RU2018121643A - Сополимеры пропиленовые - Google Patents
Сополимеры пропиленовые Download PDFInfo
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- RU2018121643A RU2018121643A RU2018121643A RU2018121643A RU2018121643A RU 2018121643 A RU2018121643 A RU 2018121643A RU 2018121643 A RU2018121643 A RU 2018121643A RU 2018121643 A RU2018121643 A RU 2018121643A RU 2018121643 A RU2018121643 A RU 2018121643A
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- RU
- Russia
- Prior art keywords
- hexene
- propylene copolymer
- weight
- range
- flow rate
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
- C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
- C08F4/6545—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium and metals of C08F4/64 or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
- B32B2250/242—All polymers belonging to those covered by group B32B27/32
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/31—Heat sealable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/514—Oriented
- B32B2307/518—Oriented bi-axially
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/05—Bimodal or multimodal molecular weight distribution
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/26—Use as polymer for film forming
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/14—Copolymers of propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Claims (13)
1. Пропиленовый сополимер 1-гексена, содержащий от 5,5 до 9,0% производных единиц 1-гексена по массе, имеющий:
а) два пика на графике ДСК, имеющие разницу в высоте от 0 до 5 мВт;
б) более высокую температуру плавления, измеряемую при помощи ДСК, в диапазоне от 141,0°С до 151,0°С;
в) скорость течения расплава (СТР), измеряемую по ASTM D 1238, 230°С/2,16 кг, от 3,5 до 8,0 г/10 мин.
2. Пропиленовый сополимер 1-гексенапо п. 1, содержащий от 6,0 до 8,5% производных единиц 1-гексена по массе.
3. Пропиленовый сополимер 1-гексена по п. 2, содержащий от 6,5 до 8,0% производных единиц 1-гексена по массе.
4. Пропиленовый сополимер 1-гексена по п. 1, отличающийся тем, что температура плавления двух пиков находится в диапазоне от 5°C до 30°C.
5. Пропиленовый сополимер 1-гексена по п. 1, отличающийся тем, что максимальная температура плавления, измерения путем ДСК, находится в диапазоне от 142,0°C до 149,0°C.
6. Пропиленовый сополимер 1-гексена по п. 1, растворимость которого в ксилоле при 25°C меньше либо равна 25% по массе, но больше 12% по массе.
7. Пропиленовый сополимер 1-гексена по п. 6, растворимость которого в ксилоле при 25°C меньше либо равна 20% по массе, но больше 12% по массе.
8. Пропиленовый сополимер 1-гексена по п. 1, отличающийся тем, что скорость течения расплава находится в диапазоне от 3,8 до 7,5 г/10 мин.
9. Пропиленовый сополимер 1-гексена по п. 8, отличающийся тем, что скорость течения расплава находится в диапазоне от 4,0 до 6,0 г/10 мин.
10. Пленка, состоящая из пропиленового сополимера 1-гексена по п. 1.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15199653 | 2015-12-11 | ||
EP15199653.5 | 2015-12-11 | ||
PCT/EP2016/078415 WO2017097578A1 (en) | 2015-12-11 | 2016-11-22 | Propylene copolymers |
Publications (3)
Publication Number | Publication Date |
---|---|
RU2018121643A true RU2018121643A (ru) | 2019-12-16 |
RU2018121643A3 RU2018121643A3 (ru) | 2020-01-29 |
RU2723242C2 RU2723242C2 (ru) | 2020-06-09 |
Family
ID=55022275
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2018121643A RU2723242C2 (ru) | 2015-12-11 | 2016-11-22 | Сополимеры пропиленовые |
Country Status (8)
Country | Link |
---|---|
US (1) | US10711080B2 (ru) |
EP (1) | EP3387027B1 (ru) |
JP (1) | JP2018535306A (ru) |
KR (1) | KR102078953B1 (ru) |
CN (1) | CN108290982B (ru) |
BR (1) | BR112018010614B1 (ru) |
RU (1) | RU2723242C2 (ru) |
WO (1) | WO2017097578A1 (ru) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3655445B1 (en) * | 2017-07-19 | 2023-12-13 | Basell Poliolefine Italia S.r.l. | Propylene copolymers |
WO2020064190A1 (en) * | 2018-09-26 | 2020-04-02 | Borealis Ag | Propylene copolymer composition with excellent optical and mechanical properties |
CN112638960A (zh) * | 2018-09-26 | 2021-04-09 | 博里利斯股份公司 | 在薄膜应用中使用的丙烯无规共聚物 |
EP3628486B1 (en) * | 2018-09-26 | 2020-11-18 | Borealis AG | A multilayer film |
EP3950739B1 (en) * | 2020-08-05 | 2023-11-08 | Borealis AG | Polypropylene sheet |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
IT1209255B (it) | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
IT1227260B (it) | 1988-09-30 | 1991-03-28 | Himont Inc | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
BR9005444A (pt) * | 1989-10-31 | 1991-09-17 | Union Carbide Chem Plastic | Processo para a preparacao de copolimeros aleatorios |
EP0588208A3 (en) * | 1992-09-12 | 1994-07-06 | Hoechst Ag | Polyolefin moulding composition with broad melt range, process and use therefore |
IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
US7919561B2 (en) | 1996-09-04 | 2011-04-05 | Exxonmobil Chemical Patents Inc. | Process of producing thermoplastic polymer blends |
US6583227B2 (en) | 1996-09-04 | 2003-06-24 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
CA2262468A1 (en) | 1996-09-04 | 1998-03-12 | Exxon Chemical Patents, Inc. | Improved propylene polymers for oriented films |
US6576306B2 (en) | 1996-09-04 | 2003-06-10 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
MY136330A (en) | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
PL1759139T3 (pl) | 2004-06-25 | 2008-08-29 | Basell Poliolefine Italia Srl | Układy rurowe wykonane z bezładnych kopolimerów propylenu i alfa-olefin |
WO2006069205A1 (en) * | 2004-12-21 | 2006-06-29 | Dow Global Technologies Inc. | Polypropylene-based adhesive compositions |
CN101903424A (zh) | 2007-12-18 | 2010-12-01 | 巴塞尔聚烯烃意大利有限责任公司 | 丙烯与己烯-1的共聚物和从其得到的吹塑膜 |
JP5400794B2 (ja) | 2007-12-19 | 2014-01-29 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 軟質で可撓性のポリオレフィン組成物 |
EP2279216B1 (en) | 2008-05-28 | 2011-09-28 | Borealis AG | Propylene-hexene random copolymer produced in the presence of a ziegler natta catalyst |
US8227547B2 (en) * | 2008-12-15 | 2012-07-24 | Exxonmobil Chemical Patents Inc. | Foamable thermoplastic reactor blends and foam article therefrom |
US8663763B2 (en) | 2009-11-17 | 2014-03-04 | Basell Poliolefine Italia S.R.L. | Thermoshrinkable films |
ATE552303T1 (de) * | 2010-04-21 | 2012-04-15 | Borealis Ag | Propylen-/1-hexen copolymerzusammensetzung mit breitem verarbeitungsfenster für abdichtungen |
EP2661466B1 (en) | 2011-01-03 | 2016-03-30 | Borealis AG | Sealing material of polypropylene with high melting temperature |
ES2527333T5 (es) * | 2011-02-14 | 2021-08-02 | Borealis Ag | Copolímero de propileno sellador |
PT2540499E (pt) | 2011-06-27 | 2014-03-06 | Borealis Ag | Película polimérica de multi-camada orientada biaxialmente |
EP2583999A1 (en) * | 2011-10-20 | 2013-04-24 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions |
ES2605038T3 (es) * | 2011-10-31 | 2017-03-10 | Borealis Ag | Mezcla de polipropileno con mejor balance entre SIT y punto de fusión |
US9096700B2 (en) * | 2012-12-10 | 2015-08-04 | Exxonmobil Chemical Patents Inc. | Polymerization process for production of polymer |
KR101730287B1 (ko) * | 2013-03-26 | 2017-04-25 | 보레알리스 아게 | 높은 충격 특성을 갖는 프로필렌 공중합체 |
BR112016008914B1 (pt) | 2013-10-30 | 2021-08-03 | Basell Poliolefine Italia S.R.L. | Copolímeros multimodais de propileno e 1-hexeno e folha industrial compreendendo os mesmos |
US20160319095A1 (en) * | 2013-12-27 | 2016-11-03 | Kaneka Corporation | Polyolefin resin foam particles, and polyolefin resin in-mold expansion molded article |
-
2016
- 2016-11-22 EP EP16798752.8A patent/EP3387027B1/en active Active
- 2016-11-22 WO PCT/EP2016/078415 patent/WO2017097578A1/en active Application Filing
- 2016-11-22 CN CN201680068706.9A patent/CN108290982B/zh active Active
- 2016-11-22 KR KR1020187017995A patent/KR102078953B1/ko active IP Right Grant
- 2016-11-22 US US16/061,164 patent/US10711080B2/en active Active
- 2016-11-22 BR BR112018010614-3A patent/BR112018010614B1/pt active IP Right Grant
- 2016-11-22 JP JP2018545685A patent/JP2018535306A/ja active Pending
- 2016-11-22 RU RU2018121643A patent/RU2723242C2/ru active
Also Published As
Publication number | Publication date |
---|---|
RU2018121643A3 (ru) | 2020-01-29 |
EP3387027B1 (en) | 2024-02-14 |
CN108290982A (zh) | 2018-07-17 |
US20180362682A1 (en) | 2018-12-20 |
WO2017097578A1 (en) | 2017-06-15 |
CN108290982B (zh) | 2021-01-05 |
BR112018010614B1 (pt) | 2022-04-26 |
US10711080B2 (en) | 2020-07-14 |
KR20180097588A (ko) | 2018-08-31 |
KR102078953B1 (ko) | 2020-04-03 |
BR112018010614A2 (pt) | 2018-11-13 |
RU2723242C2 (ru) | 2020-06-09 |
JP2018535306A (ja) | 2018-11-29 |
EP3387027A1 (en) | 2018-10-17 |
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