RU2012149351A - NEW METAL-ORGANIC FRAME-BASED STRUCTURES AS ELECTRODE MATERIAL FOR LITHIUM-ION BATTERIES - Google Patents

NEW METAL-ORGANIC FRAME-BASED STRUCTURES AS ELECTRODE MATERIAL FOR LITHIUM-ION BATTERIES Download PDF

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RU2012149351A
RU2012149351A RU2012149351/04A RU2012149351A RU2012149351A RU 2012149351 A RU2012149351 A RU 2012149351A RU 2012149351/04 A RU2012149351/04 A RU 2012149351/04A RU 2012149351 A RU2012149351 A RU 2012149351A RU 2012149351 A RU2012149351 A RU 2012149351A
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electrode material
metal
lithium
ion
acid
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RU2012149351/04A
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Russian (ru)
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Наталия ТРУХАН
Ульрих Мюллер
Александер ПАНЧЕНКО
Итамар Михаэль МАЛЬКОВСКИЙ
Андреас ФИШЕР
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Басф Се
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic System
    • C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic System without C-Metal linkages
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic System
    • C07F1/02—Lithium compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

1. Электродный материал, который подходит для литий-ионного аккумулятора и содержит пористую металлоорганическую каркасную структуру, причем каркасная структура содержит ионы лития и при необходимости ион по меньшей мере одного другого металла, и по меньшей мере одно по меньшей мере бидентатное органическое соединение, и по меньшей мере одно по меньшей мере бидентатное органическое соединение основано на дигидроксидикарбоновой кислоте, которая может быть обратимо окислена до хиноидной структуры.2. Электродный материал по п.1, в котором содержится один или более других металлических ионов.3. Электродный материал по п.2, в котором по меньшей мере один другой металлический ион выбирается из группы, состоящей из металлов: кобальт, железо, никель, медь, марганец, хром, ванадий и титан.4. Электродный металл по п.1, в котором дигидроксидикарбоновой кислотой является дигидроксибензолдикарбоновая кислота.5. Электродный металл по любому из п.п.1-4, в котором дигидроксидикарбоновой кислотой является 2,5-дигидрокситерефталевая кислота.6. Пористая металлоорганическая каркасная структура, как раскрывается в любом из п.п.1-5.7. Применение пористой металлоорганической каркасной структуры по п.6 в электродном материале для литий-ионных аккумуляторов.8. Аккумулятор, содержащий электродный материал по любому из п.п.1-5.9. Электрохимический элемент, содержащий электродный материал по любому из п.п.1-5.10. Применение пористой металлоорганической каркасной структуры по п.6 в электродном материале для электрохимических элементов.1. An electrode material that is suitable for a lithium-ion battery and comprises a porous organometallic framework structure, the framework structure comprising lithium ions and optionally an ion of at least one other metal, and at least one at least bidentate organic compound, and at least one at least bidentate organic compound is based on dihydroxydicarboxylic acid, which can be reversibly oxidized to a quinoid structure. 2. The electrode material of claim 1, wherein one or more other metal ions are contained. The electrode material of claim 2, wherein the at least one other metal ion is selected from the group consisting of metals: cobalt, iron, nickel, copper, manganese, chromium, vanadium, and titanium. The electrode metal of claim 1, wherein the dihydroxydicarboxylic acid is dihydroxybenzenedicarboxylic acid. An electrode metal according to any one of claims 1 to 4, wherein the dihydroxydicarboxylic acid is 2,5-dihydroxyterephthalic acid. A porous organometallic scaffold structure as disclosed in any one of claims 1-5.7. The use of a porous organometallic framework according to claim 6 in an electrode material for lithium-ion batteries. A battery containing an electrode material according to any one of claims 1-5.9. An electrochemical cell containing an electrode material according to any one of claims 1-5.10. The use of a porous organometallic framework according to claim 6 in an electrode material for electrochemical cells.

Claims (10)

1. Электродный материал, который подходит для литий-ионного аккумулятора и содержит пористую металлоорганическую каркасную структуру, причем каркасная структура содержит ионы лития и при необходимости ион по меньшей мере одного другого металла, и по меньшей мере одно по меньшей мере бидентатное органическое соединение, и по меньшей мере одно по меньшей мере бидентатное органическое соединение основано на дигидроксидикарбоновой кислоте, которая может быть обратимо окислена до хиноидной структуры.1. An electrode material that is suitable for a lithium-ion battery and contains a porous organometallic frame structure, the frame structure containing lithium ions and, if necessary, an ion of at least one other metal, and at least one at least one bidentate organic compound, and at least one at least bidentate organic compound is based on dihydroxy dicarboxylic acid, which can be reversibly oxidized to a quinoid structure. 2. Электродный материал по п.1, в котором содержится один или более других металлических ионов.2. The electrode material according to claim 1, which contains one or more other metal ions. 3. Электродный материал по п.2, в котором по меньшей мере один другой металлический ион выбирается из группы, состоящей из металлов: кобальт, железо, никель, медь, марганец, хром, ванадий и титан.3. The electrode material according to claim 2, in which at least one other metal ion is selected from the group consisting of metals: cobalt, iron, nickel, copper, manganese, chromium, vanadium and titanium. 4. Электродный металл по п.1, в котором дигидроксидикарбоновой кислотой является дигидроксибензолдикарбоновая кислота.4. The electrode metal according to claim 1, in which the dihydroxy dicarboxylic acid is dihydroxybenzenedicarboxylic acid. 5. Электродный металл по любому из п.п.1-4, в котором дигидроксидикарбоновой кислотой является 2,5-дигидрокситерефталевая кислота.5. The electrode metal according to any one of claims 1 to 4, in which the dihydroxy dicarboxylic acid is 2,5-dihydroxy terephthalic acid. 6. Пористая металлоорганическая каркасная структура, как раскрывается в любом из п.п.1-5.6. Porous organometallic frame structure, as disclosed in any one of claims 1 to 5. 7. Применение пористой металлоорганической каркасной структуры по п.6 в электродном материале для литий-ионных аккумуляторов.7. The use of the porous organometallic frame structure according to claim 6 in the electrode material for lithium-ion batteries. 8. Аккумулятор, содержащий электродный материал по любому из п.п.1-5.8. A battery containing electrode material according to any one of claims 1 to 5. 9. Электрохимический элемент, содержащий электродный материал по любому из п.п.1-5.9. An electrochemical cell containing electrode material according to any one of claims 1 to 5. 10. Применение пористой металлоорганической каркасной структуры по п.6 в электродном материале для электрохимических элементов. 10. The use of the porous organometallic frame structure according to claim 6 in the electrode material for electrochemical cells.
RU2012149351/04A 2010-04-21 2011-04-19 NEW METAL-ORGANIC FRAME-BASED STRUCTURES AS ELECTRODE MATERIAL FOR LITHIUM-ION BATTERIES RU2012149351A (en)

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EP10160560.8 2010-04-21
EP10160560 2010-04-21
PCT/IB2011/051696 WO2011132147A1 (en) 2010-04-21 2011-04-19 Novel metal-organic frameworks as electrode material for lithium ion accumulators

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CN105390696B (en) * 2015-12-04 2018-01-23 华南师范大学 A kind of preparation method of height ratio capacity lithium cell cathode material
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CN106981661B (en) * 2017-06-05 2019-08-23 南京工业大学 A kind of preparation method of lithium ion battery electrode material
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KR102488917B1 (en) * 2017-11-24 2023-01-17 한국재료연구원 Method of manufacturing fast chargeable electrode with 3D printed metal organic framework
FR3082513B1 (en) * 2018-06-18 2020-09-25 Commissariat Energie Atomique PROCESS FOR THE PREPARATION OF A LITHIA METAL OXIDE THAT CAN BE USED AS AN ACTIVE MATERIAL FOR A POSITIVE ELECTRODE
CN109054035B (en) * 2018-06-29 2020-11-10 中国科学院合肥物质科学研究院 Nanometer flower-shaped Ti-MOF fluorescent probe material and preparation method and application thereof
CN110491686A (en) * 2019-08-28 2019-11-22 齐鲁工业大学 A kind of preparation method and application of bimetallic organic coordination compounds electrode material
CN112490412B (en) * 2019-09-11 2022-10-04 肇庆市华师大光电产业研究院 Novel sodium-ion battery negative electrode material and preparation method thereof
JP7354740B2 (en) 2019-10-01 2023-10-03 株式会社豊田中央研究所 Method for manufacturing electricity storage device and method for activating electrode for electricity storage device
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WO2011132147A1 (en) 2011-10-27
CN102893434A (en) 2013-01-23
CA2795517A1 (en) 2011-10-27
EP2561568A1 (en) 2013-02-27
JP2013525972A (en) 2013-06-20
KR20130033369A (en) 2013-04-03

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