RU2014120337A - METHOD FOR PRODUCING 3 - {[3- (1,5,3-Dithiazepan-3-ylmethyl) Cyclohexyl] Methyl} -1,5,3-Dithiazepane and Its Use as a Means with Fungicidal Activity - Google Patents

METHOD FOR PRODUCING 3 - {[3- (1,5,3-Dithiazepan-3-ylmethyl) Cyclohexyl] Methyl} -1,5,3-Dithiazepane and Its Use as a Means with Fungicidal Activity Download PDF

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RU2014120337A
RU2014120337A RU2014120337/04A RU2014120337A RU2014120337A RU 2014120337 A RU2014120337 A RU 2014120337A RU 2014120337/04 A RU2014120337/04 A RU 2014120337/04A RU 2014120337 A RU2014120337 A RU 2014120337A RU 2014120337 A RU2014120337 A RU 2014120337A
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cyclohexyl
dithiazepan
ylmethyl
methyl
dithiazepane
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RU2014120337/04A
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Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Наиля Фауатовна Галимзянова
Елена Борисовна Рахимова
Ринат Арфикович Исмагилов
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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Abstract

1. Способ получения 3-{[3-(1,5,3-дитиазепан-3-илметил)циклогексил]метил}-1,5,3-дитиазепана (1):отличающийся тем, что [3-(аминометил)циклогексил]метиламин подвергают взаимодействию с 1-окса-3,6-дитиациклогептаном в среде хлороформа в присутствии катализатора SmCl·6HO при мольном соотношении [3-(аминометил)циклогексил]метиламин: 1-окса-3,6-дитиациклогептан: SmCl·6HO=1:2: (0.03-0.07) при комнатной температуре (~20°C) и атмосферном давлении в течение 2.5-3.5 ч.2. Применение 3-{[3-(1,5,3-дитиазепан-3-илметил)циклогексил]метил}-1,5,3-дитиазепана (1) в качестве средства с фунгицидной активностью для борьбы с грибковыми заболеваниями сельскохозяйственных культур, вызываемыми грибами Rhizoctonia solani.1. The method of obtaining 3 - {[3- (1,5,3-dithiazepan-3-ylmethyl) cyclohexyl] methyl} -1,5,3-dithiazepane (1): characterized in that [3- (aminomethyl) cyclohexyl ] methylamine is reacted with 1-oxa-3,6-dithiacycloheptane in chloroform medium in the presence of a SmCl · 6HO catalyst with a molar ratio of [3- (aminomethyl) cyclohexyl] methylamine: 1-oxa-3,6-dithiacycloheptane: SmCl · 6HO = 1: 2: (0.03-0.07) at room temperature (~ 20 ° C) and atmospheric pressure for 2.5-3.5 hours. 2. The use of 3 - {[3- (1,5,3-dithiazepan-3-ylmethyl) cyclohexyl] methyl} -1,5,3-dithiazepan (1) as an agent with fungicidal activity for controlling fungal diseases of crops caused by Rhizoctonia solani mushrooms.

Claims (2)

1. Способ получения 3-{[3-(1,5,3-дитиазепан-3-илметил)циклогексил]метил}-1,5,3-дитиазепана (1):1. The method of obtaining 3 - {[3- (1,5,3-dithiazepan-3-ylmethyl) cyclohexyl] methyl} -1,5,3-dithiazepane (1):
Figure 00000001
Figure 00000001
 отличающийся тем, что [3-(аминометил)циклогексил]метиламин подвергают взаимодействию с 1-окса-3,6-дитиациклогептаном в среде хлороформа в присутствии катализатора SmCl3·6H2O при мольном соотношении [3-(аминометил)циклогексил]метиламин: 1-окса-3,6-дитиациклогептан: SmCl3·6H2O=1:2: (0.03-0.07) при комнатной температуре (~20°C) и атмосферном давлении в течение 2.5-3.5 ч.characterized in that [3- (aminomethyl) cyclohexyl] methylamine is reacted with 1-oxa-3,6-dithiacycloheptane in chloroform medium in the presence of a SmCl 3 · 6H 2 O catalyst with a molar ratio of [3- (aminomethyl) cyclohexyl] methylamine: 1-oxa-3,6-dithiacycloheptane: SmCl 3 · 6H 2 O = 1: 2: (0.03-0.07) at room temperature (~ 20 ° C) and atmospheric pressure for 2.5-3.5 hours. 2. Применение 3-{[3-(1,5,3-дитиазепан-3-илметил)циклогексил]метил}-1,5,3-дитиазепана (1) в качестве средства с фунгицидной активностью для борьбы с грибковыми заболеваниями сельскохозяйственных культур, вызываемыми грибами Rhizoctonia solani.2. The use of 3 - {[3- (1,5,3-dithiazepan-3-ylmethyl) cyclohexyl] methyl} -1,5,3-dithiazepane (1) as an agent with fungicidal activity for controlling fungal diseases of crops caused by fungi of Rhizoctonia solani.
RU2014120337/04A 2014-05-20 2014-05-20 METHOD FOR PRODUCING 3 - {[3- (1,5,3-Dithiazepan-3-ylmethyl) Cyclohexyl] Methyl} -1,5,3-Dithiazepane and Its Use as a Means with Fungicidal Activity RU2014120337A (en)

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Effective date: 20151022