RU2687429C1 - Liquid composition of irritant action for self-protection means (versions) - Google Patents

Abstract

FIELD: active protection devices.SUBSTANCE: invention relates to means of self-protection of the population, specifically to liquids with irritating action of non-lethal effect on human, used as a thrown mass of special-purpose cartridge, in particular, in aerosol spray can small-size of ASCS and ASCSP used in tubeless shooting devices for metered aerosol spraying of "DMAS" type, or pyromechanical cartridges used in devices "OSA", "Strazhnik". Liquid irritant composition contains at least one irritant, dimethyl sulphoxide and an organic solvent or a mixture of organic solvents. Dimethyl sulphoxide compound contains in a mixture with water, and as an organic solvent contains an oxygen-containing organic solvent with oxygen content of not less than 15 wt% and a boiling point of not less than 180 C, selected from a group of diatomic alcohols (glycols), polyglycols and mono- or diesters thereof, or a triatomic alcohol – glycerine and its mono- and diethers, or a mixture of said solvents in a different combination. Composition according to any of the versions may contain a dye and a thickener.EFFECT: composition has stable characteristics in the temperature range from -254 °C to +50 °C and throwing range of not less than 3 m, wherein combination of components provides possibility of controlling parameters of mixture on range and irritant effect.10 cl, 2 tbl, 22 ex

Description

The invention relates to the means of self-defense of the population, namely to liquids with irritant effects of non-lethal effects on humans, used as a projectile for throwing mass of a special purpose cartridge, in particular, in small-sized aerosol cans of BAM and BAMP type, used in tubeless shooting devices for metered aerosol spraying "IMPACT" or pyromechanical cartridges used in the devices "OCA", "Guard".

Known variants of the liquid composition irritant for self-defense (RF Patent No. 263,448, IPC C06D 7/00, Z. 10/19/2016, op. 10/30/2017). In a known liquid formulation, at least one irritant, thickener and organic solvent or a mixture of organic solvents are used, and as an organic solvent it contains glycerol triacetate or a mixture of tri-, di- and monoacetate glycerin with a glycerol triacetate content of at least 54 wt. % Alternatively, the composition also contains dimethyl sulfoxide (DMSO). The technical result of the invention is to increase the effectiveness of irritation, effective firing range, improve the production conditions of cartridges, equipped with a patented composition.

As a prototype, the selected liquid irritant composition for self-defense (RF Patent No. 2381205, IPC C06D 7/00, H. 07/14/2008, op. 10/02/2010) containing at least one irritant, thickener, dimethyl sulfoxide and organic solvent or a mixture of organic solvents in the following ratio, wt. %:

irritant 0.15 ÷ 4 organic solvent 23.5 ÷ 94.6 dimethyl sulfoxide 2 ÷ 35 thickener 1,4 ÷ 55

As an organic solvent or a mixture of organic solvents can be: monohydric alcohol - ethyl or isopropyl, a mixture of 1,1,5-trihydro-octafluorheptanol and 1,1,7-trihydrododecafluoroheptanol or propylene glycol. Most of these solvents tend to evaporate during the flight of droplets when throwing an irritant liquid, causing a decrease in efficiency due to a decrease in the proportion of the substance delivered to the target and a decrease in the throwing distance of the liquid formulation.

The objective of the invention was to improve the quality of the compositions, positively affecting the effectiveness of shots, as well as solve the problem of choosing the components of the mixture, due to the combination of which would provide the ability to control the parameters of the mixture range and irritant effects, including to comply with current legislation.

A large role in the effectiveness of self-defense, with the use of annoying recipes, is also played by the speed of the effects of the recipes, that is: the time from the moment the recipe hits the mucous membranes of the attacker until it is neutralized.

In solving this problem, as a result of research, it suddenly turned out that a whole group of oxygen-containing organic solvents with an oxygen content of at least 15 masses has a positive effect on the effective firing range. % and with a boiling point of at least 180 ° C, from the group of dihydric alcohols (glycols), polyglycols, and their simple mono- or diesters, or a trihydric alcohol - glycerin and its simple mono- and di-esters, or mixtures of these solvents in various combinations.

Studies have also shown that in this case, the irritating effect of the formulation is enhanced and accelerated when using dimethyl sulfoxide in a mixture with water or dimethyl sulfoxide in a mixture with water and α-propylene glycol.

Solvents of the found group are very resistant to water, unlike, for example, from esters, acetals and ketals. In particular, glycerol ester - triacetin (contains more than 15% by weight of oxygen, bp. 250 ° C), which is an excellent solvent for irritating formulations that do not contain water (see, for example, RF Patent 2634448) slowly decomposes ( hydrolyzed) with water to form acetic acid, which is unacceptable. Oxygen-containing organic liquids of the specified group of substances containing at least 15% of the mass. oxygen can not only dissolve the irritant, but also give homogeneous solutions with water in combination with DMSO within the limits specified in the claims. With a lower content of oxygen in the solvent (less than 15% of the mass.), As a rule, the mixture (formulation) is stratified into separate phases of different composition, from which the ballistic and irritating properties of the formulations deteriorate and (or) become unstable. A group of organic liquids containing at least 15% of the mass. Oxygen includes not only highly soluble, but also hardly soluble organic liquids in water, which, in combination with DMSO, are capable of dissolving the required amount of water. In addition, these organic solvents give a sharp jump in the freezing temperature decrease (freezing temperature depression) after mixing them with water and DMSO. This is an important factor in expanding the range of solvents because even solvents with a relatively high melting point (-10 ÷ + 20 ° C) become suitable for the preparation of irritating recipes. The freezing point of irritating formulations should be below -20 ° C.

When using the above organic solvents, there is no noticeable loss of water from the recipe drops when throwing it. Probably, water is retained in the formulation due to the polar interaction of water molecules with oxygen-containing groups of solvent molecules. And, probably due to this interaction with oxygen-containing groups of an organic solvent, the presence of water in the formulation, within the specified limits, has almost no negative effect on the throwing distance, despite the fact that the bale. water is known to be 100 ° C.

This problem is also solved due to a certain ratio of mixture components. In one embodiment, the ratio of components, wt.%, Is:

Irritant 0.1 ÷ 12.0 Oxygenated organic solvent 28.0 ÷ 90.0 Dimethyl sulfoxide 3,0 ÷ 40,0 Water 3.0 ÷ 25.0
In another embodiment (with α-propylene glycol as an additional booster and stifling accelerator) the ratio of components, wt.%, Is:
Irritant 0.1 ÷ 12.0
Oxygenated organic solvent 23.0 ÷ 80.0
Dimethyl sulfoxide 3,0 ÷ 40,0
Water 3.0 ÷ 25.0
α-Propylene glycol 10.0 ÷ 45.0

Water content less than 3 wt. % does not give a clear acceleration-enhancement of irritation, and with the masses. % water over 25% there is a separation of the liquid mixture into two separate liquid phases and (or) part of the irritant is precipitated, and there is also a noticeable decrease in the effective throwing range.

When used as a booster accelerator additionally α-propylene glycol, with its content of the masses. % less than 10, the effect of accelerating the enhancement of the irritant also becomes difficult to distinguish, and with masses. % α-propylene glycol over 45 is not observed, the effect of further enhancing-accelerating the burning ability, and the introduced excess α-propylene glycol performs the function of an oxygen-containing organic solvent.

When self-defense with the use of irritating substances, in some cases it is not enough effects of the formulation on the eyes, for example, when the attacker with glasses. In this case, the effectiveness of self-defense can be significantly increased due to the effect of the fine aerosol on the respiratory tract, while, as a rule, the throwing distance decreases. It was found that the relative amount of fine aerosol depends most of all on the boiling point of the solvent. The most suitable way to control the ballistic and irritating characteristics of water-based formulations is to use co-solvents - substances from the group of mono- and di-esters of glycols and (or) monohydric alcohols, and (or) ketones, or a mixture of these co-solvents in various combinations, with an oxygen content of at least 15 masses % and with a boiling point of less than 180 ° C. The lower the boiling point of the cosolvent (in the range from 78 to 179 ° C, see table 2) and the larger its mass fraction, the stronger the dispersion.

The probable need to reduce the maximum throwing range should not be ruled out, if the legislation introduces a restriction on the maximum throwing range in self-defense with these means.

As irritants, it is preferable to use low-toxic substances that act on pain receptors - "Algogen" (literally - causing pain). These are substances: CR (dibenz [b, f-1, 4-oxazepine), CH (1-methoxy-1,3,5-cycloheptatriene), OS (oleoresin capsicum) - red pepper extracts containing capsaicin, and their synthetic analogues - vanillum amide of pelargonic acid (VAPK, PAVA) and morpholide of pelargonic acid (IPC). A promising irritant is allylthioisocyanate - the active ingredient of mustard. This low toxic substance can easily be obtained synthetically. Unlike the aforementioned irritants, it has a fairly high volatility. Chloroacetophenone (CN) and 2-chlorobenzylidenemalonodonitrile (CS), which are widely used in the past, are unsuitable not only because of rather high toxicity (respectively, 1st and 2nd hazard class), but also because CN slowly interacts with glycols to form ketals, and CS slowly decomposes (hydrolyzed) with water also to form physiologically inactive substances.

It is advisable to add to the composition of the dye, in the amount of 0.001-0.1 wt. %, and a thickener (Aerosil or a mixture of Aerosil with a polymeric organic thickener) in an amount of 1.0 ÷ 10 wt. %

The most applicable solvents and cosolvents are given respectively in Tab. 1 and Tab. 2

The inventive compositions are illustrated by examples.

The evaluation of the ballistic characteristics of the composition was carried out by firing at the target from the device "UDAR" with the BAMP pulleys filled with the claimed composition from a distance of 2 ÷ 9 m; In all examples of formulations in which solvents with t. Kip were used. not less than 180 ° С (Table 1), the effective throwing range was 4-8 m, and when adding solvents with a bale. less than 180 ° C (table. 2) - 3-5 m

The rapidity of exposure to two formulations with a minimum content of irritant (0.1 wt.%) According to the time of onset of blepharospasm (irresistible eyelid closure) was tested on volunteers through field tests. As a result, it was found that when water is present in the composition, the response time of the composition increases about 2 times (from 2-3 seconds to 1-1.5 seconds), and in the presence of water and α-propylene glycol - about 3-4 times: blepharospasm occurs in less than 1 second.

For the remaining formulations, with a relatively high content of irritants, the irritating effect (speed and intensity of exposure) was tested on volunteers and one of the authors by applying 0.2 g of the composition according to option 1 or 2 and (on the other hand) of the respective reference composition, symmetrically on the skin of the hands of the forearm from the side of the palm. The "speed" of the composition was evaluated by the time until the sensation of burning appeared. The degree of reddening of the skin was also visually assessed, which intensified with the sensation of subjects gaining a burning sensation. The sensations of subjects in time and intensity of exposure were individual in nature, but in all examples the time of onset of exposure was always less and intensity was greater for formulations containing DMSO and water (option 1) or, respectively, for formulations containing DMSO, water and α-propylene glycol (option 2). The time given in the examples is averaged for two (three) inspected.

In describing the examples, the following abbreviations are used:

PG - α-propylene glycol

DMSO - dimethyl sulfoxide.

MPK - morpholide pelargonic acid.

CR - dibenz [b, f] -1, 4-oxazepine.

CH-1-methoxy-1,3,5-cycloheptatriene.

PEG-200 - polyethylene glycol with an average molecular weight (M.) = 200;

PEG-400 - polyethylene glycol with an average M. = 400;

OS ₉₅ - 95% capsaicin, selective red pepper extract with capsaicin content of 95%, oleoresin capsicum 95%;

OS ₁₀ - 10% capsaicin, selective extract of red pepper with the content of capsaicin 10%, oleoresin capsicum 10%;

SC CO2 (5%) is a supercritical selective concentrate of red pepper (“Gorofit” pepper) with 5% capsaicin content.

Table 1

Organic solvents for irritating formulations.

Glycols, glycol ethers, as well as glycerin and its ethers with a boiling point above 180 ° C and with a share of oxygen of at least 15% by weight.

Notes. * M.p. - melting point, (T.z.) - freezing point;

∞ - mixed with water in all respects; H.R. - well soluble (limited, but more than 10 g in 100 g of water); W.R. - moderately soluble (less than 10, but more than 1 g in 100 g of water); T.R. - it is difficult to dissolve (less than 1, but more than 0.3 g in 100 g of water);

(-) - dash: no data.

table 2

Organic co-solvents *.

Mono - and diesters of glycols with t. Kip. below 180 ° C, as well as monohydric alcohols and ketones with a mass fraction of oxygen of at least 16%.

Note. * Solvents of this group with t. Kip. below 180 ° C can be used in formulations only as cosolvents in a mixture with higher boiling solvents from group 1. The throwing range for their use is 3-5 m.

Examples, for the first variant of the claimed invention.

Example 1.1.

Liquid irritant composition containing irritant CR as an irritant, β-butylene glycol (see table 1, pos. No. 4) as a solvent, accelerator-booster amplifier — DMSO (minimal) + water, in the following ratio of components, masses . %:

CR 1.0

β-butylene glycol 86.0

DMSO (minimum) 3.0

Water 10.0

Time before the beginning of a burning sensation - 74sec

In a similar composition of the comparison without water - 91 seconds., The difference - 17 seconds.

Hereinafter, the water in the composition of the comparison is replaced by an equal mass fraction of the above organic solvent.

Effective throwing range - 8 m.

Example 1.2.

In example 1.1, characterized in that as an irritant, the composition contains allyl isothiocyanate (CH ₂ = CH-CH ₂ -SCN), as a solvent - a mixture of polyethylene glycol PEG-400 and β-propylene glycol (β-PG) in a mass ratio of 1: 2 (see table 1, pos. No. 11 and No. 3, respectively), with the following ratio of components, mass. %:

Allyl isothiocyanate (maximum) 12.0

PEG-400 (17%) + β-PG (34%) 51.0

DMSO 12.0

Water (maximum) 25.0

Time to the beginning of a burning sensation - 65 seconds

In a similar composition of comparison without water - 93 seconds., The difference - 28 seconds.

Effective throwing range - 6 m.

Example 1.3.

In example 1.1, characterized in that as an irritant, the composition contains SC CO2 (“Gorofit” pepper) with 5% capsaicin content, β-butyleneneglycol dibutyl ether (solvent with close to minimum oxygen content; see table 1 , pos. No. 23), in the following ratio of components, mass. %:

SK CO2 (5%) concentrate of red pepper 10.0

Dibutyl ether β-butylene glycol 47.0

DMSO (maximum) 40.0

Water (minimum) 3.0

Time to the beginning of a burning sensation - 99 seconds

In the same composition of comparison without water - 106 seconds., The difference - 7 seconds.

Effective throwing range - 5-6 m.

Example 1.4.

In example 1.1, characterized in that as an irritant, the composition contains a mixture of allylisothiocyanate with a selective concentrate of red pepper extract containing 10% capsoicin (OC ₁₀ ), as a solvent is a mixture of ethylene glycol and glycerin (see table 1, item No. 1 and No. 6, respectively) in the ratio of 1: 1, with the following ratio of components, mass. %:

Allyl isothiocyanate 5, 0

(OS ₁₀ ) 5.0

Ethylene glycol (14%) + glycerin (14%) 28.0 (minimum)

DMSO (maximum) 40.0

Water 22.0

Time to the beginning of a burning sensation - 60 seconds.

In the same composition of comparison without water - 86 seconds., The difference - 26 seconds.

Effective throwing range - 5-6 m.

Example 1.5.

In example 1.1, characterized in that as a solvent, the composition contains dipropylene glycol (see table. 1, item. No. 12), in the following ratio of components, mass. %:

CR (minimum) 0.1

Dipropylene glycol 40.0

DMSO 39.9

Water 20.0

Time before the beginning of a burning sensation - 118 sec.

In the same composition of comparison without water - 143 seconds., The difference - 25 seconds.

The effective throwing range is 6-7 m.

Example 1.6.

In example 1.1, characterized in that as an irritant, the composition contains a mixture of irritant CR with selective concentrate of red pepper extract containing 95% capsoicin (OC ₉₅ ), a mixture of glycerol monomethyl ether (1,2) is used as a solvent with glycerol diisopropyl ether (1,3-diisopropoxypropanol-2) in a mass ratio of 1: 1 (see Table 1, pos. No. 25 and No. 28, respectively), in the following ratio of components, mass. %:

CR 0.5

OC95 0.5

Glycerol monomethyl ether (45.0%)

+ glycerol diisopropyl ester (45.0%) 90.0 (maximum)

DMSO 5.0

Water 4.0

Time to the beginning of a burning sensation - 82 seconds

In a similar composition of comparison without water - 90 seconds., The difference - 8 seconds.

Effective throwing range - 8m.

Example 1.7

In example 1.1, characterized in that as an annoying
substances the composition contains a mixture of irritants CR and CH, as a solvent - a mixture of α-propylene glycol (PG) and diethylene glycol (DEG)
(see table 1, pos. No. 2 and No. 7, respectively) in a mass ratio of 3: 1, with the following ratio of components, mass. %:

CR 1.0

CH 2.0

PG (60%) + DEG (20%) 80.0

DMSO 5.0

Water 12.0

Time before the sensation of burning - 58s

In the same composition of comparison without water - 77 seconds., The difference - 19 seconds.

Effective throwing range - 6m.

Example 1.8

In example 1.7, characterized in that instead of α-propylene glycol (PG), the composition contains ethylene glycol (EG), with the same ratio of components, mass. %:

CR 1.0

CH 2.0

EG (60%) + DEG (20%) 80.0

DMSO 5.0

Water 12.0

Time to the beginning of a burning sensation - 80 sec.

In a similar composition of comparison without water - 98 seconds, the difference - 18 seconds.

Effective throwing range - 6m.

Example 1.9

In example 1.1, characterized in that as a solvent, the composition contains a mixture of diethyl ether of diethylene glycol (diethylcarbitol) (see table 1, item No. 21) with a co-solvent - cyclohexanol (see table 2, No. 15); in addition, the composition contains a thickener - a mixture of polyvinyl alcohol with aerosil, as well as - basic magenta (dye) in the following ratio of components, mass. %:

CR 0.9

Diethylcarbitol (44%) + cyclohexanol (24%) 67.0

DMSO 25.0

Water 6.0

Polyvinyl alcohol (0.4%) + aerosil (0.6%) 1.0

Fuchsin basic 0.1

Time to start burning sensation - 70 sec.

In a similar composition of comparison without water - 81 seconds, the difference - 11 seconds.

Effective throwing range - 4-5 m.

Example 1.10

In Example 1.9, characterized in that as a co-solvent the composition contains H-butyl alcohol (n-butanol) (see Table 2, No. 11), polyvinylpyrrolidone as a thickener, and methylene blue as a dye in the following ratio of components mass %:

CR 0.99

Diethylcarbitol (36%) + N-butanol (22%) 58.0

DMSO 25.0

Water 6.0

Polyvinylpyrrolidone 10.0

Methylene blue 0.01

Polyacrylamide 1.0

Time before the beginning of a burning sensation - 71 sec.

In the same composition of the comparison without PG - 88 seconds, the difference - 17 seconds.

Effective throwing range - 6 m.

Example 2.7.

According to Example 2.5., Characterized in that PG is used as a solvent and as a component of a booster accelerator accelerator (the PEG-200 solvent is replaced with an equal amount of PG):

CH 1.0

OS ₁₀ 3.0

DMSO 25.0

Water 3.0

GHG (45% + 23%) 68.0

The separation of the mass fraction of GHGs by 45% as an accelerator amplifier and 23% as a solvent is conditional, but it indicates that with a mass fraction of GHGs above 45%, no further effect of amplification-acceleration of stinginess is observed.

Time to the beginning of a burning sensation - 62 seconds.

In a similar composition of comparison without PG - 86 seconds (solvent - PEG-200), the difference - 24 seconds.

Effective throwing range - 5-6 m.

Example 2.8.

In example 2.6., Characterized in that the solvent used is a mixture of dipropylene glycol monomethyl ether (Dovanol DPM) (Table 1, item # 17) and co-solvent - cyclohexanone (Table 2, item # 19), and as a thickener the composition contains polyvinyl alcohol (PVA) and aerosil, and also additionally contains a dye - methylene blue, in the following ratio of components, mass. %:

CH 1.0

OS ₁₀ 3.0

Dovanol DPM (20%) + cyclohexanone (16%) 37.0

DMSO 25.0

Water 3.0

PG 25.0

PVA 5.0

Aerosil 0.98

Methylene blue 0.02

Time before the beginning of a burning sensation - 75 seconds.

In a similar composition of comparison without PG - 90 seconds., The difference - 15 seconds.

Effective throwing range - 4-5m.

Example 2.9

In example 2.6., Characterized in that the solvent used is a mixture of β-propylene glycol (β-PG) (Table 1, item # 3) and dipropyleneglycol monomethyl ether (Table 1), item # 17) and as a thickener, the composition contains polyvinyl alcohol (PVA) and aerosil, the dye is fuchsin, in the following ratio of components, mass. %:

CH 1.0

OS ₁₀ 3.0

β-PG (20%) + Dovanol DPM (21%) 41.0

DMSO 25.0

Water 3.0

PG 25.0

PVA 1.0

Aerosil 0.9

Fuchsin 0, 1

The time before the start of a burning sensation is 72 seconds.

In the same composition of comparison without PG and without β-PG - 90 sec., The difference is 18 sec.

Effective throwing range - 7m.

Example 2.10

In example 2.6., Characterized in that the solvent used is a mixture of dipropylene glycol monomethyl ether (Dovanol DPM) (Table 1, item # 17) and a co-solvent - methyl ethyl ketone (IEC) (Table 2, item # 16), as a thickener, the composition contains polyvinylpyrrolidone (PVP) and aerosil, and as a dye - brilliant green, in the following ratio of components, mass. %:

CH 0.99

OS ₁₀ 3.0

Dovanol DPM (20%) + IEC (13%) 33.0

DMSO 25.0

Water 3.0

PG 25.0

Polyvinylpyrrolidone 10.0

Brilliant Green 0.01

The time before the burning sensation was not determined.

Effective throwing range - 3-4 m.

Example 2.11.

In example 2.1, characterized in that the solvent used is dipropylene glycol dimethyl ether (DMEDP) - a solvent with so-called bale. 184 ° C (see table 1, pos. No. 18), with the following ratio of components, mass. %:

CR 1.0

DMEDP 76.0

DMSO 3.0

Water 10.0

PG 10.0

The time before the burning sensation was not determined.

Effective throwing range - 5 m.

An experimental batch of aerosol cans, filled with the claimed composition, was tested at one of the enterprises in Nizhny Novgorod. Tests have shown a high efficiency of the composition both for irritating properties and for ensuring high ballistic characteristics. The stability of the characteristics of the liquid composition in the temperature range from minus 25 ° C to plus 50 ° C: throwing distance - not less than 3 m.

Claims (12)

1. Liquid irritant composition for self-defense means containing at least one irritant, dimethyl sulfoxide and organic solvent or mixture of organic solvents, characterized in that it contains dimethyl sulfoxide in a mixture with water, and as an organic solvent contains oxygen-containing organic solvent containing oxygen at least 15 wt.% and having a boiling point of not less than 180 ^{° C} selected from the group consisting of dihydric alcohols (glycols), polyglycols and their simple mono- or diesters or trohat ohm alcohol - glycerin and its simple mono - and diesters, or a mixture of these solvents in various combinations in the following ratio of components, wt.%: Irritant  0.1-12.0 Oxygenated organic solvent  28.0-90.0 Dimethyl sulfoxide  3.0-40.0 Water  3.0-25.0 2. The composition according to claim 1, characterized in that it additionally contains an organic cosolvent selected from the group of simple mono- and di-esters of glycols and (or) monohydric alcohols, and (or) ketones or a mixture of these cosolvents in various combinations with non-oxygen content less than 16 wt.% and with a boiling point of less than 180 ^about C. 3. The composition according to claim 1 or 2, characterized in that it additionally contains a dye in an amount of 0.001-0.1 wt.%. 4. The composition according to claim 1 or 2, characterized in that it further contains a thickener in an amount of 1.0-10 wt.%. 5. The composition according to claim 4, characterized in that as a thickener it contains aerosil or a mixture of aerosil with a polymeric organic thickener. 6. A liquid irritant composition for self-defense products containing at least one irritant, dimethyl sulfoxide and an organic solvent or a mixture of organic solvents, characterized in that it contains dimethyl sulfoxide in a mixture with water, as an additional amplifier and burning agent contains α-propylene glycol, and the organic solvent comprises an oxygen-containing organic solvent with an oxygen content of at least 15 wt.% and having a boiling point of not less than 180 ^{° C} selected from the group s dihydric alcohols (glycols), polyglycols and their simple mono- or diesters or triatomic alcohol - glycerol and its simple mono- and diesters, or mixtures of these solvents in various combinations of the following component ratio, wt.%: Irritant  0.1-12.0 Oxygenated organic solvent  23.0-80.0 Dimethyl sulfoxide  3.0-40.0 Water  3.0-25.0 α-propylene glycol  10.0-45.0 7. The composition according to claim 6, characterized in that it additionally contains an organic cosolvent selected from the group of mono- and di-esters of glycols and (or) monohydric alcohols, and (or) ketones or a mixture of these cosolvents in various combinations with an oxygen content of at least 16 wt.% And with a boiling point of less than 180 ^o C. 8. The composition according to claim 6 or 7, characterized in that it additionally contains a dye in an amount of 0.001-0.1 wt.%. 9. The composition according to claim 6 or 7, characterized in that it further contains a thickener in an amount of 1.0 - 10 wt.%. 10. The composition according to claim 9, characterized in that as a thickener it contains aerosil or a mixture of aerosil with polymeric organic thickener.