RU2611140C1 - Method for alcohol-free perfumes production - Google Patents

Abstract

FIELD: chemistry.

SUBSTANCE: invention refers to perfumes. The method for alcohol-free perfume products production, comprising perfume composition preparation, mixing with micro-emulgator followed by addition of water to form a transparent microemulsion. Solubilizate LRI and/or 9 NII Kosmakol in an amount of 80 to 300% by weight of the perfume composition are used as the microemulgator. Water is introduced into the mixture under vigorous stirring.

EFFECT: invention provides improved organoleptic properties of perfume products, simplification of production and technological process.

5 tbl, 3 ex

Description

The invention relates to perfumes and can be used in the preparation of perfumes, such as perfumes, perfumes, eau de toilette, cologne, fragrant water, or any other perfumes.

A known method of preparing perfumery liquids (SU No. 707953, class C11B 9/00, 1980), comprising introducing a 0.5-3% aqueous solution of high molecular weight polyethylene glycol polyethylene oxide in an amount of 0.001-0.003% by weight in a solution of the composition in ethyl alcohol in order to accelerate the formation of sediment, reduce the aging time and increase the stability of perfume liquids to precipitation during storage.

The presence of ethanol in the perfume liquid does not allow to obtain perfume products with a delicate aroma, as alcohol distorts the unique smells of perfumes.

A known method for the preparation of perfumery liquids, perfumery waters, eau de toilette and colognes with a high water content (RU 2495097, class СВВ 9/00, 2013), including obtaining a solution of the perfumery composition in alcohol, standing the solution for maturation of the sediment, followed by separation by filtration. Activated anode water in the amount of 15% of the total volume of the mixture of all components, where glassy carbon is used as the anode, is introduced into the solution of the perfume composition in alcohol. The resulting mixture at a temperature of 18-20 ° C is stirred for 5 hours with an interval of 20 minutes, then, adding ethyl alcohol, stirred for 30 minutes and incubated for 18 hours

The disadvantage of this method is primarily the need for the presence of ethanol in the composition of the perfume composition, as well as its rather complicated production, including the use of special anode water that requires additional equipment, which can affect the cost of the product without improving its properties.

There is also a known method for the preparation of perfumery liquids, for example perfumes and colognes, which consists in preparing a composition that is mixed with alcohol and water and left to ripen. In this case, when mixing the composition with alcohol, an aqueous solution of a surfactant (microemulsifier) is added to the liquid, in which the disodium salt of ethyldiaminetetraacetic acid is used. Next, the ripened liquid is filtered and poured (SU 181765 from 07/14/1966)

The disadvantage of all known methods is the obligatory use of alcohol in the process of preparing perfumery products, the presence of which affects its organoleptic properties, including worsens aroma, complicates the organization of production and the technological process, which requires significant time costs for the products to mature for maturation and an additional stage - filtering, as a result of which significant losses are inevitable.

The prototype of the invention is a method for producing alcohol-free perfume products, including the preparation of a perfume composition, mixing it with a microemulsifier, and then introducing water into the mixture to form a transparent microemulsion (WO 1994007461 A1, 04/14/1994).

The disadvantage of this method is the instability of the resulting perfume products during storage and transportation, requiring additional operations in the production in the form of aging (from 1 to 3 months) and filtration.

The objective of the invention is to develop a new method for producing alcohol-free perfumery products of a wide range and with high stability.

The technical result of the invention is to simplify the organization of production and the process.

The problem and the technical result are achieved by the fact that the method of producing alcohol-free perfume products includes the preparation of a perfume composition, mixing it with a microemulsifier, followed by the introduction of water into the mixture with the formation of a transparent microemulsion. According to the invention, the LR Solubilizer and / or Cosmacol NII 9 are used as a microemulsifier in an amount of from 80 to 300% by weight. by weight of the perfume composition, and water is introduced into the mixture with vigorous stirring.

The main difference of the new method for producing alcohol-free perfumery products is the choice and quantitative content of Solubilizer LRI and / or Cosmacol NII 9, which have a high solubility of hydrophobic substances in water. The amount of microemulsifier is due to its composition and can vary from 80 to 300% by weight. The amount of microemulsifier is less than 80% by weight. by weight of the perfume composition will not allow to obtain a transparent microemulsion with high stability and will require the operation of aging and filtration. With an increase in the amount of microemulsifier, the viscosity of perfumery products will increase and its application in the form of a gel form is possible, which will expand the range of perfumery products, and a further quantitative increase in excess of 300% by weight is impractical because it will not affect the increase in stability, and consequently, the simplification of the organization of production.

The method of obtaining alcohol-free perfumery products is illustrated by the following examples.

Example 1

To the perfume composition (PC 1) of the following composition, in weight. %:

Aldehyde C 12 MNA 0.02 Bergamot, essential oil 5 Lemon, essential oil 3 Ylang Ylang, essential oil 7 Orivon 0.5 Rose, perfume fragrance four Jasmine Sambac, absolute one Lily of the valley, perfume 2 Neroli, essential oil 2 Sandalwood, essential oil 3 Vetiver Essential Oil one Patchouli, essential oil 2 Oak Moss, Resinoid 0.1 Vanilla, absolute 2 Ambroxan 0.1 Animalide 0.01

LR Solubilizer or Cosmacol NII 9 was added and mixed until uniform. Then, water was added to the resulting mixture with vigorous stirring until a clear emulsion formed.

Experiments were conducted with a different ratio of perfume composition and microemulsifiers. The results are shown in table 1.

The perfume water obtained immediately after preparation is ready for packaging and use, since no alcohol precipitates for a long time in alcohol-free perfume products. Due to the exclusion of the aging process, the technological process is greatly simplified and cheaper in comparison with the existing existing methods for producing perfumery products.

Example 2

Example 2 was carried out according to the same technology as in example 1. Additional experiments were carried out using a perfume composition (PC 2) of the following composition, in weight. %:

Mango, perfume 10 Peony, perfume 5 Lilac, perfume fragrance 5 Lily, perfume fragrance 5 Tiare, perfume fragrance 6 Udovy tree, perfumery fragrance 8 Jasmine, absolute 7

From the results of table 2 it is seen that a mixture of microemulsifiers can also be used as a solvent for the perfume composition. In addition, it was experimentally determined that the minimum required amount of microemulsifier also depends on the composition of the perfume composition.

Perfumery water, eau de toilette, cologne and fragrant water can be used in the form of a spray, as well as in the form of concentrated perfumes - in gel form.

As the aqueous phase can be used water infusions, hydrolytes, mixtures thereof, and water-soluble aromatic substances can be added to the water.

Example 3

A comparison of the organoleptic properties and odor resistance of alcohol-free and alcoholic perfume water was carried out on the example of the perfume composition (PC 3) of the following composition, in weight. %:

Mango, perfume 3 Currant, perfume fragrance 3 Aldehyde C 14 (2% in DPG) four Jasmine, absolute 5 Ylang Ylang, essential oil 3 Atlas cedar, essential oil 10 Sandalwood, essential oil 3 Vanilla, absolute 5 Galaxolid 50 DEF 3

Alcohol-free perfumery water on blotters and on the skin has a more subtle but vibrant aroma without a sharp irritating smell of alcohol. Odor resistance of alcohol-free perfume water was observed on blotters for 7 days.

The experiments made it possible to determine the maximum and minimum number of microemulsifiers Solubilizant LRI or Cosmacol NII 9 both individually and in mixture. The minimum required amount of microemulsifier is selected individually, based on the composition of the perfume composition, and is not limited to the presented examples, but within the limits of the claimed proportions.

Obtained by the claimed method, the perfumery product is either a transparent liquid that can be used with a spray, or has a gel shape.

The products are thermostable, withstands freezing and does not change their organoleptic properties after thawing - it has been experimentally confirmed, but standard storage conditions are recommended - from +5 to + 25 ° С.

The choice of a microemulsifier in the form of LR Solubilizer and / or Cosmacol NII 9 and its quantitative ratio of the weight of the perfume composition from 80 to 300% by weight makes it possible to exclude the aging operation and carry out the filling process in bottles immediately after preparation. This significantly reduces the labor costs associated with the need for long-term storage of large volumes of liquid.

The production of alcohol-free perfumes is an environmental advantage. The Convention on Organic Solvents in several European countries regulates the reduction of the use of organic solvents to preserve the environment.

The absence of alcohol in the process greatly simplifies the organization of production, since alcohol refers to explosive and fire hazardous substances.

The method of producing alcohol-free perfumery products has now passed experimental tests and is fully ready for its industrial use.

Claims (1)

A method of producing an alcohol-free perfumery product, comprising preparing a perfumery composition, mixing it with a microemulsifier and then introducing water into a mixture to form a transparent microemulsion, characterized in that LRI Solubilizer and / or Cosmacol NII 9 are used as a microemulsifier in an amount of from 80 to 300% by weight . by weight of the perfume composition, and water is introduced into the mixture with vigorous stirring.