RU2616701C2 - Метод производства пероксида водорода - Google Patents
Метод производства пероксида водорода Download PDFInfo
- Publication number
- RU2616701C2 RU2616701C2 RU2014118591A RU2014118591A RU2616701C2 RU 2616701 C2 RU2616701 C2 RU 2616701C2 RU 2014118591 A RU2014118591 A RU 2014118591A RU 2014118591 A RU2014118591 A RU 2014118591A RU 2616701 C2 RU2616701 C2 RU 2616701C2
- Authority
- RU
- Russia
- Prior art keywords
- hydrogen peroxide
- working solution
- production
- unit
- hydrogenation
- Prior art date
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 790
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 244
- 238000000034 method Methods 0.000 claims abstract description 513
- 239000012224 working solution Substances 0.000 claims abstract description 312
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 143
- 239000003054 catalyst Substances 0.000 claims abstract description 130
- 238000000605 extraction Methods 0.000 claims abstract description 92
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 85
- 230000003647 oxidation Effects 0.000 claims abstract description 82
- 150000001875 compounds Chemical class 0.000 claims abstract description 56
- 238000012544 monitoring process Methods 0.000 claims abstract description 45
- 239000000126 substance Substances 0.000 claims abstract description 29
- 150000004056 anthraquinones Chemical class 0.000 claims abstract description 25
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000004891 communication Methods 0.000 claims abstract description 23
- 239000003960 organic solvent Substances 0.000 claims abstract description 23
- 230000000694 effects Effects 0.000 claims abstract description 12
- 238000009434 installation Methods 0.000 claims description 80
- 230000008929 regeneration Effects 0.000 claims description 79
- 238000011069 regeneration method Methods 0.000 claims description 79
- 230000008569 process Effects 0.000 claims description 52
- 239000007789 gas Substances 0.000 claims description 45
- 230000033228 biological regulation Effects 0.000 claims description 44
- 239000007788 liquid Substances 0.000 claims description 26
- 238000001311 chemical methods and process Methods 0.000 claims description 23
- 230000007420 reactivation Effects 0.000 claims description 23
- 125000004122 cyclic group Chemical group 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 230000001276 controlling effect Effects 0.000 claims description 17
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 16
- 230000015572 biosynthetic process Effects 0.000 claims description 14
- 230000001590 oxidative effect Effects 0.000 claims description 13
- 229920001131 Pulp (paper) Polymers 0.000 claims description 12
- 239000006227 byproduct Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 230000001105 regulatory effect Effects 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 230000000737 periodic effect Effects 0.000 claims description 10
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 9
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 claims description 9
- 125000004151 quinonyl group Chemical group 0.000 claims description 9
- 238000004497 NIR spectroscopy Methods 0.000 claims description 7
- 238000005065 mining Methods 0.000 claims description 7
- 239000004753 textile Substances 0.000 claims description 7
- 230000002441 reversible effect Effects 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 238000004611 spectroscopical analysis Methods 0.000 claims description 3
- 238000004448 titration Methods 0.000 claims description 3
- 230000005540 biological transmission Effects 0.000 claims description 2
- 230000008054 signal transmission Effects 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 description 52
- 239000001257 hydrogen Substances 0.000 description 51
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 48
- 241000196324 Embryophyta Species 0.000 description 37
- 239000000203 mixture Substances 0.000 description 37
- 239000000243 solution Substances 0.000 description 29
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 21
- 238000005259 measurement Methods 0.000 description 20
- 230000008901 benefit Effects 0.000 description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 14
- 230000003197 catalytic effect Effects 0.000 description 14
- -1 cyclic anthraquinone Chemical class 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 14
- 239000001301 oxygen Substances 0.000 description 14
- 239000002245 particle Substances 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 11
- 239000011261 inert gas Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 238000004061 bleaching Methods 0.000 description 9
- 238000005187 foaming Methods 0.000 description 9
- 150000002978 peroxides Chemical class 0.000 description 9
- 238000004458 analytical method Methods 0.000 description 7
- 230000007613 environmental effect Effects 0.000 description 7
- 150000002431 hydrogen Chemical class 0.000 description 7
- 238000009776 industrial production Methods 0.000 description 7
- 229910052763 palladium Inorganic materials 0.000 description 7
- 230000002829 reductive effect Effects 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000004821 distillation Methods 0.000 description 5
- 238000011031 large-scale manufacturing process Methods 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000001491 aromatic compounds Chemical class 0.000 description 4
- 238000004817 gas chromatography Methods 0.000 description 4
- 231100001261 hazardous Toxicity 0.000 description 4
- 238000004128 high performance liquid chromatography Methods 0.000 description 4
- 238000004811 liquid chromatography Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 150000004053 quinones Chemical class 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 230000001172 regenerating effect Effects 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- AKIIJALHGMKJEJ-UHFFFAOYSA-N (2-methylcyclohexyl) acetate Chemical compound CC1CCCCC1OC(C)=O AKIIJALHGMKJEJ-UHFFFAOYSA-N 0.000 description 3
- UMWZLYTVXQBTTE-UHFFFAOYSA-N 2-pentylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(CCCCC)=CC=C3C(=O)C2=C1 UMWZLYTVXQBTTE-UHFFFAOYSA-N 0.000 description 3
- 239000003849 aromatic solvent Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 230000002262 irrigation Effects 0.000 description 3
- 238000003973 irrigation Methods 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- HXQPUEQDBSPXTE-UHFFFAOYSA-N Diisobutylcarbinol Chemical compound CC(C)CC(O)CC(C)C HXQPUEQDBSPXTE-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
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- 230000004048 modification Effects 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 238000001139 pH measurement Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 238000003969 polarography Methods 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 238000004451 qualitative analysis Methods 0.000 description 2
- 238000004445 quantitative analysis Methods 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000011877 solvent mixture Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- OTBHDFWQZHPNPU-UHFFFAOYSA-N 1,2,3,4-tetrahydroanthracene-9,10-dione Chemical class O=C1C2=CC=CC=C2C(=O)C2=C1CCCC2 OTBHDFWQZHPNPU-UHFFFAOYSA-N 0.000 description 1
- WUKWGUZTPMOXOW-UHFFFAOYSA-N 2-(2-methylbutan-2-yl)anthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)(C)CC)=CC=C3C(=O)C2=C1 WUKWGUZTPMOXOW-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- MCYPCBFOVKMNDW-UHFFFAOYSA-N 2-butan-2-ylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)CC)=CC=C3C(=O)C2=C1 MCYPCBFOVKMNDW-UHFFFAOYSA-N 0.000 description 1
- MAKLMMYWGTWPQM-UHFFFAOYSA-N 2-butylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(CCCC)=CC=C3C(=O)C2=C1 MAKLMMYWGTWPQM-UHFFFAOYSA-N 0.000 description 1
- IFHQWLHVCATXGU-UHFFFAOYSA-N 2-pentan-2-ylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)CCC)=CC=C3C(=O)C2=C1 IFHQWLHVCATXGU-UHFFFAOYSA-N 0.000 description 1
- BQUNPXRABCSKJZ-UHFFFAOYSA-N 2-propan-2-ylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3C(=O)C2=C1 BQUNPXRABCSKJZ-UHFFFAOYSA-N 0.000 description 1
- YTPSFXZMJKMUJE-UHFFFAOYSA-N 2-tert-butylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)(C)C)=CC=C3C(=O)C2=C1 YTPSFXZMJKMUJE-UHFFFAOYSA-N 0.000 description 1
- AIWWFEBAHIXODC-UHFFFAOYSA-N 2h-anthracene-1,9,10-trione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(=O)CC=C2 AIWWFEBAHIXODC-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- 244000019194 Sorbus aucuparia Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 238000009455 aseptic packaging Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 150000004336 hydroxyquinones Chemical class 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000010399 physical interaction Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 150000004059 quinone derivatives Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 235000006414 serbal de cazadores Nutrition 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000005236 sound signal Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11184575.6 | 2011-10-11 | ||
| EP11184575 | 2011-10-11 | ||
| PCT/EP2012/069408 WO2013053616A1 (en) | 2011-10-11 | 2012-10-02 | Process for producing hydrogen peroxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2014118591A RU2014118591A (ru) | 2015-11-20 |
| RU2616701C2 true RU2616701C2 (ru) | 2017-04-18 |
Family
ID=46963741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2014118591A RU2616701C2 (ru) | 2011-10-11 | 2012-10-02 | Метод производства пероксида водорода |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US10793433B2 (en:Method) |
| EP (1) | EP2766299B1 (en:Method) |
| AP (1) | AP3842A (en:Method) |
| AR (1) | AR088307A1 (en:Method) |
| CA (1) | CA2850213C (en:Method) |
| CL (1) | CL2014000811A1 (en:Method) |
| FI (1) | FI2766299T3 (en:Method) |
| IN (1) | IN2014CN03356A (en:Method) |
| MY (1) | MY185780A (en:Method) |
| PE (1) | PE20141489A1 (en:Method) |
| PT (1) | PT2766299T (en:Method) |
| RU (1) | RU2616701C2 (en:Method) |
| UY (1) | UY34378A (en:Method) |
| WO (1) | WO2013053616A1 (en:Method) |
| ZA (1) | ZA201402447B (en:Method) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IN2014CN03354A (en:Method) | 2011-10-11 | 2015-07-03 | Solvay | |
| CN105021684B (zh) * | 2014-04-29 | 2018-12-25 | 中国石油化工股份有限公司 | 蒽醌法生产双氧水过程中氢化效率、氧化效率和萃余浓度的测定方法 |
| WO2017028911A1 (en) * | 2015-08-19 | 2017-02-23 | Solvay Sa | Process for manufacturing hydrogen peroxide |
| WO2022101079A1 (en) | 2020-11-12 | 2022-05-19 | Solvay Sa | Raman spectroscopic method for the control of a liquid mixture |
| CN114906817B (zh) * | 2021-02-08 | 2023-12-05 | 中国石油化工股份有限公司 | 存储器、双氧水萃取工艺控制方法、装置和设备 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999040024A1 (en) * | 1998-02-04 | 1999-08-12 | Solvay (Societe Anonyme) | Process for the manufacture of hydrogen peroxide |
| RU2336225C2 (ru) * | 2002-09-30 | 2008-10-20 | Дегусса Аг | Новые водные растворы пероксида водорода |
| RU82361U1 (ru) * | 2008-12-08 | 2009-04-20 | Закрытое акционерное общество "Инженерный дом" | Система централизованного мониторинга и управления оборудованием удаленных объектов |
| RU97365U1 (ru) * | 2009-12-28 | 2010-09-10 | Общество с ограниченной ответственностью "Фирменное специализированное предприятие "КРАВТ" | Автоматическая хлораторная для обеззараживания воды газообразным хлором |
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| JPS504121B1 (en:Method) | 1970-03-31 | 1975-02-15 | ||
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| FI97465C (fi) | 1995-02-10 | 1996-12-27 | Kemira Chemicals Oy | Menetelmä vetyperoksidin valmistamiseksi |
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- 2012-10-02 EP EP12766673.3A patent/EP2766299B1/en active Active
- 2012-10-02 CA CA2850213A patent/CA2850213C/en active Active
- 2012-10-02 PE PE2014000523A patent/PE20141489A1/es active IP Right Grant
- 2012-10-02 US US14/350,820 patent/US10793433B2/en active Active
- 2012-10-02 WO PCT/EP2012/069408 patent/WO2013053616A1/en active Application Filing
- 2012-10-02 IN IN3356CHN2014 patent/IN2014CN03356A/en unknown
- 2012-10-02 PT PT127666733T patent/PT2766299T/pt unknown
- 2012-10-02 AP AP2014007561A patent/AP3842A/en active
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| WO1999040024A1 (en) * | 1998-02-04 | 1999-08-12 | Solvay (Societe Anonyme) | Process for the manufacture of hydrogen peroxide |
| RU2336225C2 (ru) * | 2002-09-30 | 2008-10-20 | Дегусса Аг | Новые водные растворы пероксида водорода |
| RU82361U1 (ru) * | 2008-12-08 | 2009-04-20 | Закрытое акционерное общество "Инженерный дом" | Система централизованного мониторинга и управления оборудованием удаленных объектов |
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Also Published As
| Publication number | Publication date |
|---|---|
| US20140255294A1 (en) | 2014-09-11 |
| BR112014008479A2 (pt) | 2017-04-11 |
| AP3842A (en) | 2016-09-30 |
| ZA201402447B (en) | 2017-08-30 |
| PE20141489A1 (es) | 2014-10-23 |
| CL2014000811A1 (es) | 2014-06-20 |
| CA2850213C (en) | 2020-07-21 |
| MY185780A (en) | 2021-06-07 |
| EP2766299A1 (en) | 2014-08-20 |
| CA2850213A1 (en) | 2013-04-18 |
| FI2766299T3 (fi) | 2023-04-03 |
| UY34378A (es) | 2013-04-30 |
| PT2766299T (pt) | 2023-03-20 |
| WO2013053616A1 (en) | 2013-04-18 |
| EP2766299B1 (en) | 2022-12-28 |
| RU2014118591A (ru) | 2015-11-20 |
| AP2014007561A0 (en) | 2014-04-30 |
| US10793433B2 (en) | 2020-10-06 |
| CN103946155A (zh) | 2014-07-23 |
| IN2014CN03356A (en:Method) | 2015-07-03 |
| AR088307A1 (es) | 2014-05-21 |
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