RU2019138625A - Нано- и/или микроструктурированные печатные электроды - Google Patents
Нано- и/или микроструктурированные печатные электроды Download PDFInfo
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- RU2019138625A RU2019138625A RU2019138625A RU2019138625A RU2019138625A RU 2019138625 A RU2019138625 A RU 2019138625A RU 2019138625 A RU2019138625 A RU 2019138625A RU 2019138625 A RU2019138625 A RU 2019138625A RU 2019138625 A RU2019138625 A RU 2019138625A
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- Russia
- Prior art keywords
- nano
- microparticles
- gold
- carbon black
- group
- Prior art date
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- 239000011859 microparticle Substances 0.000 claims 9
- 239000002105 nanoparticle Substances 0.000 claims 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 6
- 239000006229 carbon black Substances 0.000 claims 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 4
- 229910052737 gold Inorganic materials 0.000 claims 4
- 239000010931 gold Substances 0.000 claims 4
- 229910052751 metal Inorganic materials 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 3
- 229910045601 alloy Inorganic materials 0.000 claims 3
- 239000000956 alloy Substances 0.000 claims 3
- 229910052802 copper Inorganic materials 0.000 claims 3
- 239000010949 copper Substances 0.000 claims 3
- 239000007788 liquid Substances 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 3
- 229910052697 platinum Inorganic materials 0.000 claims 3
- 239000000523 sample Substances 0.000 claims 3
- 229910052709 silver Inorganic materials 0.000 claims 3
- 239000004332 silver Substances 0.000 claims 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 239000004155 Chlorine dioxide Substances 0.000 claims 1
- 239000012491 analyte Substances 0.000 claims 1
- 239000002775 capsule Substances 0.000 claims 1
- 238000005266 casting Methods 0.000 claims 1
- 235000019398 chlorine dioxide Nutrition 0.000 claims 1
- 239000008151 electrolyte solution Substances 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- 238000005259 measurement Methods 0.000 claims 1
- 239000012528 membrane Substances 0.000 claims 1
- 239000002923 metal particle Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/18—Water
- G01N33/182—Specific anions in water
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/307—Disposable laminated or multilayered electrodes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/301—Reference electrodes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/302—Electrodes, e.g. test electrodes; Half-cells pH sensitive, e.g. quinhydron, antimony or hydrogen electrodes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/308—Electrodes, e.g. test electrodes; Half-cells at least partially made of carbon
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/416—Systems
- G01N27/48—Systems using polarography, i.e. measuring changes in current under a slowly-varying voltage
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Pathology (AREA)
- Immunology (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Food Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Claims (18)
1. Нано- и/или микроструктурированный печатный электрод для измерения в жидкостях аналита, выбранного из группы, состоящей из диоксида хлора, свободного хлора, общего хлора и перуксусной кислоты, характеризующийся тем, что изготовлен с использованием нано- или микрочастиц углеродной сажи и/или нано- или микрочастиц металла, выбранного из группы, состоящей из золота, серебра, платины, меди и их комбинаций или сплавов.
2. Печатный электрод по п. 1, содержащий по меньшей мере одно отверстие (21).
3. Печатный электрод по п. 1, в котором количество нанесенных на него нано- или микрочастиц углеродной сажи и/или металлических частиц составляет от 0,1 до 50 мкл, предпочтительно от 1 до 20 мкл, более предпочтительно от 2 до 14 мкл, и указанное нанесение выполнено путем последовательных нанесений по 2 мкл каждое.
4. Печатный электрод по п. 1, который изготовлен с использованием металлических нано- или микрочастиц, имеющих средний диаметр от 20 до 0,05 мкм, предпочтительно от 10 до 0,3 мкм, более предпочтительно 1 мкм.
5. Печатный электрод по п. 4, в котором металл представляет собой золото и средний диаметр микрочастиц составляет 1 мкм.
6. Электрохимический датчик, содержащий один или более электродов по любому из пп. 1-5.
7. Электрохимический зонд, содержащий один или более датчиков по п. 6.
8. Способ изготовления печатного электрода по п. 1, характеризующийся тем, что в процессе печати используют краску, содержащую нано- или микрочастицы углеродной сажи и/или нано- или микрочастицы металла, выбранного из группы, состоящей из золота, серебра, платины, меди и их комбинаций или сплавов.
9. Способ изготовления печатного электрода по п. 1, характеризующийся тем, что (методом «дроп кастинга») наносят на его поверхность капли жидкости, которая содержит нано- или микрочастицы углеродной сажи и/или нано- или микрочастицы металла, выбранного из группы, состоящей из золота, серебра, платины, меди и их комбинаций или сплавов, и обеспечивают возможность такой жидкости затвердеть или испариться.
10. Набор, содержащий по меньшей мере электрохимический зонд по п. 7 и дополнительно содержащий:
- по меньшей мере, держатель зонда;
- по меньшей мере, капсулу;
- по меньшей мере, электролитический раствор или гель;
- по меньшей мере, гидрофобную и/или гидрофильную мембрану; и
- по меньшей мере, электронное устройство для управления, реализации и/или передачи данных.
11. Набор по п. 10 для измерения одного или более аналитов, соответствующих п. 1, в воде для промышленного или гражданского использования.
12. Набор по п. 10 для измерения одного или более аналитов, соответствующих п. 1, во время синтетического промышленного процесса.
13. Набор по пп. 10-12 для измерения в непрерывном режиме одного или более аналитов, соответствующих п. 1.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT102017000046831A IT201700046831A1 (it) | 2017-05-03 | 2017-05-03 | Nuovi sensori stampati nano e/o microstrutturati. |
| IT102017000046831 | 2017-05-03 | ||
| PCT/EP2018/061383 WO2018202793A2 (en) | 2017-05-03 | 2018-05-03 | Nano- and/or micro-structured printed electrodes |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2019138625A true RU2019138625A (ru) | 2021-06-03 |
| RU2019138625A3 RU2019138625A3 (ru) | 2021-09-28 |
| RU2773686C2 RU2773686C2 (ru) | 2022-06-07 |
Family
ID=
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018202793A3 (en) | 2018-12-13 |
| US20230194458A1 (en) | 2023-06-22 |
| CN110573868A (zh) | 2019-12-13 |
| CN116879364A (zh) | 2023-10-13 |
| EP3619528A2 (en) | 2020-03-11 |
| JP2020518804A (ja) | 2020-06-25 |
| US20200191740A1 (en) | 2020-06-18 |
| WO2018202793A2 (en) | 2018-11-08 |
| IT201700046831A1 (it) | 2018-11-03 |
| JP7455582B2 (ja) | 2024-03-26 |
| RU2019138625A3 (ru) | 2021-09-28 |
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