RU2015125545A - MASTERBATCH CONTAINING CYCLIC KETONE PEROXIDE - Google Patents

MASTERBATCH CONTAINING CYCLIC KETONE PEROXIDE Download PDF

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RU2015125545A
RU2015125545A RU2015125545A RU2015125545A RU2015125545A RU 2015125545 A RU2015125545 A RU 2015125545A RU 2015125545 A RU2015125545 A RU 2015125545A RU 2015125545 A RU2015125545 A RU 2015125545A RU 2015125545 A RU2015125545 A RU 2015125545A
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masterbatch
polymer matrix
ketone peroxide
paragraphs
cyclic ketone
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RU2015125545A
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Russian (ru)
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RU2655322C2 (en
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Пол Альберт ЯКОБУЧЧИ
Вилхелм Клас ФРЕЙЛИНК
Барт ФИШЕР
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Акцо Нобель Кемикалз Интернэшнл Б.В.
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Priority claimed from PCT/EP2013/075191 external-priority patent/WO2014086692A1/en
Publication of RU2015125545A publication Critical patent/RU2015125545A/en
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Publication of RU2655322C2 publication Critical patent/RU2655322C2/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/203—Solid polymers with solid and/or liquid additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36—After-treatment
    • C08J9/40—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides

Claims (19)

1. Мастербатч, содержащий димерный и/или тримерный циклический пероксид кетона, распределенный в полимерной матрице с пористостью, выраженной в виде процентной доли пустот в объеме матрицы, составляющей от 0,1 до 80 об.%, при этом указанный мастербатч содержит на 100 г полимерной матрицы от 1 до 30 г димерного и/или тримерного циклического пероксида кетона и менее 0,20 г насыщенных углеводородов, содержащих от 17 до 51 атома углерода.1. A masterbatch containing dimeric and / or trimeric cyclic ketone peroxide distributed in a polymer matrix with porosity expressed as a percentage of voids in the matrix volume of 0.1 to 80 vol.%, Wherein said masterbatch contains 100 g polymer matrix from 1 to 30 g of dimeric and / or trimeric cyclic ketone peroxide and less than 0.20 g of saturated hydrocarbons containing from 17 to 51 carbon atoms. 2. Мастербатч по п. 1, содержащий на 100 г полимерной матрицы менее 0,15 г насыщенных углеводородов, содержащих от 17 до 51 атома углерода.2. The masterbatch according to claim 1, containing per 100 g of the polymer matrix less than 0.15 g of saturated hydrocarbons containing from 17 to 51 carbon atoms. 3. Мастербатч по п. 2, содержащий на 100 г полимерной матрицы менее 0,10 г насыщенных углеводородов, содержащих от 17 до 51 атома углерода. 3. The masterbatch according to claim 2, containing per 100 g of the polymer matrix less than 0.10 g of saturated hydrocarbons containing from 17 to 51 carbon atoms. 4. Мастербатч по любому из пп. 1-3, в котором димерный циклический пероксид кетона имеет структуру согласно формуле (I), а тримерный циклический пероксид кетона имеет структуру согласно формуле (II)4. Masterbatch according to any one of paragraphs. 1-3, in which the dimeric cyclic ketone peroxide has a structure according to the formula (I), and the trimeric cyclic ketone peroxide has a structure according to the formula (II)
Figure 00000001
Figure 00000001
 в которых R1-R6 независимо выбирают из группы, состоящей из водорода, C1-C20 алкильных, C3-C20 циклоалкильных, C6-C20 арильных, C7-C20 аралкильных и C7-C20 алкарильных групп, которые могут включать линейные или разветвленные алкильные фрагменты; при этом каждый из R1-R6 может необязательно иметь в качестве заместителя одну или несколько групп выбираемых из гидрокси-, алкокси-, линейных или разветвленных алкильных, арилокси-, сложноэфирных, карбокси-, нитрильных и амидогрупп.in which R 1 -R 6 independently selected from the group consisting of hydrogen, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 aralkyl and C 7 -C 20 alkaryl groups which may include linear or branched alkyl moieties; wherein each of R 1 -R 6 may optionally have one or more groups selected from hydroxy, alkoxy, linear or branched alkyl, aryloxy, ester, carboxy, nitrile and amido groups as a substituent. 5. Мастербатч по п. 4, в котором циклический пероксид 5. The masterbatch of claim 4, wherein the cyclic peroxide кетона представляет собой 3,6,9-триэтил-3,6,9-триметил-1,4,7-трипероксонан.the ketone is 3,6,9-triethyl-3,6,9-trimethyl-1,4,7-triperoxonan. 6. Мастербатч по любому из пп. 1-3, в котором получаемый мастербатч содержит от 4 до 18 г димерного и/или тримерного циклического пероксида кетона на 100 г полимерной матрицы.6. Masterbatch according to any one of paragraphs. 1-3, in which the resulting masterbatch contains from 4 to 18 g of dimeric and / or trimeric cyclic ketone peroxide per 100 g of polymer matrix. 7. Мастербатч по любому из пп. 1-3, в котором полимерная матрица имеет пористость от 10 до 60 об.%.7. Masterbatch according to any one of paragraphs. 1-3, in which the polymer matrix has a porosity of from 10 to 60 vol.%. 8. Мастербатч по любому из пп. 1-3, в котором полимерная матрица, по меньшей мере, на 50 мас.% состоит из полипропилена, полиэтилена, этиленовинилацетатного полимера или любых их смесей.8. Masterbatch according to any one of paragraphs. 1-3, in which the polymer matrix, at least 50 wt.% Consists of polypropylene, polyethylene, ethylene-vinyl acetate polymer or any mixtures thereof. 9. Мастербатч по п. 8, в котором полимер соответствует сорту полимеров, полученных в полимеризаторе, или сорту экструдированных пористых полимеров.9. The masterbatch according to claim 8, in which the polymer corresponds to the grade of polymers obtained in the polymerizer, or the grade of extruded porous polymers. 10. Мастербатч по любому из пп. 1-3, в котором состав содержит один или несколько дополнительных пероксидов или гидропероксидов.10. Masterbatch according to any one of paragraphs. 1-3, in which the composition contains one or more additional peroxides or hydroperoxides. 11. Способ получения мастербатча по пп. 1-10, содержащий стадии:11. The method of obtaining masterbatch according to paragraphs. 1-10, containing the stage: (i) обеспечения полимерной матрицы с пористостью, выраженной в виде процентной доли пустот в объеме матрицы, составляющей от 0,1 до 80 об.%, и (i) providing a polymer matrix with porosity expressed as a percentage of voids in the matrix volume of 0.1 to 80% by volume, and (ii) пропитки указанной полимерной матрицы составом, содержащим димерный и/или тримерный циклический пероксид кетона, а также один или несколько растворителей.(ii) impregnating said polymer matrix with a composition comprising a dimeric and / or trimeric cyclic ketone peroxide, as well as one or more solvents. 12. Применение мастербатча по пп. 1-10 для модификации полимеров.12. The use of masterbatch on PP. 1-10 for polymer modification. 13. Применение по п. 12, в котором модификация включает разрыв полимерных цепей полипропиленовых гомополимеров и/или сополимеров пропилена и этилена. 13. The use of claim 12, wherein the modification comprises breaking polymer chains of polypropylene homopolymers and / or copolymers of propylene and ethylene. 14. Применение по п. 12, в котором модификация включает введение длинноцепочечной разветвленности или сшивание полиэтиленов.14. The use according to claim 12, in which the modification includes the introduction of long chain branching or crosslinking of polyethylene.
RU2015125545A 2012-12-05 2013-12-02 Masterbatch comprising cyclic ketone peroxide RU2655322C2 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261733556P 2012-12-05 2012-12-05
US61/733,556 2012-12-05
EP13150128.0 2013-01-03
EP13150128 2013-01-03
PCT/EP2013/075191 WO2014086692A1 (en) 2012-12-05 2013-12-02 Masterbatch comprising a cyclic ketone peroxide

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RU2015125545A true RU2015125545A (en) 2017-01-11
RU2655322C2 RU2655322C2 (en) 2018-05-25

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BR (1) BR112015011895B1 (en)
ES (1) ES2704661T3 (en)
IN (1) IN2015DN03934A (en)
MY (1) MY178742A (en)
PH (1) PH12015501205B1 (en)
RU (1) RU2655322C2 (en)
TR (1) TR201900036T4 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2022349C (en) * 1989-10-13 2001-07-17 Daryl L. Stein Peroxide masterbatches using polycaprolactone as the carrier
IT1240647B (en) * 1990-05-14 1993-12-17 Himont Inc NON-EXTRUDED CONCENTRATES OF ADDITIVES, CHARGES OR PIGMENTS
HU216142B (en) * 1994-07-21 1999-04-28 Akzo Nobel N.V. Cyclic ketone peroxide formulations and their use for modification of (co)polymers
US7198844B2 (en) * 2003-01-17 2007-04-03 Crompton Corporation Microporous polymeric resin containing stabilizers and method for making thereof
FR2946653B1 (en) * 2009-06-15 2012-08-03 Arkema France PROCESS FOR PRODUCING A MIXED-MASTER COMPOSITION COMPRISING AN ORGANIC PEROXIDE

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RU2655322C2 (en) 2018-05-25
TR201900036T4 (en) 2019-02-21
BR112015011895B1 (en) 2021-05-11
PH12015501205A1 (en) 2015-08-17
PH12015501205B1 (en) 2015-08-17
BR112015011895A2 (en) 2017-07-11
IN2015DN03934A (en) 2015-10-02
ES2704661T3 (en) 2019-03-19
MY178742A (en) 2020-10-20

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