RU2316502C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2316502C1
RU2316502C1 RU2006125619/03A RU2006125619A RU2316502C1 RU 2316502 C1 RU2316502 C1 RU 2316502C1 RU 2006125619/03 A RU2006125619/03 A RU 2006125619/03A RU 2006125619 A RU2006125619 A RU 2006125619A RU 2316502 C1 RU2316502 C1 RU 2316502C1
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RU
Russia
Prior art keywords
glaze
cao
sio
mno
mgo
Prior art date
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RU2006125619/03A
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Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
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Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006125619/03A priority Critical patent/RU2316502C1/en
Application granted granted Critical
Publication of RU2316502C1 publication Critical patent/RU2316502C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: technology of silicates; composition of nonfritted glazes used for manufacture of floor ceramic tiles.
SUBSTANCE: proposed glaze contains the following constituents, mass-%: SiO2, 62.0-66.0; Al2O3, 10.0-14.0; CaO, 6.0-8.0; MgO, 2.0-4.0; B2O3, 5.0-7.0; Na2O, 1.0-2.0; TiO2, 3.0-5.0; MnO2, 2.0-3.0.
EFFECT: enhanced luster and wear resistance of glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов, а именно к составам нефриттованных глазурей, используемых в производстве керамической плитки для полов.The invention relates to the field of technology of silicates, namely, compositions of jade glazes used in the manufacture of ceramic floor tiles.

Известна глазурь, содержащая SiO2, CaO, B2O3, Na2O, P2O5 /1/.Known glaze containing SiO 2 , CaO, B 2 O 3 , Na 2 O, P 2 O 5/1 /.

Известна глазурь следующего состава, мас.%: SiO2 64,89-66,67; Al2O3 12,8-12,84; CaO 3,69-3,79; MgO 1,09-1,15; Fe2O3 2,23-2,55; B2O3 7,0-7,74; Na2O 0,54-0,85; K2O 1,7-2,22; FeO 3,9-4,75 /2/. Блеск такой глазури составляет 11-14%, истираемость 0,02-0,08 г/см2.Glaze of the following composition is known, wt.%: SiO 2 64.89-66.67; Al 2 O 3 12.8-12.84; CaO 3.69-3.79; MgO 1.09-1.15; Fe 2 O 3 2.23-2.55; B 2 O 3 7.0-7.74; Na 2 O 0.54-0.85; K 2 O 1.7-2.22; FeO 3.9-4.75 / 2 /. The gloss of such a glaze is 11-14%, the abrasion is 0.02-0.08 g / cm 2 .

Цель изобретения состоит в повышении блеска и износостойкости глазури.The purpose of the invention is to increase the gloss and wear resistance of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят TiO2 и MnO2, при следующем соотношении компонентов, мас.%: SiO2 62,0-66,0; Al2O3 10,0-14,0; CaO 6,0-8,0; MgO 2,0-4,0; B2O3 5,0-7,0; Na2O 1,0-2,0; TiO2 3,0-5,0; MnO2 2,0-3,0.The goal is achieved by the fact that TiO 2 and MnO 2 are additionally introduced into the glaze, in the following ratio of components, wt.%: SiO 2 62.0-66.0; Al 2 O 3 10.0-14.0; CaO 6.0-8.0; MgO 2.0-4.0; B 2 O 3 5.0-7.0; Na 2 O 1.0-2.0; TiO 2 3.0-5.0; MnO 2 2.0-3.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

ТаблицаTable СоставStructure Компоненты, мас.%:Components, wt.%: Блеск, %Gloss,% Истираемость, г/см2 Abrasion, g / cm 2 SiO2 SiO 2 Al2O3 Al 2 O 3 CaOCao MgOMgO B2O3 B 2 O 3 Na2ONa 2 O TiO2 TiO 2 MnO2 MnO 2     1one 62,062.0 14,014.0 6,06.0 4,04.0 5,05,0 2,02.0 5,05,0 2,02.0 ~20~ 20 ~0,01~ 0.01 22 64,064.0 12,012.0 7,07.0 3,03.0 6,06.0 1,51,5 4,04.0 2,52,5 ~20~ 20 ~0,01~ 0.01 33 66,066.0 10,010.0 8,08.0 2,02.0 7,07.0 1,01,0 3,03.0 3,03.0 ~20~ 20 ~0,01~ 0.01

Компоненты глазури измельчают мокрым способом в шаровых мельницах до остатка 0,02-0,05% на сетке №0056, добавляя 5-7% глины. Влажность готовой глазурной суспензии должна быть 45-50%. Нанесенную на керамическую плитку глазурную суспензию обжигают при 1200°С.The components of the glaze are ground wet in ball mills to a residue of 0.02-0.05% on a mesh No. 0056, adding 5-7% clay. The moisture content of the finished glaze suspension should be 45-50%. The glaze suspension deposited on the ceramic tile is fired at 1200 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №908757, С03С 9/00, 1982.1. USSR author's certificate No. 908757, С03С 9/00, 1982.

2. Авторское свидетельство СССР №1263683, С04B 41/86, 1986.2. USSR Author's Certificate No. 1263683, С04B 41/86, 1986.

Claims (1)

Глазурь, содержащая SiO2, Al2О3, CaO, MgO, В2О3, Na2O, отличающаяся тем, что дополнительно содержит TiO2 и MnO2 при следующем соотношении компонентов, мас.%:Glaze containing SiO 2 , Al 2 O 3 , CaO, MgO, B 2 O 3 , Na 2 O, characterized in that it additionally contains TiO 2 and MnO 2 in the following ratio, wt.%: SiO2 SiO 2 62,0-66,062.0-66.0 Al2O3 Al 2 O 3 10,0-14,010.0-14.0 CaOCao 6,0-8,06.0-8.0 MgOMgO 2,0-4,02.0-4.0 В2O3 B 2 O 3 5,0-7,05.0-7.0 Na2ONa 2 O 1,0-2,01.0-2.0 TiO2 TiO 2 3,0-5,03.0-5.0 MnO2 MnO 2 2,0-3,02.0-3.0
RU2006125619/03A 2006-07-17 2006-07-17 Glaze RU2316502C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006125619/03A RU2316502C1 (en) 2006-07-17 2006-07-17 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006125619/03A RU2316502C1 (en) 2006-07-17 2006-07-17 Glaze

Publications (1)

Publication Number Publication Date
RU2316502C1 true RU2316502C1 (en) 2008-02-10

Family

ID=39266207

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006125619/03A RU2316502C1 (en) 2006-07-17 2006-07-17 Glaze

Country Status (1)

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RU (1) RU2316502C1 (en)

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