RU2309916C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2309916C1
RU2309916C1 RU2006118522/03A RU2006118522A RU2309916C1 RU 2309916 C1 RU2309916 C1 RU 2309916C1 RU 2006118522/03 A RU2006118522/03 A RU 2006118522/03A RU 2006118522 A RU2006118522 A RU 2006118522A RU 2309916 C1 RU2309916 C1 RU 2309916C1
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RU
Russia
Prior art keywords
glaze
bao
cao
mgo
compositions
Prior art date
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RU2006118522/03A
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Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
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Юлия Алексеевна Щепочкина
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Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006118522/03A priority Critical patent/RU2309916C1/en
Application granted granted Critical
Publication of RU2309916C1 publication Critical patent/RU2309916C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
    • C03C3/112—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine
    • C03C3/115—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron
    • C03C3/118—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron containing aluminium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: compositions of nonfritted glazes.
SUBSTANCE: invention relates to compositions of nonfritted glazes used in manufacturing face tiles. Proposed glaze comprises the following components, wt.-%: SiO2, 45.0-50.0; Al2O3, 1.0-3.0; CaO, 6.0-10.0; MgO, 1.0-3.0; K2O, 2.0-4.0; ZnO, 3.0-5.0; ZrO2, 1.0-2.0; B2O3, 10.0-15.0; BaO, 5.0-7.0; CaF2, 5.0-10.0, and TiO2, 5.0-7.0. Invention provides enhancing resistance of glaze to cold, whiteness and luster.
EFFECT: improved and valuable properties of glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов, в частности к составам нефриттованных глазурей, используемых в производстве облицовочной плитки.The invention relates to the field of technology of silicates, in particular to compositions of non-grit glazes used in the manufacture of facing tiles.

Известна глазурь, содержащая, мас.%: SiO2 49,5-54,0; Al2O3 4,0-6,0; CaO 4,0-6,0; MgO 0,5-1,0; B2O3 24,0-27,5; BaO 4,0-6,0; Na2O 5,5-8,0 /1/.Known glaze containing, wt.%: SiO 2 49.5-54.0; Al 2 O 3 4.0-6.0; CaO 4.0-6.0; MgO 0.5-1.0; B 2 O 3 24.0-27.5; BaO 4.0-6.0; Na 2 O 5.5-8.0 / 1 /.

Известна глазурь, содержащая, мас.%: SiO2 42,23-60,35; Al2O3 2,4-3,8; CaO 5,8-7,9; MgO 0,39-0,58; K2O 0,54-0,75; Na2O 2,8-4,9; ZnO 4,0-5,1; ZrO2 0,9-3,95; B2O3 19,2-25,04; BaO 3,5-6,7 /2/.Known glaze containing, wt.%: SiO 2 42,23-60,35; Al 2 O 3 2.4-3.8; CaO 5.8-7.9; MgO 0.39-0.58; K 2 O 0.54-0.75; Na 2 O 2,8-4,9; ZnO 4.0-5.1; ZrO 2 0.9-3.95; B 2 O 3 19.2-25.04; BaO 3.5-6.7 / 2 /.

Цель изобретения - повышение морозостойкости, белизны, блеска глазури.The purpose of the invention is to increase frost resistance, whiteness, gloss of glaze.

Цель достигается тем, что в состав глазури дополнительно вводят CaF2 и TiO2, при следующем соотношении компонентов, мас.%: SiO2 45,0-50,0; Al2O3 1,0-3,0; CaO 6,0-10,0; MgO 1,0-3,0; K2O 2,0-4,0; ZnO 3,0-5,0; ZrO2 1,0-2,0; B2O3 10,0-15,0; BaO 5,0-7,0; CaF2 5,0-10,0; TiO2 5,0-7,0.The goal is achieved by the fact that CaF 2 and TiO 2 are additionally added to the glaze, with the following ratio of components, wt.%: SiO 2 45.0-50.0; Al 2 O 3 1.0-3.0; CaO 6.0-10.0; MgO 1.0-3.0; K 2 O 2.0-4.0; ZnO 3.0-5.0; ZrO 2 1.0-2.0; B 2 O 3 10.0-15.0; BaO 5.0-7.0; CaF 2 5.0-10.0; TiO 2 5.0-7.0.

В таблице приведем составы глазури.The table below shows the composition of the glaze.

  СоставStructure Компоненты, мас.%:Components, wt.%: SiO2 SiO 2 Al2O3 Al 2 O 3 CaOCao MgOMgO K2OK 2 O ZnOZno ZrO2 ZrO 2 B2O3 B 2 O 3 BaOBao CaF2 CaF 2 TiO2 TiO 2 1one 45,045.0 1,01,0 6,06.0 3,03.0 2,02.0 5,05,0 1,01,0 15,015.0 5,05,0 10,010.0 7,07.0 22 48,048.0 2,02.0 8,08.0 2,02.0 3,03.0 4,04.0 1,51,5 12,012.0 6,06.0 7,07.0 6,06.0 33 50,050,0 3,03.0 10,010.0 1,01,0 4,04.0 3,03.0 2,02.0 10,010.0 7,07.0 5,05,0 5,05,0

Морозостойкость глазури составит: для 1 и 2 составов 120 циклов, для 3 состава 100 циклов. Белизна глазури 90% для всех составов.Frost resistance of the glaze will be: for 1 and 2 compositions of 120 cycles, for 3 composition of 100 cycles. Glaze whiteness 90% for all formulations.

Блеск глазури 90° для всех составов.Glaze gloss 90 ° for all formulations.

Компоненты глазури размалывают с добавкой 0,2% электролита и 45% воды до остатка не более 0,2% на сетке №0056. Суспензию наносят на изделия и обжигают при 1100°С.The components of the glaze are ground with the addition of 0.2% electrolyte and 45% water to a residue of not more than 0.2% on mesh No. 0056. The suspension is applied to the products and fired at 1100 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №1089068, С03С 9/00, 1984.1. USSR author's certificate No. 1089068, С03С 9/00, 1984.

2. Авторское свидетельство СССР №1191432, С03С 8/04, 1985.2. USSR Author's Certificate No. 1191432, С03С 8/04, 1985.

Claims (1)

Глазурь, содержащая SiO2, Al2О3, CaO, MgO, K2O, ZnO, ZrO2, В2O3, ВаО, отличающаяся тем, что дополнительно содержит CaF2 и TiO2 при следующем соотношении компонентов, мас. %: SiO2 45,0-50,0; Al2О3 1,0-3,0; CaO 6,0-10,0; MgO 1,0-3,0; K2O 2,0-4,0; ZnO 3,0-5,0; ZrO2 1,0-2,0; В2О3 10,0-15,0; ВаО 5,0-7,0; CaF2 5,0-10,0; TiO2 5,0-7,0.Glaze containing SiO 2 , Al 2 O 3 , CaO, MgO, K 2 O, ZnO, ZrO 2 , B 2 O 3 , BaO, characterized in that it additionally contains CaF 2 and TiO 2 in the following ratio of components, wt. %: SiO 2 45.0-50.0; Al 2 O 3 1.0-3.0; CaO 6.0-10.0; MgO 1.0-3.0; K 2 O 2.0-4.0; ZnO 3.0-5.0; ZrO 2 1.0-2.0; B 2 O 3 10.0-15.0; BaO 5.0-7.0; CaF 2 5.0-10.0; TiO 2 5.0-7.0.
RU2006118522/03A 2006-05-29 2006-05-29 Glaze RU2309916C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006118522/03A RU2309916C1 (en) 2006-05-29 2006-05-29 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006118522/03A RU2309916C1 (en) 2006-05-29 2006-05-29 Glaze

Publications (1)

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RU2309916C1 true RU2309916C1 (en) 2007-11-10

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RU2006118522/03A RU2309916C1 (en) 2006-05-29 2006-05-29 Glaze

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111960673A (en) * 2020-08-26 2020-11-20 江西新明珠建材有限公司 Manufacturing method of marble ceramic tile with glaze whiteness of 70 degrees

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111960673A (en) * 2020-08-26 2020-11-20 江西新明珠建材有限公司 Manufacturing method of marble ceramic tile with glaze whiteness of 70 degrees

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