RU2544549C1 - Composition for preparing polymer matrix containing polydicyclopentadiene for producing composite, polydicyclopentadiene composite and method for producing it - Google Patents

Abstract

FIELD: chemistry.

SUBSTANCE: composition for preparing a polymer matrix contains, wt %: polymeric modifier 0.5-20.0, radical initiator 0.1-4.0, polymer stabiliser 0.1-4.0, modifying additive 1.0-15.0, ruthenic catalyst of metathesis polymerisation of dicyclopentadiene 0.001-0.02 and dicyclopentadiene min. 98% purity - the rest. The polydicyclopentadiene composite contains carbon-containing inorganic filler, organic-silicone modifier and polymer matrix described above in the preset mixture ratio. The composite is produced by preparing the polymer matrix by mixing dicyclopentadiene with polymer stabiliser and modifier, heating the prepared mixture to temperature 60-180°C and keeping the mixture at the given temperature for 2-360 min. After the mixture is cooled to 0-50°C, mixed with radical initiator, modifying additive and catalyst and agitated, the produced matrix is combined with reinforcing carbon-containing inorganic filler pre-treated with organic-silicone modifier. The polymerisation represents heated in a mould to 120-300°C and keeping at the above temperature for 1-300 min.

EFFECT: improving characteristics of the polydicyclopentadiene and reinforcing carbon composites reflected by increasing bending and tensile strength and elastic modulus, and ease of manufacturing ensured by using thermally activated carbene complexes of rhutenium.

6 cl, 39 ex

Description

The invention relates to the chemistry of macromolecular compounds, in particular to composite materials and the technology for their production using polydicyclopentadiene.

A known method for producing composite materials from polydicyclopentadiene using fiberglass treated with lubricants based on organosilicon compounds. Metathesis polymerization is carried out using ruthenium catalysts of the first generation (US 6436476 B1, 02.20.2002).

The disadvantage of this method is the use of ineffective ruthenium catalysts of the first generation, leading to low-quality products.

A known method of producing composite materials from polydicyclopentadiene using fiberglass treated with silicone sizing. For polymerization, the second generation Grubbs catalyst is used, which has a high activation rate (International Publication WO 2004009507 A1, 01.29.2004).

The disadvantage of this method is the use of an expensive second-generation Grubbs catalyst, the high activation rate of which significantly reduces the time interval for the use of the polymerization mixture. In the manufacture of large products with reinforcement and fillers, defects can occur: bubbles, unimpregnated areas and cracks.

A known method for the production of composite materials containing polydicyclopentadiene, according to which they mix in any sequence of dicyclopentadiene, antioxidant, elastomer, modifying additives, which include a carbon-containing filler, using a thermally activated catalyst. The polymerization of the obtained reaction mass is carried out by heating from 30 to 210 ° C (RU 2465286 C2, 10.27.2012).

The disadvantage of this method is the use of a polymer binder with low strength and heat resistance, which does not have good adhesion to the filler, which worsens the performance of the products. Despite the presence of reinforcing fillers, the material has a low modulus of elasticity of 2.2 GPa. The glass transition temperature of the material, even in its best modifications, does not exceed 163 ° C.

The closest technical solution is the method of producing carbon fabric composite materials using a monomer based on dicyclopentadiene and tetracycline dodecene. To ensure bonding of carbon fiber to the polymer, unsaturated compounds containing an isocyanate fragment or a mixture of unsaturated compounds with a mobile hydrogen atom and diisocyanate are used. Metathesis polymerization is carried out using a second-generation Grubbs catalyst (US 2012088879 A1, 04/12/2012).

The disadvantage of this method is the use of an expensive second-generation Grubbs catalyst, the high activation rate of which significantly reduces the time interval for the use of the polymerization mixture. In the manufacture of large products with reinforcement and fillers, defects can occur: bubbles, unimpregnated areas and cracks.

The technical problem solved by the proposed group of inventions is the development of a composition for the preparation of a polymer matrix containing polydicyclopentadiene, used in the preparation of composite materials based on polydicyclopentadiene and reinforcing carbon-containing inorganic fillers having enhanced physical and mechanical characteristics of the composite material, and the development of a method for producing these materials.

The technical result from the implementation of the proposed group of inventions is to improve the characteristics of composite materials based on polydicyclopentadiene and reinforcing carbon-containing fillers, expressed, in particular, in increasing the strength and elastic modulus during bending and tension, and the manufacturability of their production based on the use of thermally activated carbene complexes of ruthenium.

The technical problem is solved by using the composition to prepare a polymer matrix containing polydicyclopentadiene with the following content of components, mass ..%:

polymer modifier 0.5-20.0 radical initiator 0.1-4.0 polymer stabilizer 0.1-4.0 modifying additive 1.0-15.0 ruthenium metathesis catalyst polymerization of dicyclopentadiene 0.001-0.02 dicyclopentadiene not less than 98% purity rest,

wherein the polymeric modifier as it contains ethylidene norbornene (ENB) or cyclopentadiene oligomers, acrylic, methacrylic, styrene, silicone and epoxy monomers selected from: allyl methacrylate, glycidyl methacrylate, etilendimetakrilat, diethylene glycol dimethacrylate, butilenglikoldimetakrilat, tritsiklodekandimetanoldimetakrilat, ethoxylated bisphenol A dimethacrylate, trimethylolpropane trimethacrylate, 3- methacryloxypropyltrimethoxysilane, vinyltrimethoxysilane, 5-trialkoxysilyl-2-norbornene, divinylbenzene , diisopropenylbenzene or diane epoxy resin or mixtures thereof, as a radical initiator it contains: di-tert-butyl peroxide, dicumyl peroxide, 2,3-dimethyl-2,3-diphenyl-butane or triphenylmethane or mixtures thereof, it contains a polymer stabilizer : tetrakis [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane, 2,6-di-tert-butyl-4- (dimethylamino) phenol, 1,3,5-trimethyl-2,4 6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene, tris (4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) isocyanurate, 3,5-di-tert-butyl -4-hydroxyanisole, 4,4′-methylenebis (2,6-di-tr t-butylphenol), diphenylamine, para-di-tert-butylphenylenediamine, N, N′-diphenyl-1,4-phenylenediamine, tris (2,4-di-tert-butylphenyl) phosphite, tris (nonylphenyl) phosphite, bis ( 2,2,6,6-tetramethyl-4-piperidinyl) sebacinate, bis (1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) sebacinate, bis (1-methyl-2,2,6, 6-tetramethyl-4-piperidinyl) sebacinate, 2-tert-butyl-6- (5-chloro-2H-benzotriazol-2-yl) -4-methylphenol, 2- (2H-benzotriazol-2-yl) -4, 6-bis (1-methyl-1-phenyl) phenol or mixtures thereof, and as a modifying additive - a mixture in equal proportions of diisocyanate and hydroxymethacrylate. The diisocyanate is selected from the group: 2,4-toluene diisocyanate, 1,6-hexanediisocyanate, methylene bis (4,1-phenylene) diisocyanate, and hydroxymethacrylate is selected from the group: 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, glycerin dimethacrylate, bisphenol glycidyl methacrylate.

As a catalyst, a ruthenium catalyst for the metathesis polymerization of dicyclopentadiene of the formula is used:

where the Deputy L is selected from the group:

The ruthenium catalyst for the metathesis polymerization of dicyclopentadiene (hereinafter referred to as the catalyst) with the substituent N- [1,3-bis- (2,4,6-trimethylphenyl) -2-imidazolidinylidene] dichloro (oN, N-dimethylaminomethylphenylmethylene) ruthenium is known and described in RU 2377257 C1, 12/27/2009. A catalyst where a substituent L is selected from the group N1-N5 is known and described in RU 2393171 C1, 06/27/2010, and a catalyst where a substituent L is selected from the group N1a-N1c is known from RU 2462308 C1, 09/27/2012.

These catalysts are resistant to a wide range of polymer additives, the use of which extends technological capabilities in the manufacture of products from polydicyclopentadiene.

The obtained polymer matrix containing polydicyclopentadiene is included in the composition of the composite material containing a carbon-containing inorganic filler, an organosilicon modifier in the following components, wt ..%:

organosilicon modifier 0.01-1.0 carbon-containing inorganic filler 5.0-80.0 polydicyclopentadiene-containing polymer matrix rest, according to any one of claims 1, 2

wherein the organosilicon modifier is selected from the group: vinyltrimethoxysilane, vinyl tris (2-methoxyethoxy) silane, 3-methacryloxypropyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3-thiopropyltrialkoxysilane, 5-trialkoxysilyl-2-n-tri-norbenene -N ′ - (4-vinylbenzyl) ethylene diamine hydrochloride or mixtures thereof, and the carbon-containing inorganic filler is selected from: carbon fiber, roving and woven materials based on them. The diisocyanate is selected from the group: 2,4-toluene diisocyanate, 1,6-hexanediisocyanate, methylene bis (4,1-phenylene) diisocyanate, and hydroxymethacrylate is selected from the group: 2-hydroxyethyl methacrylate, 2-hydroxypropylmethacrylate, glyceride dimethacrylate, bisphenol methylene .

The technical problem is also solved by the method of producing a composite material based on polydicyclopentadiene, providing for the preparation of a polymer matrix according to any one of claims 1 to 2 by mixing dicyclopentadiene with a polymer stabilizer and a modifier, heating the resulting mixture to a temperature of 60-180 ° C, holding the mixture at this temperature in for 2-360 minutes and its cooling to a temperature of 0 to 50 ° C, subsequent mixing with a radical initiator, a modifying additive and a catalyst, and mixing the mixture, the resulting mat Rice is combined with a carbon-containing inorganic reinforcing filler treated with a solution of organosilicon modifier, and polymerization is carried out by heating in the mold to a temperature of 120-300 ° C and holding at this temperature from 1 to 300 minutes.

Moreover, the reinforcing carbon-containing material before its use is treated by holding it in an aqueous or aqueous-alcoholic 0.1-1.5% solution of an organosilicon modifier (sizing) at a pH of 4.2-4.7 for 10-120 minutes and drying at a temperature of 90 -120 ° C.

The joint introduction of the indicated combination of mixture components in appropriate ratios makes it possible to achieve a purposefully set unique combination of the main characteristics of the composite material based on polycyclopentadiene in a wide range of conditions for its practical application, that is, it allows controlling the combination of mechanical strength, heat and oil resistance. In this case, unique combinations of mechanical strength, glass transition temperature, chemical and atmospheric resistance are achieved.

The claimed method allows to obtain composite materials with high mechanical properties, thermal and chemical stability with reduced catalyst consumption and thermal control of the beginning of the polymerization process. These effects are provided by the special properties of the catalyst, which at a given temperature and quantity activates the polymerization of dicyclopentadiene and the physicochemical interaction with it of the above modifying additives. In this case, polydicyclopentadiene with the corresponding modifiers included in the polymer structure is formed.

As a result, the modulus of elasticity of the composite is reached up to 50 GPa, tensile strength up to 900 MPa, breaking stress at bending up to 1200 MPa, in combination with heat resistance under load up to 320 ° C. The coefficient of linear thermal expansion is 20-80 μm / (m · ° C). Swelling in oil products 0.5-5% of the mass .. for 30 days at 25 ° C.

The composite material is obtained using the claimed composition to obtain a polymer matrix in the following way.

A polymer matrix is prepared in a separate container: dicyclopentadiene (DCPD), a stabilizer and a polymer modifier are mixed, then the mixture is heated to a temperature of 60-180 ° C and kept at a given temperature for 2-360 minutes, after cooling, a radical initiator, a modifying additive and a catalyst are introduced in an inert solvent (methylene chloride, toluene, tetrahydrofuran). After adding the catalyst, the solution is stirred for a certain time at a given temperature. The resulting solution is impregnated with a reinforcing carbon-containing inorganic filler and polymerization is carried out by heating in the mold to a temperature of 120-300 ° C and holding at this temperature from 1 to 300 minutes. Moreover, the reinforcing carbon-containing material before its use is treated by holding it in an aqueous or aqueous-alcoholic 0.1-1.5% solution of an organosilicon modifier (sizing) at a pH of 4.2-4.7 for 10-120 minutes and drying at a temperature of 90 -120 ° C.

The resulting composite material is tested according to the following indicators:

Glass transition temperature (Tg):

- A from 251 to 350 ° C

- B from 191 to 250 ° C

- B 141 to 190 ° C

- D from 80 to 140 ° C

Flexural modulus (E), GPa:

- And more than 40

- B from 20 to 40

- B from 10 to 20

- G from 1 to 10

Bending stress at maximum load (GOST 4648), MPa:

- And more than 1000

- B from 800 to 1000

- B from 500 to 800

- g less than 500

Tensile Strength (GOST 11262), MPa:

- And more than 600

- B from 300 to 600

- In from 100 to 300

- g less than 100

This technical solution is illustrated by the following examples:

Example 1

Obtaining a composite material having the composition: carbon-containing inorganic filler - twill weaving carbon fabric, density 204 g / m (60 mass ..%); polymer matrix - (39.95 mass ..%); organosilicon sizing - vinyltrimethoxysilane (0.05% of the mass ..). The polymer matrix in the material has the following composition: polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane (0.05 mass ..%), tris (2,4-di-tert -butylphenyl) phosphite (0.05 mass ..%), polymer modifiers - ENB (2.55 mass ..%), allyl methacrylate (0.42 mass ..%), radical initiator di-tert-butyl peroxide (0.85 mass ..%), the modifying additive is 2,4-toluene diisocyanate (7.5 mass ..%), 2-hydroxyethyl methacrylate (7.5 mass ..%), PDCPD (81.08%).

The material of this composition is prepared as follows. A mixture of DCPD (81.074 mass ..%), polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane (0.05 mass ..%), tris (2,4-di tert-butylphenyl) phosphite (0.05 mass ..%), modifiers: ENB (2.55 mass ..%), allyl methacrylate (0.42 mass ..%) is heated to a temperature of 60 ° C and incubated for 2 min, cooled to a temperature of 20 ° C, add a radical initiator: di-tert-butyl peroxide (0.85 wt ..%) and a modifying additive: 2,4-toluene diisocyanate (7.5 wt ..%), 2-hydroxyethyl methacrylate ( 7.5 mass ..%). With stirring, add a solution of catalyst N (0.006% by mass ..) in methylene chloride, incubated for 120 minutes. The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a trimethoxyvinylsilane-based sizing agent. The sample is heated to a temperature of 300 ° C and maintained at a given temperature for 1 min. A solid sample is obtained: Tg (B), e (B), bending stress at maximum load (B), tensile strength (B).

Example 2

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 204 g / m ² (60 wt ..%); polymer matrix - (39.94 mass ..%); organosilicon sizing - vinyltrimethoxysilane (0.06 mass ..%). The polymer matrix in the material has the following composition: PDCPD (81.08 mass ..%), polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxy dihydrocinnamate)] methane (0.05 mass ..% ), tris (2,4-di-tert-butylphenyl) phosphite (0.05 mass ..%), polymeric modifiers - ENB (2.55 mass ..%), allyl methacrylate (0.42 mass ..%), radical initiator di-tert-butyl peroxide (0.85 mass ..%), the modifying additive is 2,4-toluene diisocyanate (7.5 mass ..%), 2-hydroxyethyl methacrylate (7.5 mass ..%).

The material of this composition is prepared as follows. A mixture of DCPD (81.073 mass ..%), polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane (0.05 mass ..%), tris (2,4-di tert-butylphenyl) phosphite (0.05 mass ..%), modifiers: ENB (2.55 mass ..%), allyl methacrylate (0.42 mass ..%) is heated to a temperature of 60 ° C and held for 60 min, cooled to a temperature of 20 ° C, add the di-tert-butyl peroxide radical initiator (0.85 mass ..%) and a modifying additive: 2,4-toluene diisocyanate (7.5 mass ..%), 2-hydroxyethyl methacrylate (7 5 mass ..%). With stirring, add a solution of catalyst N1 (0.007 mass ..%), in methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a trimethoxyvinylsilane-based sizing agent. The sample is heated to a temperature of 300 ° C and maintained at a given temperature for 5 minutes. A solid sample is obtained: Tg (B), E (B), bending stress at maximum load (B), tensile strength (B).

Example 3

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon twill weave with a density of 204 g / m ² (60 wt ..%); polymer matrix - (39.99 mass ..%); organosilicon sizing - vinyltrimethoxysilane (0.01% of the mass ..). The polymer matrix in the material has the following composition: PDCPD (76.08 mass ...%), polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 mass .. %) and tris (2,4-di-tert-butylphenyl) phosphite (0.3 mass ..%), modifiers - ENB (2.3 mass ..%), ethoxylated bisphenol A dimethacrylate (3.0 mass .. %) and epoxy resin ED-20 (1.5 mass ..%), the radical initiator dicumyl peroxide (1.52% mass ..), the modifying additive is 2,4-toluene diisocyanate (7.5 mass ..%), 2 -hydroxyethyl methacrylate (7.5 mass ..%).

The material of this composition is prepared as follows. A mixture of DCPD (76.072 mass ..%), polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 mass ..%) and tris (2,4-di tert-butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.3 wt.%), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and epoxy resin ED-20 (1, 5 wt.%) Is heated to a temperature of 120 ° C and incubated for 60 min, cooled to a temperature of 25 ° C and a radical initiator, dicumyl peroxide (1.52 wt.%), Is added, modifying the additive: 2,4-toluene diisocyanate (7, 5 wt.%) And 2-hydroxyethyl methacrylate (7.5 wt.%). With stirring, a solution of catalyst N2 (0.008 wt.%) In toluene is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a sizing based on vinyltrimethoxysilane. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (B), E (B), bending stress at maximum load (B), tensile strength (B).

Example 4

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - vinyltrimethoxysilane (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (76.08 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.3 wt.), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and epoxy resin ED- 20 (1.5 wt.%), Radical initiator dicumyl peroxide (1.52 wt.%), Modifying additive - 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%) .

The material of this composition is prepared as follows. A mixture of DCPD (76.073 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.3 wt.%), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and epoxy resin ED-20 (1.5 wt.%) ) heated to a temperature of 120 ° C and incubated for 60 min, cooled to a temperature of 50 ° C and add the radical initiator dicumyl peroxide (1.52 wt.%), modifying additive: 2,4-toluene diisocyanate (7.5 wt.%) and 2-hydroxyethyl methacrylate (7.5 wt.%). With stirring, a solution of catalyst N3 (0.007 wt.%) In toluene is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a sizing based on vinyltrimethoxysilane. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 35 minutes. A solid sample is obtained: Tg (C), E (B), bending stress at maximum load (B), tensile strength (B).

Example 5

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - 3-methacryloxypropyltrimethoxysilane (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (76.08 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.3 wt.%), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and ED epoxy -20 (1.5 wt.%), Radical initiator dicumyl peroxide (1.52 wt.%), Modifying additive - 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%) )

The material of this composition is prepared as follows. A mixture of DCPD (76.072 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.3 wt.%), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and epoxy resin ED-20 (1.5 wt.%) ) heated to a temperature of 120 ° C and incubated for 60 minutes, cooled to a temperature of 25 ° C and add the radical initiator dicumyl peroxide (1.52 wt.%), modifying additive: 2,4-toluene diisocyanate (7.5 wt.%) and 2-hydroxyethyl methacrylate (7.5 wt.%). With stirring, a solution of catalyst N4 (0.008 wt.%) In toluene is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a sizing based on 3-methacryloxypropyltrimethoxysilane. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (C), E (B), bending stress at maximum load (B), tensile strength (B).

Example 6

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - 3-methacryloxypropyltrimethoxysilane (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (76.08 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.3 wt.%), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and ED epoxy -20 (1.5 wt.%), Radical initiator dicumyl peroxide (1.52 wt.%), Modifying additive - 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%) )

The material of this composition is prepared as follows. A mixture of DCPD (76.073 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.3 wt.%), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and epoxy resin ED-20 (1.5 wt.%) ) heated to a temperature of 120 ° C and incubated for 60 minutes, cooled to a temperature of 25 ° C and add the radical initiator dicumyl peroxide (1.52 wt.%), modifying additive: 2,4-toluene diisocyanate (7.5 wt.%) and 2-hydroxyethyl methacrylate (7.5 wt.%). With stirring, a solution of catalyst N5 (0.007 wt.%) In toluene is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a sizing based on 3-methacryloxypropyltrimethoxysilane. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (C), E (B), bending stress at maximum load (B), tensile strength (B).

Example 7

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - 5-trialkoxysilyl-2-norbornene (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (75.98 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.3 wt.%), 5-trialkoxysilyl-2-norbornene (4.6 wt.%), the radical initiator is dicumyl peroxide (1.52 wt.%), the modifying additive is 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (75.972 wt.% Wt.), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di -t-butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.3 wt.%), 5-trialkoxysilyl-2-norbornene (4.6 wt.%) is heated to a temperature of 120 ° C and maintained for 60 min, cooled to a temperature of 25 ° C and add the radical initiator dicumyl peroxide (1.52 wt.%), modifying additive: 2,4-toluene diisocyanate (7.5 wt.%) and 2-hydroxyethyl methacrylate (7.5 wt. .%). With stirring, a solution of catalyst N5 (0.008 wt.%) In methylene chloride is added; the resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (B), E (B), bending stress at maximum load (A), tensile strength (B).

Example 8

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - 5-trialkoxysilyl-2-norbornene (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (75.98 wt.%), Polymer stabilizers-tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.3 wt.%), 5-trialkoxysilyl-2-norbornene (4.6 wt.%), the radical initiator is dicumyl peroxide (1.52 wt.%), the modifying additive is 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (75.973 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.3 wt.%), 5-trialkoxysilyl-2-norbornene (4.6 wt.%) is heated to a temperature of 120 ° C and incubated for 60 min, cooled to a temperature of 25 ° C and the radical initiator dicumyl peroxide (1.52 wt.%), Modifying additive: 2,4-toluene diisocyanate (7.5 wt.%) And 2-hydroxyethyl methacrylate (7.5 wt.%) Was added. ) With stirring, a solution of catalyst N1a (0.007 wt.%) In methylene chloride is added; the resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (B), E (B), bending stress at maximum load (A), tensile strength (B).

Example 9

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 204 g / m ² (60 wt.%); polymer matrix - (39 wt.%); organosilicon sizing - vinyltrimethoxysilane (1 wt.%). The polymer matrix in the material has the following composition: PDCPD (64.05 mass%), polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxy dihydrocinnamate)] methane (0.04 mass%), tris (2,4-di-tert-butylphenyl) phosphite (0.06 wt.%), a polymer modifier - ENB (20 wt.%), the radical initiator di-tert-butyl peroxide (0.85% wt.), modifying additive - 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (64.044 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane (0.04 wt.%), Tris (2,4-di-tert -butylphenyl) phosphite (0.06 wt.%), ENB modifier (20 wt.%) is heated to a temperature of 60 ° C and maintained for 360 minutes, cooled to a temperature of 20 ° C, the radical initiator di-tert-butyl peroxide ( 0.85 wt.%) And a modifying additive: 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%). With stirring, add a solution of catalyst N6a (0.006 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a trimethoxyvinylsilane-based sizing agent. The sample is heated to a temperature of 300 ° C and maintained at a given temperature for 1 min. A solid sample is obtained: Tg (B), E (B), bending stress at maximum load (C), tensile strength (C).

Example 10

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 204 g / m ² (60 wt.%); polymer matrix - (39 wt.%); organosilicon sizing - vinyltrimethoxysilane (1 wt.%). The polymer matrix in the material has the following composition: PDCPD (64.05 mass%), polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxy dihydrocinnamate)] methane (0.04 mass%), tris (2,4-di-tert-butylphenyl) phosphite (0.06 wt.%), a polymer modifier - ENB (20 wt.%), the radical initiator di-tert-butyl peroxide (0.85 wt.%), modifying additive - 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (64.044 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane (0.04 wt.%), Tris (2,4-di-tert -butylphenyl) phosphite (0.06 wt.%), modifier - ENB (20 wt.%) is heated to a temperature of 60 ° C and incubated for 300 min, cooled to a temperature of 20 ° C, the radical initiator di-tert-butyl peroxide is added (0.85 wt.%) And a modifying additive: 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%). With stirring, add a solution of catalyst N11a (0.006 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a trimethoxyvinylsilane-based sizing agent. The sample is heated to a temperature of 300 ° C and maintained at a given temperature for 1 min. A solid sample is obtained: Tg (B), E (B), bending stress at maximum load (C), tensile strength (C).

Example 11

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - vinyltrimethoxysilane (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (70.2 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (1.7 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (2.3 wt.%), modifiers - ENB (2.3 wt.%), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and ED epoxy -20 (1.5 wt.%), The radical initiator dicumyl peroxide (4 wt.%), The modifying additive is 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (70.193 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (1.7 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (2.3 wt.%), modifiers: ENB (2.3 wt.%), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and epoxy resin ED-20 (1.5 wt.%) ) heated to a temperature of 120 ° C and incubated for 60 min, cooled to a temperature of 25 ° C and add the radical initiator dicumyl peroxide (4 wt.%), modifying additive: 2,4-toluene diisocyanate (7.5 wt.%) and 2 -hydroxyethyl methacrylate (7.5 wt.%). With stirring, a solution of catalyst N16a (0.007 wt.%) In toluene is added; the resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on vinyltrimethoxysilane. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (B), E (B), bending stress at maximum load (B), tensile strength (B).

Example 12

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - vinyltrimethoxysilane (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (70.2 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (1.7 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (2.3 wt.%), modifiers - ENB (2.3 wt.%), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and ED epoxy -20 (1.5 wt.%), The radical initiator dicumyl peroxide (4 wt.%), The modifying additive is 2,4-toluene diisocyanate (7.5 wt.%), 2-hydroxyethyl methacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (70.193 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (1.7 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (2.3 wt.%), modifiers: ENB (2.3 wt.%), ethoxylated bisphenol A dimethacrylate (3.0 wt.%) and epoxy resin ED-20 (1.5 wt.%) ) heated to a temperature of 120 ° C and held for 60 minutes, cooled to a temperature of 25 ° C and add the radical initiator dicumyl peroxide (4 wt.%), modifying additive: 2,4-toluene diisocyanate (7.5 wt.%) and 2 -hydroxyethyl methacrylate (7.5 wt.%). With stirring, a solution of catalyst N1b (0.007 wt.%) In toluene is added; the resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on vinyltrimethoxysilane. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (B), E (B), bending stress at maximum load (B), tensile strength (B).

Example 13

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - 5-trialkoxysilyl-2-norbornene (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (75.98 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.3 wt.%), 5-trialkoxysilyl-2-norbornene (4.6 wt.%), radical initiators dicumyl peroxide (0.76 wt.%), 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), modifying additive - 2,4-toluene diisocyanate (7.5 wt.%), 2 -hydroxyethyl methacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (75.973 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.3 wt.%), 5-trialkoxysilyl-2-norbornene (4.6 wt.%) is heated to a temperature of 180 ° C and maintained for 60 min, cooled to 0 ° C and radical initiators added: dicumyl peroxide (0.76 wt.%), 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%) Modifying additive: 2,4- toluene diisocyanate (7.5 wt.%) and 2-hydroxyethyl methacrylate (7.5 wt.%). With stirring, a solution of catalyst N2a (0.007 wt.%) In methylene chloride is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a sizing agent based on 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 280 ° C and maintained at a predetermined temperature for 30 minutes. A solid sample is obtained: Tg (A), E (A), bending stress at maximum load (B), tensile strength (B).

Example 14

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - 5-trialkoxysilyl-2-norbornene (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (75.98 wt.%), Polymer stabilizers - tetra-kit [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.% ) and tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.3 wt.%), 5-trialkoxysilyl-2-norbornene (4.6 wt.%) ), radical initiators - dicumyl peroxide (0.76 wt.%), 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), a modifying additive - 2,4-toluene diisocyanate (7.5 wt.%) ), 2-hydroxyethyl methacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (75.973 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3% wt.) And tris (2,4-di-tert -butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.3 wt.%), 5-trialkoxysilyl-2-norbornene (4.6 wt.%) is heated to a temperature of 180 ° C and maintained for 60 min, cooled to a temperature of 25 ° C and radical initiators are added: dicumyl peroxide (0.76 wt.%), 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%) Modifying additive: 2,4- toluene diisocyanate (7.5 wt.%) and 2-hydroxyethyl methacrylate (7.5 wt.%). While stirring, a solution of N7a catalyst (0.007 wt.%) In methylene chloride is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a sizing agent based on 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 280 ° C and maintained at a given temperature for 30 minutes. A solid sample is obtained: Tg (A), E (A), bending stress at maximum load (B), tensile strength (B).

Example 15

Obtaining a composite material having the composition: carbon-containing inorganic filler — twill weaving carbon fabric, density 600 g / m ² (80 wt.%); polymer matrix - (19.95 wt.%); organosilicon sizing is a mixture of 3-methacryloxypropyltrimethoxysilane (0.025 wt.%) and 5-trialkoxysilyl-2-norbornene (0.025 wt.%). The polymer matrix in the material has the following composition: PDCPD (80.54 wt.%), Polymer stabilizers - 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.05 wt.%), N, N ′ -diphenyl-1,4-phenylenediamine (0.05 wt.%) polymer modifiers - ENB (2.50 wt.%), ethylene dimethacrylate (0.40 wt.%), radical initiators - dicumyl peroxide (0.73 wt.%) ) and 2,3-dimethyl-2,3-diphenylbutane (0.73 wt.%), the modifying additive is 1,6-hexanediisocyanate (7.5 wt.%), 2-hydroxypropylmethacrylate (7.5 wt.%) .

The material of this composition is prepared as follows. A mixture of DCPD (80.534 wt.%), A polymer stabilizer: 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.05 wt.%), N, N′-diphenyl-1,4-phenylenediamine ( 0.05 wt.%.), Modifiers: ENB (2.50 wt.%), Ethylene dimethacrylate (0.40 wt.%) Is heated to a temperature of 60 ° C and held for 360 minutes, cooled to a temperature of 20 ° C, radical initiators are added: dicumyl peroxide (0.73 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.73 wt.%) as well as a modifying additive: 1,6-hexanediisocyanate (7.5 wt.%) ), 2-hydroxypropylmethacrylate (7.5 wt.%). With stirring, add a solution of catalyst N12a (0.006 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on 3-methacryloxypropyltrimethoxysilane and 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 280 ° C and maintained at a predetermined temperature for 30 minutes. A solid sample is obtained: Tg (A), E (A), bending stress at maximum load (A), tensile strength (A).

Example 16

Obtaining a composite material having the composition: carbon-containing inorganic filler — twill weaving carbon fabric, density 600 g / m ² (80 wt.%); polymer matrix - (19.95 wt.%); organosilicon sizing is a mixture of 3-methacryloxypropyltrimethoxysilane (0.025 wt.%) and 5-trialkoxysilyl-2-norbornene (0.025 wt.%). The polymer matrix in the material has the following composition: PDCPD (80.54 wt.%), Polymer stabilizers - 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.05 wt.%), N, N ′ -diphenyl-1,4-phenylenediamine (0.05 wt.%) polymer modifiers: ENB (2.50% wt.), ethylene dimethacrylate (0.40 wt.%), radical initiators - dicumyl peroxide (0.73 wt.%) ) and 2,3-dimethyl-2,3-diphenylbutane (0.73 wt.%), the modifying additive is 1,6-hexanediisocyanate (7.5 wt.%), 2-hydroxypropylmethacrylate (7.5 wt.%) .

The material of this composition is prepared as follows. A mixture of DCPD (80.534 wt.%), A polymer stabilizer: 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.05 wt.%), N, N′-diphenyl-1,4-phenylenediamine ( 0.05 wt.%.), Modifiers: ENB (2.50 wt.%), Ethylene dimethacrylate (0.40 wt.%) Is heated to a temperature of 60 ° C and held for 360 minutes, cooled to a temperature of 20 ° C, radical initiators are added: dicumyl peroxide (0.73 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.73 wt.%), as well as a modifying additive: 1,6-hexanediisocyanate (7.5 wt. %), 2-hydroxypropylmethacrylate (7.5 wt.%). With stirring, add a solution of catalyst N17a (0.006 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on 3-methacryloxypropyltrimethoxysilane and 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 280 ° C and maintained at a given temperature for 30 minutes. A solid sample is obtained: Tg (A), E (A), bending stress at maximum load (A), tensile strength (A).

Example 17

Obtaining a composite material having the composition: carbon-containing inorganic filler — twill weaving carbon fabric, density 600 g / m ² (80 wt.%); polymer matrix - (19.95 wt.%); organosilicon sizing is a mixture of 3-thiopropyltrialkoxysilane (0.02 wt.%) and 5-trialkoxysilyl-2-norbornene (0.03 wt.%). The polymer matrix in the material has the following composition: PDCPD (80.48 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxy dihydrocinnamate)] methane (0.05 wt.%), tris (4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) isocyanurate (0.05 wt.%), polymer modifiers - ENB (2.50 wt.%), ethylene dimethacrylate (0.40 wt.%) , radical initiators are dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), the modifying additive is methylene bis (4,1-phenylene) diisocyanate (7 5 wt.%), 2-hydroxypropylmethacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (80.474 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane (0.05 wt.%), Tris (4-tert-butyl-3 -hydroxy-2,6-dimethylbenzyl) isocyanurate (0.05 wt.%), ENB modifiers (2.50 wt.%), ethylene dimethacrylate (0.40 wt.%) is heated to a temperature of 60 ° C and kept at for 360 min, cooled to a temperature of 20 ° C, radical initiators are added: dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), as well as a modifying additive: methylene bis (4,1-phenylene) diisocyanate (7.5 wt.%), 2-hydroxypropyl methacrylate (7.5 mass.%). With stirring, a solution of catalyst N2b (0.006 wt.%) In methylene chloride is added, kept for 100 minutes. The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on 3-thiopropyltrialkoxysilane (0.02 wt.%) And 5-trialkoxysilyl-2-norbornene (0.03 wt.%). The sample is heated to a temperature of 280 ° C and maintained at a predetermined temperature for 30 minutes. A solid sample is obtained: Tg (A), E (A), bending stress at maximum load (A), tensile strength (A).

Example 18

Obtaining a composite material having the composition: carbon-containing inorganic filler — twill weaving carbon fabric, density 600 g / m ² (80 wt.%); polymer matrix - (19.95 wt.%); organosilicon sizing is a mixture of 3-thiopropyltrialkoxysilane (0.02 wt.%) and 5-trialkoxysilyl-2-norbornene (0.03 wt.%). The polymer matrix in the material has the following composition: PDCPD (80.48 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxy dihydrocinnamate)] methane (0.05 wt.%), tris (4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) isocyanurate (0.05 wt.%), polymer modifiers - ENB (2.50 wt.%), ethylene dimethacrylate (0.40 wt.%) , the radical initiator is dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), the modifying additive is methylene bis (4,1-phenylene) diisocyanate (7.5 wt.%), 2-hydroxypropylmethacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (80.474 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane (0.05 wt.%), Tris (4-tert-butyl-3 -hydroxy-2,6-dimethylbenzyl) isocyanurate (0.05 wt.%), modifiers: ENB (2.50 wt.%), ethylene dimethacrylate (0.40 wt.%) is heated to a temperature of 60 ° C and maintained for 360 min, cooled to a temperature of 20 ° C, radical initiators are added: dicumyl peroxide (0.76 wt.%) And 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), As well as a modifying additive: methylene bis (4,1-phenylene) diisocyanate (7.5 wt.%), 2-hydroxypropyl acrylate (7.5 wt.%). With stirring, a solution of catalyst S3b (0.006 wt.%) In methylene chloride is added, kept for 100 minutes. The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on 3-thiopropyltrialkoxysilane and 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 280 ° C and maintained at a predetermined temperature for 30 minutes. A solid sample is obtained: Tg (A), E (A), bending stress at maximum load (A), tensile strength (A).

Example 19

Obtaining a composite material having the composition: carbon-containing inorganic filler — twill weaving carbon fabric, density 600 g / m ² (80 wt.%); polymer matrix - (19.95 wt.%); organosilicon sizing is a mixture of 3-thiopropyltrialkoxysilane (0.02 wt.%) and 5-trialkoxysilyl-2-norbornene (0.03 wt.%). The polymer matrix in the material has the following composition: PDCPD (80.48 wt.%), Polymer stabilizers - 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl ) benzene (0.05 wt.%), bis (2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.05 wt.%), polymeric modifiers - ENB (2.50 wt.%), ethylene dimethacrylate (0.40 wt.%), radical initiators - dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), the modifying additive is methylene bis ( 4,1-phenylene) diisocyanate (7.5 wt.%), Glycerin dimethacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (80.479 wt.%), Polymer stabilizers: 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene (0.05 wt.% ), bis (2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.05 wt.%), modifiers: ENB (2.50 wt.%), ethylene dimethacrylate (0.40 wt.%) is heated to a temperature of 60 ° C and maintained for 360 min, cooled to a temperature of 20 ° C, radical initiators are added: dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt. %), as well as a modifying additive: methylene bis (4,1-phenylene) diisocyanate (7.5 wt.%), glycerin dimethacrylate (7.5 wt.%). With stirring, add a solution of catalyst N3a (0.001 wt.%) In methylene chloride, incubated for 100 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on 3-thiopropyltrialkoxysilane (0.02 wt.%) And 5-trialkoxysilyl-2-norbornene (0.03 wt.%). The sample is heated to a temperature of 280 ° C and maintained at a predetermined temperature for 30 minutes. A solid sample is obtained: Tg (A), E (A), bending stress at maximum load (A), tensile strength (A).

Example 20

Obtaining a composite material having the composition: carbon-containing inorganic filler — twill weaving carbon fabric, density 600 g / m ² (80 wt.%); polymer matrix - (19.95 wt.%); organosilicon sizing is a mixture of 3-thiopropyltrialkoxysilane (0.02 wt.%) and 5-trialkoxysilyl-2-norbornene (0.03 wt.%). The polymer matrix in the material has the following composition: PDCPD (80.48 wt.%), Polymer stabilizers - 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl ) benzene (0.05 wt.%), bis (2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.05 wt.%), polymeric modifiers - ENB (2.50 wt.%), ethylene dimethacrylate (0.40 wt.%), radical initiators - dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), the modifying additive is methylene bis ( 4,1-phenylene) diisocyanate (7.5 wt.%), Glycerin dimethacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (80.479 wt.%), Polymer stabilizers: 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene (0.05 wt.% ), bis (2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.05 wt.%), modifiers: ENB (2.50 wt.%), ethylene dimethacrylate (0.40 wt.%) is heated to a temperature of 60 ° C and maintained for 360 min, cooled to a temperature of 20 ° C, radical initiators are added: dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt. %) as well as a modifying additive: methylene bis (4,1-phenylene) diisocyanate (7.5 wt.%), glycerin dimethacrylate (7.5 wt.%). With stirring, add a solution of the catalyst N8a (0.001 wt.%) In methylene chloride, incubated for 100 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on 3-thiopropyltrialkoxysilane and 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 280 ° C and maintained at a predetermined temperature for 30 minutes. A solid sample is obtained: Tg (A), E (A), bending stress at maximum load (A), tensile strength (A).

Example 21

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 600 g / m ² (70 wt.% Mass.); polymer matrix - (29.95 wt.%); organosilicon sizing is a mixture of 3-methacryloxypropyltrimethoxysilane (0.025 wt.%) and 5-trialkoxysilyl-2-norbornene (0.025 wt.%). The polymer matrix in the material has the following composition: PDCPD (81.2 wt.%), Polymer stabilizers - 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.05 wt.%), N, N ′ -diphenyl-1,4-phenylenediamine (0.05 wt.%) polymer modifiers - ENB (2.1 wt.%), ethylene dimethacrylate (0.34 wt.%), radical initiators - dicumyl peroxide (0.63 wt.%) ) and 2,3-dimethyl-2,3-diphenylbutane (0.63 wt.%), the modifying additive is 1,6-hexanediisocyanate (7.5 wt.%), 2-hydroxypropylmethacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (81.192 wt.%), Polymer stabilizers: 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.05 wt.%), N, N′-diphenyl-1,4-phenylenediamine ( 0.05% wt ..) modifiers: ENB (2.1 wt.%), Ethylene dimethacrylate (0.34 wt.%) Is heated to a temperature of 60 ° C and held for 360 minutes, cooled to a temperature of 20 ° C, add radical initiators: dicumyl peroxide (0.63 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.63 wt.%), as well as a modifying additive: 1,6-hexanediisocyanate (7.5 wt.%) ), 2-hydroxypropylmethacrylate (7.5 wt.%). With stirring, add a solution of catalyst N13a (0.008 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on 3-methacryloxypropyltrimethoxysilane and 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 280 ° C and maintained at a given temperature for 300 minutes. A solid sample is obtained: Tg (A), E (B), bending stress at maximum load (B), tensile strength (B).

Example 22

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 600 g / m ² (70 wt.%); polymer matrix - (29.95 wt.%); organosilicon sizing is a mixture of 3-methacryloxypropyltrimethoxysilane (0.025 wt.%) and 5-trialkoxysilyl-2-norbornene (0.025 wt.%). The polymer matrix in the material has the following composition: PDCPD (81.2 wt.%), Polymer stabilizers - 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.05 wt.%), N, N ′ -diphenyl-1,4-phenylenediamine (0.05 wt.%) polymer modifiers - ENB (2.1 wt.%), ethylene dimethacrylate (0.34 wt.%), radical initiators dicumyl peroxide (0.63 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.63 wt.%), the modifying additive is 1,6-hexanediisocyanate (7.5 wt.%), 2-hydroxypropylmethacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (81.192 wt.%), Polymer stabilizers: 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.05 wt.%), N, N′-diphenyl-1,4-phenylenediamine ( 0.05 wt.%) Modifiers: ENB (2.1 wt.%), Ethylene dimethacrylate (0.34 wt.%) Is heated to a temperature of 60 ° C and maintained for 360 minutes, cooled to a temperature of 20 ° C, radical initiators: dicumyl peroxide (0.63 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.63 wt.%), as well as a modifying additive: 1,6-hexanediisocyanate (7.5 wt.%) , 2-hydroxypropylmethacrylate (7.5 wt.%). With stirring, add a solution of catalyst N18a (0.008 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on 3-methacryloxypropyltrimethoxysilane and 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 280 ° C and maintained at a given temperature for 300 minutes. A solid sample is obtained: Tg (A), E (B), bending stress at maximum load (B), tensile strength (B).

Example 23

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 600 g / m ² (70 wt.%); polymer matrix - (29.95 wt.%); organosilicon sizing - 3-methacryloxypropyltrimethoxysilane (0.05 wt.%). The polymer matrix in the material has the following composition: PDCPD (80.53 wt.%), Polymer stabilizers - 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.03 wt.%), 2-tert- butyl-6- (5-chloro-2H-benzotriazol-2-yl) -4-methylphenol (0.04 wt.%), bis (1-methyl-2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.04 mass%), polymeric modifiers - ENB (2.50 mass%), diethylene glycol dimethacrylate (0.40 mass%), radical initiators - dicumyl peroxide (0.73 mass%) and 2.3- dimethyl-2,3-diphenylbutane (0.73 wt.%), the modifying additive is 2,4-toluene diisocyanate (7.5 wt.%), bisphenol A-glycidyl methacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (80.524 wt.%), Polymer stabilizers: 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.03 wt.%), 2-tert-butyl-6- (5-chloro- 2H-benzotriazol-2-yl) -4-methylphenol (0.04 wt.%), Bis (1-methyl-2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.04 wt.%) , modifiers: ENB (2.50 wt.%), diethylene glycol dimethacrylate (0.40 wt.%) is heated to a temperature of 160 ° C and held for 360 minutes, cooled to a temperature of 20 ° C, radical initiators are added: dicumyl peroxide (0, 73 wt.%) And 2,3-dimethyl-2,3-diphenylbutane (0.73 wt.%), As well as a modifying additive: 2,4-toluene diisocyanate (7 , 5 wt.%), Bisphenol A-glycidyl methacrylate (7.5 wt.%). With stirring, add a solution of catalyst N4b (0.006 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on 3-methacryloxypropyltrimethoxysilane. The sample is heated to a temperature of 280 ° C and maintained at a given temperature for 150 minutes. A solid sample is obtained: Tg (A), E (B), bending stress at maximum load (B), tensile strength (B).

Example 24

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 600 g / m ² (70 wt.%); polymer matrix - (29.95 wt.%); organosilicon sizing - 3-methacryloxypropyltrimethoxysilane (0.05 wt.%). The polymer matrix in the material has the following composition: PDCPD (80.53 wt.%), Polymer stabilizers - 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.03% wt.), 2-tert- butyl-6- (5-chloro-2H-benzotriazol-2-yl) -4-methylphenol (0.04 wt.%), bis (1-methyl-2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.04 mass%), polymeric modifiers - ENB (2.50 mass%), diethylene glycol dimethacrylate (0.40 mass%), radical initiators dicumyl peroxide (0.73 mass%) and 2,3-dimethyl -2,3-diphenylbutane (0.73 wt.%), The modifying additive is 2,4-toluene diisocyanate (7.5 wt.%), Bisphenol A-glycidyl methacrylate (7.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (80.524 wt.%), Polymer stabilizers: 2,6-di-tert-butyl-4- (dimethylamino) phenol (0.03 wt.% Mass.), 2-tert-butyl-6- (5- chloro-2H-benzotriazol-2-yl) -4-methylphenol (0.04 wt.%), bis (1-methyl-2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.04 wt. %), modifiers: ENB (2.50 wt.%), diethylene glycol dimethacrylate (0.40 wt.%) is heated to 160 ° C and held for 360 minutes, cooled to 20 ° C, radical initiators are added: dicumyl peroxide (0.73 mass %) and 2,3-dimethyl-2,3-diphenylbutane (0.73 wt.%) as well as a modifying additive: 2,4-toluene diisocyanate (7.5 wt.%), bisphenol A-glycidi methacrylate (7.5 wt.%). With stirring, add a solution of catalyst N4a (0.006 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on 3-methacryloxypropyltrimethoxysilane. The sample is heated to a temperature of 280 ° C and maintained at a given temperature for 150 minutes. A solid sample is obtained: Tg (A), E (B), bending stress at maximum load (B), tensile strength (B).

Example 25

Preparation of composite material having a composition of: carbon-containing inorganic filler - carbon cloth twilled density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - methacryloxypropyltrimethoxysilane (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (82.2 wt.%), Polymer stabilizers tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), Modifiers - ENB (2.5 wt.%), Trimethylolpropane trimethacrylate (3.3 wt.%) And epoxy resin ED-20 (1 , 6 wt.%), The radical initiator dicumyl peroxide (1.6 wt.%), The modifying additive is 2,4-toluene diisocyanate (4.1 wt.%), 2-hydroxyethyl methacrylate (4.1 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (82.193 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.5 wt.%), trimethylolpropane trimethacrylate (3.3 wt.%) and epoxy resin ED-20 (1.6 wt.%) are heated to temperature 120 ° C and maintained for 60 min, cooled to a temperature of 25 ° C and add the radical initiator dicumyl peroxide (1.6 wt.%), modifying additive: 2,4-toluene diisocyanate (4.1% wt.) and 2- hydroxyethyl methacrylate (4.1 wt.%). With stirring, a solution of catalyst N9a (0.007 wt.%) In toluene is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a methacryloxypropyltrimethoxysilane-based sizing agent. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (C), E (B), bending stress at maximum load (C), tensile strength (B).

Example 26

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - methacryloxypropyltrimethoxysilane (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (82.2 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.5 wt.%), trimethylolpropane trimethacrylate (3.3 wt.%) and epoxy resin ED-20 ( 1.6 wt.%), The radical initiator dicumyl peroxide (1.6 wt.%), The modifying additive is 2,4-toluene diisocyanate (4.1 wt.%), 2-hydroxyethyl methacrylate (4.1 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (82.193 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.5 wt.%), trimethylolpropane trimethacrylate (3.3 wt.%) and epoxy resin ED-20 (1.6 wt.%) are heated to temperature 120 ° C and maintained for 60 min, cooled to a temperature of 25 ° C and add the radical initiator dicumyl peroxide (1.6 wt.%), modifying additive: 2,4-toluene diisocyanate (4.1 wt.%) and 2- hydroxyethyl methacrylate (4.1 wt.%). With stirring, a solution of catalyst N14a (0.007 wt.%) In toluene is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a sizing based on methacryloxypropyltrimethoxysilane. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 35 minutes. A solid sample is obtained: Tg (C), E (B), bending stress at maximum load (C), tensile strength (B).

Example 27

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - vinyltrimethoxysilane (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (82.2 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.5 wt.%), trimethylolpropane trimethacrylate (3.3 wt.%) and epoxy resin ED-20 ( 1.6 wt.%), The radical initiator dicumyl peroxide (1.6 wt.%), The modifying additive is 2,4-toluene diisocyanate (4.1 wt.%), 2-hydroxyethyl methacrylate (4.1 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (82.193 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.5 wt.%), trimethylolpropane trimethacrylate (3.3 wt.%) and epoxy resin ED-20 (1.6 wt.%) are heated to temperature 120 ° C and maintained for 60 min, cooled to a temperature of 25 ° C and add the radical initiator dicumyl peroxide (1.6 wt.%), modifying additive - 2,4-toluene diisocyanate (4.1 wt.%) and 2- hydroxyethyl methacrylate (4.1 wt.%). With stirring, a solution of catalyst N19a (0.007 wt.%) In toluene is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a sizing based on vinyltrimethoxysilane. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (C), E (B), bending stress at maximum load (C), tensile strength (B).

Example 28

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - vinyltrimethoxysilane (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (82.2 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.5 wt.%), trimethylolpropane trimethacrylate (3.3 wt.%) and epoxy resin ED-20 ( 1.6 wt.%), The radical initiator dicumyl peroxide (1.6 wt.%), The modifying additive is 2,4-toluene diisocyanate (4.1 wt.%), 2-hydroxyethyl methacrylate (4.1 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (82.193 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert -butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.5 wt.%), trimethylolpropane trimethacrylate (3.3 wt.%) and epoxy resin ED-20 (1.6 wt.%) are heated to temperature 120 ° C and maintained for 60 min, cooled to a temperature of 25 ° C and add the radical initiator dicumyl peroxide (1.6 wt.%), modifying additive: 2,4-toluene diisocyanate (4.1 wt.%) and 2- hydroxyethyl methacrylate (4.1 wt.%). With stirring, a solution of catalyst N5b (0.007 wt.%) In toluene is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a sizing based on vinyltrimethoxysilane. The sample is heated to a temperature of 200 ° C and maintained at a predetermined temperature for 35 minutes. A solid sample is obtained: Tg (C), E (B), bending stress at maximum load (C), tensile strength (B).

Example 29

Preparation of composite material having a composition of: carbon-containing inorganic filler - carbon cloth twilled, density 600 g / m ² (70 wt.%); polymer matrix - (29.95 wt.%); organosilicon sizing - vinyl-tris (2-methoxyethoxy) silane (0.05 wt.%). The polymer matrix in the material has the following composition: PDCPD (85.19 wt.%), Polymer stabilizers - 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl ) benzene (0.05 wt.%), tris (nonylphenyl) phosphite (0.05 wt.%), polymer modifiers - ENB (2.5 wt.%), glycidyl methacrylate (0.4 wt.%), radical initiator dicumyl peroxide (0.85 wt.%), the modifying additive is 2,4-toluene diisocyanate (5.48 wt.%), 2-hydroxyethyl methacrylate (5.48 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (85.184 wt.%), Polymer stabilizers: 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene (0.05 wt.% ), tris (nonylphenyl) phosphite (0.05 wt.%), modifiers: ENB (2.5 wt.%), glycidyl methacrylate (0.4 wt.%) is heated to a temperature of 60 ° C and held for 360 minutes, it is cooled to a temperature of 20 ° C, the radical initiator dicumyl peroxide (0.85 wt.%) and a modifying additive are added: 2,4-toluene diisocyanate (5.48 wt.%), 2-hydroxyethyl methacrylate (5.48 wt.%). With stirring, add a solution of catalyst N5a (0.006 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on vinyl-tris (2-methoxyethoxy) silane. The sample is heated to a temperature of 200 ° C and maintained at a given temperature for 30 minutes. A solid sample is obtained: Tg (B), E (B), bending stress at maximum load (G), tensile strength (G).

Example 30

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 600 g / m ² (70 wt.%); polymer matrix - (29.95 wt.%); organosilicon sizing - vinyl-tris (2-methoxyethoxy) silane (0.05 wt.%). The polymer matrix in the material has the following composition: PDCPD (85.19 wt.%), Polymer stabilizers - 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl ) benzene (0.05 wt.%), tris (nonylphenyl) phosphite (0.05 wt.%), polymer modifiers - ENB (2.5 wt.%), glycidyl methacrylate (0.4 wt.%), radical initiator dicumyl peroxide (0.85 wt.%), the modifying additive is 2,4-toluene diisocyanate (5.48 wt.%), 2-hydroxyethyl methacrylate (5.48 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (85.184 wt.%), Polymer stabilizers: 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene (0.05 wt.% ), tris (nonylphenyl) phosphite (0.05 wt.%), modifiers: ENB (2.5 wt.%), glycidyl methacrylate (0.4 wt.%) is heated to a temperature of 60 ° C and held for 360 minutes, it is cooled to a temperature of 20 ° C, the radical initiator dicumyl peroxide (0.85 wt.%) and a modifying additive are added: 2,4-toluene diisocyanate (5.48 wt.%), 2-hydroxyethyl methacrylate (5.48 wt.%). With stirring, add a solution of catalyst N10a (0.006 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on vinyl-tris (2-methoxyethoxy) silane. The sample is heated to a temperature of 200 ° C and maintained at a given temperature for 30 minutes. A solid sample is obtained: Tg (B), E (B), bending stress at maximum load (G), tensile strength (G).

Example 31

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 600 g / m ² (70 wt.%); polymer matrix - (29.95 wt.%); organosilicon sizing is a mixture of 3-thiopropyltrialkoxysilane (0.02 wt.%) and 5-trialkoxysilyl-2-norbornene (0.03 wt.%). The polymer matrix in the material has the following composition: PDCPD (94.48 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.05 wt.%), bis (1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.05 wt.%), polymer modifiers - ENB (2.50 wt.%), ethylene dimethacrylate (0.40% wt. .), radical initiators are dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), the modifying additive is 2,4-toluene diisocyanate (0.5 wt. %), 2-hydroxyethyl methacrylate (0.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (94.474 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane (0.05 wt.%), Bis (1-octyloxy-2.2 , 6,6-tetramethyl-4-piperidinyl) sebacinate (0.05 wt.%), Modifiers: ENB (2.50 wt.%), Ethylene dimethacrylate (0.40 wt.%) Is heated to a temperature of 60 ° C and maintained within 60 min, cooled to a temperature of 20 ° C, radical initiators are added: dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), modifying additive - 2 4-toluylene diisocyanate (0.5 wt.%), 2-hydroxyethyl methacrylate (0.5 wt.%). With stirring, add a solution of catalyst N15a (0.006 wt.%) In methylene chloride, incubated for 100 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on 3-thiopropyltrialkoxysilane and 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 280 ° C and maintained at a predetermined temperature for 30 minutes. A solid sample is obtained: Tg (A), E (B), bending stress at maximum load (B), tensile strength (B).

Example 32

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 600 g / m ² (70 wt.%); polymer matrix - (29.95 wt.%); organosilicon sizing is a mixture of 3-thiopropyltrialkoxysilane (0.02 wt.%) and 5-trialkoxysilyl-2-norbornene (0.03 wt.%). The polymer matrix in the material has the following composition: PDCPD (94.48 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.05 wt.%), bis (1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.05 wt.%), polymer modifiers - ENB (2.50 wt.%), ethylene dimethacrylate (0.40% wt. .), radical initiators are dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), the modifying additive is 2,4-toluene diisocyanate (0.5 wt. %), 2-hydroxyethyl methacrylate (0.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (94.474 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane (0.05 wt.%), Bis (1-octyloxy-2.2 , 6,6-tetramethyl-4-piperidinyl) sebacinate (0.05 wt.%), Modifiers: ENB (2.50 wt.%), Ethylene dimethacrylate (0.40 wt.%) Is heated to a temperature of 60 ° C and maintained within 60 min, cooled to a temperature of 20 ° C, radical initiators are added: dicumyl peroxide (0.76 wt.%) and 2,3-dimethyl-2,3-diphenylbutane (0.76 wt.%), modifying additive - 2 4-toluylene diisocyanate (0.5 wt.%), 2-hydroxyethyl methacrylate (0.5 wt.%). With stirring, add a solution of catalyst N20a (0.006 wt.%) In methylene chloride, incubated for 100 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on 3-thiopropyltrialkoxysilane and 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 280 ° C and maintained at a predetermined temperature for 30 minutes. A solid sample is obtained: Tg (A), E (B), bending stress at maximum load (B), tensile strength (B).

Example 33

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 204 g / m ² (10 wt.%); polymer matrix - (89.95 wt.%); organosilicon sizing - N- [3- (trimethoxysilyl) propyl] -N ′ - (4-vinylbenzyl) ethylenediamine hydrochloride (0.05 wt.%). The polymer matrix in the material has the following composition: PDCPD (94.05 wt.%), Polymer stabilizers - diphenylamine (0.03 wt.%), Para-di-tert-butylphenylenediamine (0.04 wt.%), 2- ( 2H-benzotriazol-2-yl) -4,6-bis (1-methyl-1-phenyl) phenol (0.03 wt.%), Polymeric modifiers - ENB (2.50 wt.%), Divinylbenzene (1, 5 wt.%), The radical initiator 2,3-dimethyl-2,3-diphenylbutane (0.85 wt.%), The modifying additive is 2,4-toluene diisocyanate (0.5 wt.%), 2-hydroxyethylmethacrylate (0 , 5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (94.045 wt.%), Polymer stabilizers: diphenylamine (0.03 wt.%), Para-di-tert-butylphenylenediamine (0.04 wt.%), 2- (2H-benzotriazol-2-yl) - 4,6-bis (1-methyl-1-phenyl) phenol (0.03 wt.%), Modifiers: ENB (2.50 wt.%), Divinylbenzene (1.5 wt.%) Is heated to a temperature of 60 ° C and held for 360 min, cooled to a temperature of 20 ° C, add the radical initiator 2,3-dimethyl-2,3-diphenylbutane (0.85 wt.%) And a modifying additive - 2,4-toluene diisocyanate (0.5 wt.%), 2-hydroxyethyl methacrylate (0.5 wt.%). With stirring, add a solution of catalyst N1c (0.005 wt.%) In methylene chloride, incubated for 10 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on N- [3- (trimethoxysilyl) propyl] -N ′ - (4-vinylbenzyl) ethylenediamine hydrochloride. The sample is heated to a temperature of 150 ° C and maintained at a given temperature for 30 minutes. A solid sample is obtained: Tg (G), E (G), bending stress at maximum load (G), tensile strength (G).

Example 34

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 204 g / m ² (20 wt.%); polymer matrix - (79.95 wt.%); organosilicon sizing - N- [3- (trimethoxysilyl) propyl] -N ′ - (4-vinylbenzyl) ethylenediamine hydrochloride (0.05 wt.%). The polymer matrix in the material has the following composition: PDCPD (94.05 wt.%), Polymer stabilizers - diphenylamine (0.03 wt.%), Para-di-tert-butylphenylenediamine (0.04 wt.%), 2- ( 2H-benzotriazol-2-yl) -4,6-bis (1-methyl-1-phenyl) phenol (0.03 wt.%), Polymeric modifiers - ENB (2.50 wt.%), Divinylbenzene (1, 5 wt.%), The radical initiator 2,3-dimethyl-2,3-diphenylbutane (0.85 wt.%), The modifying additive is 2,4-toluene diisocyanate (0.5 wt.%), 2-hydroxyethylmethacrylate (0 , 5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (94.045 wt.%), Polymer stabilizers: diphenylamine (0.03 wt.%), Para-di-tert-butylphenylenediamine (0.04 wt.%), 2- (2H-benzotriazol-2-yl) - 4,6-bis (1-methyl-1-phenyl) phenol (0.03 wt.%), Modifiers: ENB (2.50 wt.%), Divinylbenzene (1.5 wt.%) Is heated to a temperature of 60 ° C and held for 360 min, cooled to a temperature of 20 ° C, add the radical initiator 2,3-dimethyl-2,3-diphenylbutane (0.85 wt.%) And a modifying additive - 2,4-toluene diisocyanate (0.5 wt.%), 2-hydroxyethyl methacrylate (0.5 wt.%). With stirring, add a solution of catalyst N4b (0.005 wt.%) In methylene chloride, incubated for 10 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing based on N- [3- (trimethoxysilyl) propyl] -N ′ - (4-vinylbenzyl) ethylenediamine hydrochloride. The sample is heated to a temperature of 150 ° C and maintained at a given temperature for 300 minutes. A solid sample is obtained: Tg (G), E (G), bending stress at maximum load (G), tensile strength (G).

Example 35

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 204 g / m ² (5 wt.%); polymer matrix - (94.95 wt.%); organosilicon sizing - 3-aminopropyltriethoxysilane (0.05 wt.%). The polymer matrix in the material has the following composition: PDCPD (94.05 wt.%), Polymer stabilizers - 3,5-di-tert-butyl-4-hydroxyanisole (0.05 wt.%), N, N′-methylenebis ( 2,6-di-tert-butylphenol) (0.05 wt.%), Polymer modifiers - ENB (2.50 wt.%), Diisopropenylbenzene (1.5 wt.%), Radical initiator triphenylmethane (0.85 wt. .%), the modifying additive is 2,4-toluene diisocyanate (0.5 wt.%), 2-hydroxyethyl methacrylate (0.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (94.045 wt.%), Polymer stabilizers: 3,5-di-tert-butyl-4-hydroxyanisole (0.05 wt.%), N, N′-methylenebis (2,6-di-tert-butylphenol ) (0.05 wt.%), Modifiers: ENB (2.50 wt.%), Diisopropenylbenzene (1.5 wt.%) Is heated to a temperature of 60 ° C and held for 360 minutes, cooled to a temperature of 20 ° C , the radical initiator triphenylmethane (0.85 wt.%) and the modifying additive - 2,4-toluene diisocyanate (0.5 wt.%), 2-hydroxyethyl methacrylate (0.5 wt.%) are added. With stirring, add a solution of catalyst N (0.005 wt.%) In methylene chloride, incubated for 10 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on 3-aminopropyltriethoxysilane. The sample is heated to a temperature of 150 ° C and maintained at a given temperature for 30 minutes. A solid sample is obtained: Tg (G), E (G), bending stress at maximum load (G), tensile strength (G).

Example 36

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving, density 204 g / m ² (5 wt.%); polymer matrix - (94.95 wt.%); organosilicon sizing - 3-aminopropyltriethoxysilane (0.05 wt.%). The polymer matrix in the material has the following composition: PDCPD (94.05 wt.%), Polymer stabilizers - 3,5-di-tert-butyl-4-hydroxyanisole (0.05 wt.%), N, N′-methylenebis ( 2,6-di-tert-butylphenol) (0.05 wt.%), Polymer modifiers - ENB (2.50 wt.%), Diisopropenylbenzene (1.5 wt.%), Radical initiator triphenylmethane (0.85 wt. .%), the modifying additive is 2,4-toluene diisocyanate (0.5 wt.%), 2-hydroxyethyl methacrylate (0.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (94.045 wt.%), Polymer stabilizers: 3,5-di-tert-butyl-4-hydroxyanisole (0.05 wt.%), N, N′-methylenebis (2,6-di-tert-butylphenol ) (0.05 wt.%), Modifiers: ENB (2.50 wt.%), Diisopropenylbenzene (1.5 wt.%) Is heated to a temperature of 60 ° C and held for 360 minutes, cooled to a temperature of 20 ° C , the radical initiator triphenylmethane (0.85 wt.%) and the modifying additive - 2,4-toluene diisocyanate (0.5 wt.%), 2-hydroxyethyl methacrylate (0.5 wt.%) are added. With stirring, add a solution of catalyst N1 (0.005 wt.%) In methylene chloride, incubated for 10 minutes The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on 3-aminopropyltriethoxysilane. The sample is heated to a temperature of 150 ° C and maintained at a given temperature for 30 minutes. A solid sample is obtained: Tg (G), E (G), bending stress at maximum load (G), tensile strength (G).

Example 37

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (5 wt.%); polymer matrix - (94.99 wt.%); organosilicon sizing - vinyltrimethoxysilane - (0.01 wt.%) The polymer matrix in the material has the following composition: PDCPD (94.4 wt.%), polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4- hydroxyhydrocinnamate)] methane (0.05 wt.%), tris (2,4-di-tert-butylphenyl) phosphite (0.05 wt.%), polymer modifiers - ENB (3 wt.%), butylene glycol dimethacrylate (0, 5 wt.%), The radical initiator dicumyl peroxide (1 wt.%), The modifying additive is 2,4-toluene diisocyanate (0.5 wt.%), 2-hydroxyethyl methacrylate (0.5 wt.%).

The material of this composition is prepared as follows. A mixture of DCPD (94.393 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.05 wt.%), Tris (2,4-di-tert -butylphenyl) phosphite (0.05 wt.%), modifiers: ENB (3 wt.%), butylene glycol dimethacrylate (0.5 wt.%) is heated to 60 ° С and held for 360 minutes, cooled to 20 ° С radical initiator is added dicumyl peroxide (1% wt.) and a modifying additive - 2,4-toluene diisocyanate (0.5 wt.%), 2-hydroxyethyl methacrylate (0.5 wt.%). With stirring, add a solution of catalyst N3 (0.007 wt.%) In methylene chloride, incubated for 120 minutes The resulting solution is impregnated with a reinforcing filler: treated with a sizing carbon fabric. The sample is heated to a temperature of 200 ° C and maintained at a given temperature for 30 minutes. A solid sample is obtained: Tg (B), E (G), bending stress at maximum load (G), tensile strength (G).

Example 38

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - vinyltrimethoxysilane (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (91.17 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.4 wt.%), tris (2,4-di-tert-butylphenyl) phosphite (0.1 wt.%) and bis (2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.5 wt.%), modifiers - ENB (3 wt.%), Tricyclodecane dimethanol dimethacrylate (1.9 wt.%), Radical initiator dicumyl peroxide (0.93 wt.%), Modifying additive - 2,4-toluene diisocyanate (1 wt.%), 2-hydroxyethyl methacrylate (1 mass%).

The material of this composition is prepared as follows. A mixture of DCPD (91.151 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.4 wt.%), Tris (2,4-di-tert -butylphenyl) phosphite (0.1 wt.%) and bis (2,2,6,6-tetramethyl-4-piperidinyl) sebacinate (0.5 wt.%), modifiers: ENB (3 wt.%), tricyclodecane dimethanol dimethacrylate (1.9 wt.%) Is heated to a temperature of 150 ° C and maintained for 40 minutes, cooled to a temperature of 20 ° C, radical initiator dicumyl peroxide (0.93 wt.%) And a modifying additive - 2,4-toluene diisocyanate ( 1 wt.%), 2-hydroxyethyl methacrylate (1 wt.%). With stirring, a solution of catalyst N18a (0.019 wt.%) In methylene chloride is added. The resulting solution is impregnated with a reinforcing filler: carbon fabric treated with a sizing agent based on vinyltrimethoxysilane. The sample is heated to a temperature of 200 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (C), E (B), bending stress at maximum load (B), tensile strength (B).

Example 39

Obtaining a composite material having the composition: carbon-containing inorganic filler - carbon fabric twill weaving with a density of 204 g / m ² (60 wt.%); polymer matrix - (39.99 wt.%); organosilicon sizing - 5-trialkoxysilyl-2-norbornene (0.01 wt.%). The polymer matrix in the material has the following composition: PDCPD (88.65 wt.%), Polymer stabilizers - tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di-tert-butylphenyl) phosphite (0.3 wt.%), modifiers - ENB (2.3 wt.% wt.), 5-trialkoxysilyl-2-norbornene (4.6 wt.%) ), the radical initiator is 2,3-dimethyl-2,3-diphenylbutane (0.85 wt.%), the modifying additive is 2,4-toluene diisocyanate (1.5 wt.%), 2-hydroxyethyl methacrylate (1.5 wt. .%).

The material of this composition is prepared as follows. A mixture of DCPD (88.63 wt.%), Polymer stabilizers: tetrakis [methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane (0.3 wt.%) And tris (2,4-di -t-butylphenyl) phosphite (0.3 wt.%), modifiers: ENB (2.3 wt.%), 5-trialkoxysilyl-2-norbornene (4.6 wt.%) is heated to a temperature of 120 ° C and maintained for 60 min, cooled to a temperature of 25 ° C and add a radical initiator - 2,3-dimethyl-2,3-diphenylbutane (0.85 wt.%) and a modifying additive: 2,4-toluene diisocyanate (1.5 wt. %) and 2-hydroxyethyl methacrylate (1.5 wt.%). With stirring, a solution of catalyst N20a (0.02 mass%) in methylene chloride is added, the reinforcing filler is impregnated with the resulting solution: carbon fabric treated with a sizing agent based on 5-trialkoxysilyl-2-norbornene. The sample is heated to a temperature of 220 ° C and maintained at a given temperature for 40 minutes. A solid sample is obtained: Tg (G), E (B), bending stress at maximum load (B), tensile strength (B).

This invention allows to obtain composite materials with high mechanical properties, thermal and chemical stability while reducing catalyst consumption and thermal control of the beginning of the polymerization process. These effects are provided by sets of essential features, special properties of the catalyst, which at a given temperature and quantity activates the polymerization of dicyclopentadiene and the physicochemical interaction with it of the listed modifying additives with the formation of polydicyclopentadiene with the corresponding modifiers included in the polymer structure.

Claims (6)

1. The composition for preparing a polymer matrix containing polydicyclopentadiene to obtain a composite material contains the following components, wt.%:
polymer modifier 0.5-20.0 radical initiator 0.1-4.0 polymer stabilizer 0.1-4.0 modifying additive 1.0-15.0 ruthenium metathesis catalyst 0.001-0.02 polymerization of dicyclopentadiene dicyclopentadiene not less than 98% purity rest,
wherein the polymeric modifier as it contains ethylidene norbornene (ENB) or cyclopentadiene oligomers, acrylic, methacrylic, styrene, silicone and epoxy monomers selected from: allyl methacrylate, glycidyl methacrylate, etilendimetakrilat, diethylene glycol dimethacrylate, butilenglikoldimetakrilat, tritsiklodekandimetanoldimetakrilat, ethoxylated bisphenol A dimethacrylate, trimethylolpropane trimethacrylate, 3- methacryloxypropyltrimethoxysilane, vinyltrimethoxysilane, 5-trialkoxysilyl-2-norbornene, divinylbenzene , diisopropenylbenzene or diane epoxy resin or mixtures thereof, as a radical initiator it contains: di-tert-butyl peroxide, dicumyl peroxide, 2,3-dimethyl-2,3-diphenyl-butane or triphenylmethane or mixtures thereof, it contains a polymer stabilizer : tetra-kit [methylene (3,5-di-tert-butyl-4-hydroxydihydrocinnamate)] methane, 2,6-di-tert-butyl-4- (dimethylamino) phenol, 1,3,5-trimethyl-2 4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene, tris (4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) isocyanurate, 3,5-di-tert -butyl-4-hydroxyanisole, 4,4′-methylenebis (2,6-di-tr et-butylphenol), diphenylamine, para-di-tert-butylphenylenediamine, N, N′-diphenyl-1,4-phenylenediamine, tris (2,4-di-tert-butylphenyl) phosphite, tris (nonylphenyl) phosphite, bis ( 2,2,6,6-tetramethyl-4-piperidinyl) sebacinate, bis (1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) sebacinate, bis (1-methyl-2,2,6, 6-tetramethyl-4-piperidinyl) sebacinate, 2-tert-butyl-6- (5-chloro-2H-benzotriazol-2-yl) -4-methylphenol, 2- (2H-benzotriazol-2-yl) -4, 6-bis (1-methyl-1-phenyl) phenol or mixtures thereof, and as a modifying additive - a mixture in equal proportions of diisocyanate and hydroxymethacrylate. 2. The composition according to claim 1, characterized in that the diisocyanate is selected from the group: 2,4-toluene diisocyanate, 1,6-hexanediisocyanate, methylene bis (4,1-phenylene) diisocyanate, and hydroxymethacrylate is selected from the group: 2-hydroxyethyl methacrylate , 2-hydroxypropyl methacrylate, glycerin dimethacrylate, bisphenol A-glycidyl methacrylate. 3. The composite material based on polydicyclopentadiene contains a carbon-containing inorganic filler, an organosilicon modifier, and a polymer matrix containing polydicyclopentadiene according to any one of claims 1 to 2 with the following components, wt.%:
organosilicon modifier 0.01-1.0 carbon-containing inorganic filler 5.0-80.0 a polymer matrix containing polydicyclopentadiene, rest, according to any one of paragraphs 1.2
moreover, vinyltrimethoxysilane, vinyl-tris (2-methoxyethoxy) silane, 3-methacryloxypropyltrimethoxysilane, 3-thiopropyltriethoxysilane, 3-thiopropyltrialkoxysilane, 5-trialkoxysilyl-2-norbenene or ′ - (4-vinylbenzyl) ethylenediamine hydrochloride or mixtures thereof, and carbon fibers, roving and woven materials based on them are used as carbon-containing inorganic filler. 4. The composite material according to claim 3, characterized in that the diisocyanate is selected from the group: 2,4-toluene diisocyanate, 1,6-hexanediisocyanate, methylene bis (4,1-phenylene) diisocyanate, and hydroxymethacrylate is selected from the group: 2- hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, glycerin dimethacrylate, bisphenol A-glycidyl methacrylate. 5. A method of producing a composite material based on polydicyclopentadiene according to any one of claims 3 to 4, characterized in that the polymer matrix according to any one of claims 1 to 2 is prepared by mixing dicyclopentadiene with a polymer stabilizer and a modifier, heating the resulting mixture to a temperature of 60-180 ° C, holding the mixture at a given temperature for 2-360 minutes and cooling it to a temperature of 0 to 50 ° C, subsequent mixing with a radical initiator, a modifying additive and a catalyst, and mixing the mixture, the resulting matrix inyayut with carbonaceous inorganic filler pretreated with a silicone modifier, followed by polymerization of the composite by heating at a temperature range of 120 to 300 ° C and held at this temperature for 1 to 300 minutes. 6. The method according to claim 5, characterized in that the carbon-containing inorganic filler is treated by exposure to an aqueous or aqueous-alcoholic 0.1-1.5% solution of an organosilicon modifier at a pH of 4.2-4.7 for 10-120 minutes and drying at a temperature of 90-120 ° C.