RU2318753C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2318753C1
RU2318753C1 RU2006135707/03A RU2006135707A RU2318753C1 RU 2318753 C1 RU2318753 C1 RU 2318753C1 RU 2006135707/03 A RU2006135707/03 A RU 2006135707/03A RU 2006135707 A RU2006135707 A RU 2006135707A RU 2318753 C1 RU2318753 C1 RU 2318753C1
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RU
Russia
Prior art keywords
glaze
cao
mgo
sio
seo
Prior art date
Application number
RU2006135707/03A
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Russian (ru)
Inventor
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006135707/03A priority Critical patent/RU2318753C1/en
Application granted granted Critical
Publication of RU2318753C1 publication Critical patent/RU2318753C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: technology of silicates; composition of glazes used in manufacture of decorative tiles.
SUBSTANCE: proposed glaze contains the following components, mass-%: SiO2, 50.0-54.0; Al2O3, 2.0-4.0; CaO, 13.0-17.0; MgO, 1.0-2.0; B2O3, 6.0-7.0; Fe2O3, 0.5-1.0; K2O, 3.5-4.5; SeO2, 1.5-2.5; ZnO, 8.0-10.0; TiO2, 5.0-7.0.
EFFECT: enhanced freeze resistance of glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов, в частности к составам глазурей, используемых в производстве облицовочной плитки.The invention relates to the field of technology of silicates, in particular to compositions of glazes used in the manufacture of tiles.

Известна глазурь, содержащая, мас.%: SiO2 49,79-54,3; MgO 0,25-0,28; Fe2O3 1,62-2,05; Al2O3 11,71-13,6; Na2O 2,13-3,0; B2O3 7,11-8,19; CaO 18,68-22,4; K2O 2,22-2,58; SO3 0,03-0,05 /1/.Known glaze containing, wt.%: SiO 2 49,79-54,3; MgO 0.25-0.28; Fe 2 O 3 1.62-2.05; Al 2 O 3 11.71-13.6; Na 2 O 2,13-3,0; B 2 O 3 7.11-8.19; CaO 18.68-22.4; K 2 O 2.22-2.58; SO 3 0.03-0.05 / 1 /.

Известна глазурь, содержащая, мас.%: SiO2 49,08-53,51; Al2O3 8,84-10,86; CaO 16,39-19,96; MgO 0,66-1,64; B2O3 7,6-8,34; Fe2O3 0,5-0,75; K2O 0,37-1,05; Na2O 7,08-9,34; SeO2 1,29-2,56; F' 0,69-1,42 /2/.Known glaze containing, wt.%: SiO 2 49,08-53,51; Al 2 O 3 8.84-10.86; CaO 16.39-19.96; MgO 0.66-1.64; B 2 O 3 7.6-8.34; Fe 2 O 3 0.5-0.75; K 2 O 0.37-1.05; Na 2 O 7.08-9.34; SeO 2 1.29-2.56; F '0.69-1.42 / 2 /.

Цель изобретения - повышение морозостойкости глазури.The purpose of the invention is to increase frost resistance of glaze.

Цель достигается тем, что в состав глазури дополнительно вводят ZnO и TiO2 при следующем соотношении компонентов, мас.%: SiO2 50,0-54,0; Al2O3 2,0-4,0; CaO 13,0-17,0; MgO 1,0-2,0; B2O3 6,0-7,0; Fe2O3 0,5-1,0; K2O 3,5-4,5; SeO2 1,5-2,5; ZnO 8,0-10,0; TiO2 5,0-7,0.The object is achieved in that the glaze composition is further administered ZnO and TiO 2, with the following component ratio, wt%: SiO 2 50,0-54,0;. Al 2 O 3 2.0-4.0; CaO 13.0-17.0; MgO 1.0-2.0; B 2 O 3 6.0-7.0; Fe 2 O 3 0.5-1.0; K 2 O 3.5-4.5; SeO 2 1.5-2.5; ZnO 8.0-10.0; TiO 2 5.0-7.0.

B таблице приведены составы глазури.The table shows the compositions of the glaze.

ТаблицаTable СоставStructure Компоненты, мас.%:Components, wt.%: Морозостойкость, циклыFrost resistance cycles SiO2 SiO 2 Al2O3 Al 2 O 3 CaOCao MgOMgO B2O3 B 2 O 3 Fe2O3 Fe 2 O 3 K2OK 2 O SeO2 Seo 2 ZnOZno TiO2 TiO 2 1one 50,050,0 4,04.0 17,017.0 1,01,0 7,07.0 1,01,0 3,53,5 1,51,5 8,08.0 7,07.0 200-230200-230 22 52,052.0 3,03.0 15,515,5 1,71.7 6,06.0 0,80.8 4,04.0 2,02.0 9,09.0 6,06.0 200-230200-230 33 54,054.0 2,02.0 13,013.0 2,02.0 6,56.5 0,50.5 4,54,5 2,52,5 10,010.0 5,05,0 200-230200-230

Компоненты глазури сплавляют при 1300°С, расплат гранулируют в воду. Фритту размалывают мокрым способом с добавкой 3-4% глины и 0,1-0,2% электролита (калиевое жидкое стекло). Полученную суспензию наносят на изделия и закрепляют обжигом при 950°С.The components of the glaze are fused at 1300 ° С; The frit is ground wet with the addition of 3-4% clay and 0.1-0.2% electrolyte (potassium water glass). The resulting suspension is applied to the products and fixed by firing at 950 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №1025677, С03С 9/00, 1983.1. USSR copyright certificate No. 1025677, С03С 9/00, 1983.

2. Авторское свидетельство СССР №1154230, С03С 8/06, 1985.2. USSR author's certificate No. 1154230, С03С 8/06, 1985.

Claims (1)

Глазурь, содержащая SiO2, Al2O3, CaO, MgO, B2O3, Fe2O3, K2O, SeO2, отличающаяся тем, что дополнительно содержит ZnO и TiO2 при следующем соотношении компонентов, мас.%:Glaze containing SiO 2 , Al 2 O 3 , CaO, MgO, B 2 O 3 , Fe 2 O 3 , K 2 O, SeO 2 , characterized in that it additionally contains ZnO and TiO 2 in the following ratio of components, wt.% : SiO2 SiO 2 50,0-54,050.0-54.0 Al2O3 Al 2 O 3 2,0-4,02.0-4.0 CaOCao 13,0-17,013.0-17.0 MgOMgO 1,0-2,01.0-2.0 B2O3 B 2 O 3 6,0-7,06.0-7.0 Fe2O3 Fe 2 O 3 0,5-1,00.5-1.0 K2OK 2 O 3,5-4,53.5-4.5 SeO2 Seo 2 1,5-2,51.5-2.5 ZnOZno 8,0-10,08.0-10.0 TiO2 TiO 2 5,0-7,05.0-7.0
RU2006135707/03A 2006-10-09 2006-10-09 Glaze RU2318753C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006135707/03A RU2318753C1 (en) 2006-10-09 2006-10-09 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006135707/03A RU2318753C1 (en) 2006-10-09 2006-10-09 Glaze

Publications (1)

Publication Number Publication Date
RU2318753C1 true RU2318753C1 (en) 2008-03-10

Family

ID=39280846

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006135707/03A RU2318753C1 (en) 2006-10-09 2006-10-09 Glaze

Country Status (1)

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RU (1) RU2318753C1 (en)

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