | Filter media for respiratory protection |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2687947C1 true RU2687947C1 (ru) | 2019-05-16 |
Family
ID=56802667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2018105344A RU2687947C1 (ru) | 2015-08-06 | 2016-08-04 | Фильтрующая среда для защиты органов дыхания, содержащая допированный железом оксид марганца |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10806954B2 (https=) |
| EP (1) | EP3331632B1 (https=) |
| JP (1) | JP2018532442A (https=) |
| KR (1) | KR20180037995A (https=) |
| CN (1) | CN107921352B (https=) |
| AU (1) | AU2016301347B2 (https=) |
| BR (1) | BR112018002519A2 (https=) |
| CA (1) | CA2994821A1 (https=) |
| CL (1) | CL2018000342A1 (https=) |
| RU (1) | RU2687947C1 (https=) |
| WO (1) | WO2017024116A2 (https=) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210370218A1 (en) * | 2020-05-29 | 2021-12-02 | Hollingsworth & Vose Company | Filter media comprising adsorptive particles |
| CN115850343B (zh) * | 2022-11-22 | 2025-10-21 | 南华大学 | 一种三草酸根合锰(ⅲ)酸铵的合成方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2154525C1 (ru) * | 1999-08-25 | 2000-08-20 | Закрытое акционерное общество "Сорбент-Центр Внедрение" | Адсорбент для средств защиты органов дыхания |
| RU2221627C1 (ru) * | 2002-09-17 | 2004-01-20 | Институт катализа им. Г.К. Борескова СО РАН | Поглотитель диоксида углерода, способ его получения (варианты), способ его регенерации, способ удаления диоксида углерода из газовых смесей, способ паровой или парокислородной конверсии углеводородов, способ паровой конверсии оксида углерода, способ запасания или выделения тепловой энергии с использованием поглотителя |
| WO2005005020A2 (en) * | 2003-06-26 | 2005-01-20 | 3M Innovative Properties Company | Broad spectrum filter system including tungsten-based impregnant and being useful for filtering contaminants from air or other gases |
| US20050074380A1 (en) * | 2003-07-31 | 2005-04-07 | Boren Richard M. | Metal oxide processing methods and systems |
| US20070086935A1 (en) * | 2005-10-14 | 2007-04-19 | Huimin Chen | Water treatment compositions and methods of making and using |
| US20120024799A1 (en) * | 2005-10-14 | 2012-02-02 | Inframat Corporation | Nanostructured Compositions Having Reduced Dissolution of manganese and methods of making and using the same |
| WO2014141198A1 (en) * | 2013-03-14 | 2014-09-18 | Johnson Matthey Public Limited Company | Cerium-modified manganese octahedral molecular sieves as catalysts for selective catalytic reduction |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3671606A (en) | 1969-10-02 | 1972-06-20 | Petro Tex Chem Corp | Oxidative dehydrogenation utilizing manganese ferrite |
| US4832926A (en) | 1985-11-08 | 1989-05-23 | Figgie International Inc. | Chlorine gas filtering material suitable for use in a chemical oxygen generator and method of making |
| WO1995025693A1 (en) | 1994-03-21 | 1995-09-28 | Texaco Development Corporation | Framework metal-substituted manganese oxide octahedral molecular sieve and process for its preparation |
| US5578282A (en) | 1994-11-07 | 1996-11-26 | Texaco Inc. | Octahedral molecular sieve possessing (4×4) tunnel structure and method of its production |
| LU90314B1 (de) | 1998-11-05 | 2000-05-08 | Wurth Paul Sa | Verfahren zum Herstellen von direkt reduziertem entschwefeltem Eisen |
| US6855297B2 (en) | 1998-11-16 | 2005-02-15 | Honeywell International Inc. | NOx filter |
| US6503476B1 (en) | 1999-07-23 | 2003-01-07 | The University Of Connecticut | Manganese oxide helices, rings, strands, and films, and methods for their preparation |
| US20030135082A1 (en) | 1999-09-22 | 2003-07-17 | Lixin Cao | Destruction of organophosphonate compounds |
| US20040106517A1 (en) * | 2000-05-23 | 2004-06-03 | Dlamini Thulani Humphrey | Chemicals from synthesis gas |
| JP3649996B2 (ja) | 2000-05-24 | 2005-05-18 | 三洋電機株式会社 | 非水電解質二次電池用正極活物質 |
| US7247279B2 (en) | 2000-08-01 | 2007-07-24 | Enviroscrub Technologies Corporation | System for removal of pollutants from a gas stream |
| US6610263B2 (en) | 2000-08-01 | 2003-08-26 | Enviroscrub Technologies Corporation | System and process for removal of pollutants from a gas stream |
| US7232782B2 (en) | 2002-03-06 | 2007-06-19 | Enviroscrub Technologies Corp. | Regeneration, pretreatment and precipitation of oxides of manganese |
| PL373791A1 (pl) | 2001-12-21 | 2005-09-19 | Enviroscrub Technologies Corporation | Sposób obróbki wstępnej i regeneracji tlenków manganu, zespół do wstępnej obróbki tlenków manganu, cząstki tlenków manganu otrzymane tym sposobem i placek filtracyjny z tlenków manganu |
| US20040101457A1 (en) * | 2002-06-11 | 2004-05-27 | Pahlman John E. | Disassociation processing of metal oxides |
| US20040007130A1 (en) * | 2002-07-11 | 2004-01-15 | Gislason Jason J. | Desulfurization and novel compositions for same |
| US20040152791A1 (en) | 2002-11-25 | 2004-08-05 | Zyl Andre Johan Van | Catalyst |
| WO2004067161A2 (en) | 2003-01-28 | 2004-08-12 | Enviroscrub Technologies Corporation | Oxides of manganese processed in continuous flow reactors |
| TWI453165B (zh) | 2006-06-14 | 2014-09-21 | Inframat Corp | 水處理組成物的製造方法 |
| US7585359B2 (en) * | 2006-12-27 | 2009-09-08 | J.M. Huber Corporation | Air filtration media comprising metal-doped silicon-based gel and/or zeolite materials treated with nitric acid and/or potassium persulfate |
| WO2009105406A2 (en) | 2008-02-21 | 2009-08-27 | 3M Innovative Properties Company | Adducts of amines and polycarboxylic acids, and filter media comprising such adducts |
| GB2457952A (en) | 2008-02-29 | 2009-09-02 | Nanotecture Ltd | Mesoporous particulate material |
| BR112013010543A2 (pt) * | 2010-11-03 | 2019-09-24 | Carus Corp | sorvente com base em manganês para a remoção de espécies de mercúrio de fluidos |
| US8585808B2 (en) | 2010-11-08 | 2013-11-19 | 3M Innovative Properties Company | Zinc oxide containing filter media and methods of forming the same |
| US8987160B2 (en) | 2011-03-26 | 2015-03-24 | Honda Motor Co., Ltd. | Fischer-tropsch catalysts containing iron or cobalt selective towards higher hydrocarbons |
| WO2012167280A1 (en) * | 2011-06-03 | 2012-12-06 | The Regents Of The University Of California | Manganese oxide and activated carbon fibers for removing particle, voc or ozone from a gas |
| US9908103B2 (en) * | 2012-09-25 | 2018-03-06 | University Of Connecticut | Mesoporous metal oxides and processes for preparation thereof |
| CN102861387A (zh) * | 2012-09-26 | 2013-01-09 | 泰安市金飞虹织造有限公司 | 一种交警用汽车尾气过滤口罩 |
| JP5884809B2 (ja) | 2013-11-01 | 2016-03-15 | トヨタ自動車株式会社 | 車両用大気浄化装置 |
| JP6188545B2 (ja) * | 2013-11-06 | 2017-08-30 | 共同印刷株式会社 | 硫化物系ガス吸着用積層体 |
| CN103691200A (zh) * | 2014-01-13 | 2014-04-02 | 魏耘 | 空气过滤介质材料、介质、过滤器及空气过滤方法 |
| CN104261479B (zh) * | 2014-09-28 | 2017-03-08 | 上海第二工业大学 | 一种金属掺杂纳米二氧化锰电极材料及其制备方法 |
| CN104549136A (zh) * | 2015-01-29 | 2015-04-29 | 江苏中翔网络科技有限公司 | 用于空气净化的过滤介质、滤芯、口鼻罩以及制备方法 |
-
2016
- 2016-08-04 EP EP16757758.4A patent/EP3331632B1/en active Active
- 2016-08-04 AU AU2016301347A patent/AU2016301347B2/en not_active Ceased
- 2016-08-04 BR BR112018002519A patent/BR112018002519A2/pt not_active Application Discontinuation
- 2016-08-04 WO PCT/US2016/045514 patent/WO2017024116A2/en not_active Ceased
- 2016-08-04 JP JP2018506134A patent/JP2018532442A/ja not_active Withdrawn
- 2016-08-04 KR KR1020187006102A patent/KR20180037995A/ko not_active Withdrawn
- 2016-08-04 CN CN201680046166.4A patent/CN107921352B/zh active Active
- 2016-08-04 US US15/749,820 patent/US10806954B2/en active Active
- 2016-08-04 CA CA2994821A patent/CA2994821A1/en not_active Abandoned
- 2016-08-04 RU RU2018105344A patent/RU2687947C1/ru not_active IP Right Cessation
-
2018
- 2018-02-06 CL CL2018000342A patent/CL2018000342A1/es unknown
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2154525C1 (ru) * | 1999-08-25 | 2000-08-20 | Закрытое акционерное общество "Сорбент-Центр Внедрение" | Адсорбент для средств защиты органов дыхания |
| RU2221627C1 (ru) * | 2002-09-17 | 2004-01-20 | Институт катализа им. Г.К. Борескова СО РАН | Поглотитель диоксида углерода, способ его получения (варианты), способ его регенерации, способ удаления диоксида углерода из газовых смесей, способ паровой или парокислородной конверсии углеводородов, способ паровой конверсии оксида углерода, способ запасания или выделения тепловой энергии с использованием поглотителя |
| WO2005005020A2 (en) * | 2003-06-26 | 2005-01-20 | 3M Innovative Properties Company | Broad spectrum filter system including tungsten-based impregnant and being useful for filtering contaminants from air or other gases |
| US20050074380A1 (en) * | 2003-07-31 | 2005-04-07 | Boren Richard M. | Metal oxide processing methods and systems |
| US20070086935A1 (en) * | 2005-10-14 | 2007-04-19 | Huimin Chen | Water treatment compositions and methods of making and using |
| US20120024799A1 (en) * | 2005-10-14 | 2012-02-02 | Inframat Corporation | Nanostructured Compositions Having Reduced Dissolution of manganese and methods of making and using the same |
| WO2014141198A1 (en) * | 2013-03-14 | 2014-09-18 | Johnson Matthey Public Limited Company | Cerium-modified manganese octahedral molecular sieves as catalysts for selective catalytic reduction |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3331632B1 (en) | 2020-11-25 |
| EP3331632A2 (en) | 2018-06-13 |
| CA2994821A1 (en) | 2017-02-09 |
| AU2016301347A1 (en) | 2018-03-01 |
| KR20180037995A (ko) | 2018-04-13 |
| US20180221692A1 (en) | 2018-08-09 |
| CN107921352B (zh) | 2021-06-25 |
| WO2017024116A2 (en) | 2017-02-09 |
| US10806954B2 (en) | 2020-10-20 |
| CL2018000342A1 (es) | 2018-05-25 |
| AU2016301347B2 (en) | 2019-03-07 |
| WO2017024116A3 (en) | 2017-03-16 |
| BR112018002519A2 (pt) | 2018-09-18 |
| JP2018532442A (ja) | 2018-11-08 |
| CN107921352A (zh) | 2018-04-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Sajjadi et al. | Implementation of magnetic Fe3O4@ ZIF-8 nanocomposite to activate sodium percarbonate for highly effective degradation of organic compound in aqueous solution | |
| Jin et al. | Nickel nanoparticles encapsulated in porous carbon and carbon nanotube hybrids from bimetallic metal-organic-frameworks for highly efficient adsorption of dyes | |
| Huang et al. | Effect of reduction treatment on structural properties of TiO 2 supported Pt nanoparticles and their catalytic activity for formaldehyde oxidation | |
| Alqadami et al. | Synthesis and characterization of Fe 3 O 4@ TSC nanocomposite: highly efficient removal of toxic metal ions from aqueous medium | |
| JP6345774B2 (ja) | アンモニア吸着材 | |
| Seredych et al. | Visible-light-enhanced interactions of hydrogen sulfide with composites of zinc (oxy) hydroxide with graphite oxide and graphene | |
| Alanis et al. | Photocatalytically enhanced Cr (VI) removal by mixed oxides derived from MeAl (Me: Mg and/or Zn) layered double hydroxides | |
| Beyki et al. | Dual application of facilely synthesized Fe 3 O 4 nanoparticles: fast reduction of nitro compound and preparation of magnetic polyphenylthiourea nanocomposite for efficient adsorption of lead ions | |
| Kwon et al. | Influence of attrition milling on V/Ti catalysts for the selective oxidation of ammonia | |
| Reyes-Vallejo et al. | Green synthesis of CaO-Fe₃O₄ composites for photocatalytic degradation and adsorption of synthetic dyes | |
| Pan et al. | Catalytic removal of phenol from gas streams by perovskite-type catalysts | |
| Konova et al. | Low-temperature ozone decomposition, CO and iso-propanol combustion on silver supported MCM-41 and silica | |
| RU2687947C1 (ru) | Фильтрующая среда для защиты органов дыхания, содержащая допированный железом оксид марганца | |
| Wang et al. | Preparation of Fe3O4 magnetic porous microspheres (MPMs) and their application in treating mercury-containing wastewater from the polyvinyl chloride industry by calcium carbide method | |
| Van Nguyen et al. | Mn-Doped material synthesized from red mud and rice husk ash as a highly active catalyst for the oxidation of carbon monoxide and p-xylene | |
| Zhang et al. | Synthesis and evaluation of activated carbon spheres with copper modification for gaseous elemental mercury removal | |
| Rochard et al. | MnOx‐loaded Mesoporous Silica for the Catalytic Oxidation of Formaldehyde. Effect of the Melt Infiltration Conditions on the Activity–Stability Behavior | |
| Winayu et al. | Styrene removal by low-temperature catalytic oxidation using Mn2O3/Al2SiO5 | |
| US11331645B2 (en) | Filter media for respiratory protection | |
| da Cunha et al. | Multifunctional Nb–Cu nanostructured materials as potential adsorbents and oxidation catalysts for real wastewater decontamination | |
| Tur | Investigations on the removal of elemental mercury from coal fired power plants gaseous emissions by catalytic oxidation | |
| Liu et al. | Novel efficient U–Cu/CSAC catalyst for selective reduction of NO at low temperatures: preparation, characterization, evaluation and mechanism | |
| Ali et al. | Synthesis and Characterization of AC@ Fe3O4 Nanocomposite and its Application as an Efficient Adsorbent for Removal of Some Heavy Metal Ions from Aqueous Solutions | |
| Shahzad et al. | KINETIC AND THERMODYNAMIC STUDIES FOR THE H2S ADSOPRTION USING TiO2 NANOMATERIALS | |
| Hudson et al. | Peroxydisulfate in MCM-48 silicas: powerful and clean materials for the removal of toxic gases |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20200805 |