RU2012122790A - DEVICE FOR PROTECTING COMPOSITE MATERIALS FROM ELECTROMAGNETIC EXPOSURE - Google Patents

DEVICE FOR PROTECTING COMPOSITE MATERIALS FROM ELECTROMAGNETIC EXPOSURE Download PDF

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RU2012122790A
RU2012122790A RU2012122790/05A RU2012122790A RU2012122790A RU 2012122790 A RU2012122790 A RU 2012122790A RU 2012122790/05 A RU2012122790/05 A RU 2012122790/05A RU 2012122790 A RU2012122790 A RU 2012122790A RU 2012122790 A RU2012122790 A RU 2012122790A
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laminate
sheet
laminate according
polymer
substrate
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RU2012122790/05A
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RU2546729C2 (en
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Эмили ФИССЕ
Джон ЭЛЛИС
Пол МАККЕНЗИ
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Хексел Композитс Лимитед
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/06—Interconnection of layers permitting easy separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B64—AIRCRAFT; AVIATION; COSMONAUTICS
    • B64D—EQUIPMENT FOR FITTING IN OR TO AIRCRAFT; FLIGHT SUITS; PARACHUTES; ARRANGEMENTS OR MOUNTING OF POWER PLANTS OR PROPULSION TRANSMISSIONS IN AIRCRAFT
    • B64D45/00—Aircraft indicators or protectors not otherwise provided for
    • B64D45/02—Lightning protectors; Static dischargers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/26—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer which influences the bonding during the lamination process, e.g. release layers or pressure equalising layers
    • B32B2037/268—Release layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/10—Fibres of continuous length
    • B32B2305/20—Fibres of continuous length in the form of a non-woven mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00—Metals, their alloys or their compounds
    • B32B2311/12—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2331/00—Polyvinylesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2361/00—Phenoplast, aminoplast
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2363/00—Epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2398/00—Unspecified macromolecular compounds
    • B32B2398/10—Thermosetting resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/18—Aircraft
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/0007—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality
    • B32B37/0015—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality to avoid warp or curl
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]

Abstract

1. Отверждаемый гибкий устойчивый к электромагнитному воздействию ламинат, включающий слой электропроводного металлического материала и термореактивный полимер, в котором внешняя поверхность ламината включает снимаемый лист подложки в контакте с полимером, и ламинат дополнительно включает практически нетрансформируемый лист твердого материала.2. Ламинат по п.1, который включает полимерный слой на внешней поверхности, не покрытой листом подложки.3. Ламинат по п.2, в котором внешняя поверхность ламината, не покрытая листом подложки, является более клейкой, чем внешняя поверхность, покрытая листом подложки.4. Ламинат по п.1, который включает непрерывный канал полимера сквозь толщину ламината.5. Ламинат по п.1, который предпочтительно является достаточно гибким, чтобы иметь способность образовывать рулон диаметром менее чем 20 см.6. Ламинат по п.1, который имеет толщину от 0,5 до 5,0 мм.7. Ламинат по п.1, в котором электропроводный металлический материал находится в виде листа и является пористым.8. Ламинат по п.7, в котором металлический материал представляет собой растянутую металлическую фольгу, принимающую форму проволочного сетчатого материала.9. Ламинат по п.8, в котором металлический материал имеет поверхностную плотность от 50 до 1500 г/м.10. Ламинат по п.1, в котором поверхностная плотность ламината, исключая металлический элемент, составляет менее чем 800 г/м.11. Ламинат по п.1, в котором практически нетрансформируемый твердый материал является пористым.12. Ламинат по п.11, в котором практически нетрансформируемый твердый материал является электроизоляционным.13. Ламинат по п.1, в котором практически нетрансформируемый твер�1. A curable flexible electromagnetic-resistant laminate comprising a layer of an electrically conductive metal material and a thermosetting polymer, in which the outer surface of the laminate includes a removable substrate sheet in contact with the polymer, and the laminate further includes a substantially non-transformable sheet of solid material. A laminate according to claim 1, which comprises a polymer layer on an external surface not covered by a substrate sheet. A laminate according to claim 2, wherein the outer surface of the laminate not covered by the substrate sheet is more adhesive than the outer surface coated by the substrate sheet. A laminate according to claim 1, which includes a continuous polymer channel through the thickness of the laminate. The laminate according to claim 1, which is preferably flexible enough to be able to form a roll with a diameter of less than 20 cm. The laminate according to claim 1, which has a thickness of from 0.5 to 5.0 mm. The laminate according to claim 1, in which the electrically conductive metal material is in the form of a sheet and is porous. The laminate according to claim 7, in which the metal material is a stretched metal foil, which takes the form of a wire mesh material. The laminate of claim 8, in which the metal material has a surface density of from 50 to 1500 g / m. The laminate according to claim 1, wherein the surface density of the laminate, excluding the metal element, is less than 800 g / m. The laminate according to claim 1, wherein the substantially non-transformable solid material is porous. The laminate according to claim 11, wherein the substantially non-transformable solid material is electrical insulating. The laminate according to claim 1, wherein the substantially non-transformable solid�

Claims (28)

1. Отверждаемый гибкий устойчивый к электромагнитному воздействию ламинат, включающий слой электропроводного металлического материала и термореактивный полимер, в котором внешняя поверхность ламината включает снимаемый лист подложки в контакте с полимером, и ламинат дополнительно включает практически нетрансформируемый лист твердого материала.1. A curable flexible electromagnetic-resistant laminate comprising a layer of an electrically conductive metal material and a thermosetting polymer, in which the outer surface of the laminate includes a removable substrate sheet in contact with the polymer, and the laminate further includes a substantially non-transformable sheet of solid material. 2. Ламинат по п.1, который включает полимерный слой на внешней поверхности, не покрытой листом подложки.2. The laminate according to claim 1, which includes a polymer layer on an external surface not covered by a substrate sheet. 3. Ламинат по п.2, в котором внешняя поверхность ламината, не покрытая листом подложки, является более клейкой, чем внешняя поверхность, покрытая листом подложки.3. The laminate according to claim 2, in which the outer surface of the laminate not covered by the substrate sheet is more adhesive than the outer surface coated by the substrate sheet. 4. Ламинат по п.1, который включает непрерывный канал полимера сквозь толщину ламината.4. The laminate according to claim 1, which includes a continuous channel of the polymer through the thickness of the laminate. 5. Ламинат по п.1, который предпочтительно является достаточно гибким, чтобы иметь способность образовывать рулон диаметром менее чем 20 см.5. The laminate according to claim 1, which is preferably flexible enough to have the ability to form a roll with a diameter of less than 20 cm 6. Ламинат по п.1, который имеет толщину от 0,5 до 5,0 мм.6. The laminate according to claim 1, which has a thickness of from 0.5 to 5.0 mm. 7. Ламинат по п.1, в котором электропроводный металлический материал находится в виде листа и является пористым.7. The laminate according to claim 1, in which the electrically conductive metal material is in the form of a sheet and is porous. 8. Ламинат по п.7, в котором металлический материал представляет собой растянутую металлическую фольгу, принимающую форму проволочного сетчатого материала.8. The laminate according to claim 7, in which the metal material is a stretched metal foil, which takes the form of a wire mesh material. 9. Ламинат по п.8, в котором металлический материал имеет поверхностную плотность от 50 до 1500 г/м2.9. The laminate of claim 8, in which the metal material has a surface density of from 50 to 1500 g / m 2 . 10. Ламинат по п.1, в котором поверхностная плотность ламината, исключая металлический элемент, составляет менее чем 800 г/м2.10. The laminate according to claim 1, in which the surface density of the laminate, excluding the metal element, is less than 800 g / m 2 . 11. Ламинат по п.1, в котором практически нетрансформируемый твердый материал является пористым.11. The laminate according to claim 1, wherein the substantially non-transformable solid material is porous. 12. Ламинат по п.11, в котором практически нетрансформируемый твердый материал является электроизоляционным.12. The laminate according to claim 11, in which the practically non-transformable solid material is electrical insulating. 13. Ламинат по п.1, в котором практически нетрансформируемый твердый материал имеет поверхностную плотность от 5 до 100 г/м2.13. The laminate according to claim 1, in which the practically non-transformable solid material has a surface density of from 5 to 100 g / m 2 . 14. Ламинат по п.1, в котором лист практически нетрансформируемого твердого материала находится между электропроводным металлическим материалом и листом подложки.14. The laminate according to claim 1, in which a sheet of substantially non-transformable solid material is located between the electrically conductive metal material and the substrate sheet. 15. Ламинат по п.1, в котором ламинат включает второй практически нетрансформируемый лист твердого материала.15. The laminate according to claim 1, in which the laminate includes a second practically nontransformable sheet of solid material. 16. Ламинат по п.15, в котором один лист практически нетрансформируемого твердого материала находится на любой стороне металлического материала.16. The laminate according to clause 15, in which one sheet of practically nontransformable solid material is on either side of the metal material. 17. Ламинат по п.1, в котором находится большее количество полимера на стороне металлического материала, не содержащей лист подложки, чем на стороне, содержащей лист подложки.17. The laminate according to claim 1, in which there is a greater amount of polymer on the side of a metal material not containing a substrate sheet than on the side containing the substrate sheet. 18. Способ изготовления устойчивого к электромагнитному воздействию ламината по любому из предыдущих пунктов, где способ включает непрерывное совместное поступление листа электропроводного металлического материала и листа практически нетрансформируемого твердого материала и приведение в контакт с внешними поверхностями материала двух листов материала подложки, по меньшей мере один из которых покрыт термореактивным полимером, последующее совместное сжатие листов и заключительное снятие листа материала подложки.18. A method of manufacturing an electromagnetic-resistant laminate according to any one of the preceding paragraphs, where the method includes the continuous joint receipt of a sheet of electrically conductive metal material and a sheet of practically non-transformable solid material and bringing into contact with the outer surfaces of the material two sheets of substrate material, at least one of which coated with a thermosetting polymer, subsequent joint compression of the sheets and the final removal of the sheet of substrate material. 19. Способ по п.18, в котором сжатие листов осуществляют, пропуская листы через один или более валков.19. The method according to p, in which the compression of the sheets is carried out by passing the sheets through one or more rolls. 20. Способ по п.18, в котором оба листа материала подложки покрыты термореактивным полимером.20. The method of claim 18, wherein both sheets of the substrate material are coated with a thermosetting polymer. 21. Способ по любому из пп.18-20, в котором лист практически нетрансформируемого твердого материала прикреплен к полимерному покрытию, которое покрывает лист материала подложки.21. The method according to any one of claims 18 to 20, wherein the sheet of substantially non-transformable solid material is attached to a polymer coating that covers the sheet of substrate material. 22. Способ по п.21, в котором второй практически нетрансформируемый твердый материал также прикреплен к полимерному покрытию, которое покрывает другой лист материала подложки.22. The method according to item 21, in which the second practically nontransformable solid material is also attached to the polymer coating, which covers another sheet of substrate material. 23. Способ по п.18, за которым следует сворачивание ламината с образованием рулона.23. The method of claim 18, followed by folding the laminate to form a roll. 24. Способ укладки на поверхность формы отверждаемого гибкого устойчивого к электромагнитному воздействию ламината по любому из пп.1-17, в котором внешняя поверхность ламината включает снимаемый лист подложки в контакте с полимером, где ламинат поступает автоматически с рулона на поверхность формы с помощью инструментальной головки, таким образом, что внешняя поверхность ламината, включающая клейкий отверждаемый термореактивный полимер, вступает в контакт с поверхностью формы, и ламинат прикрепляется к поверхности формы, когда инструмент накладывает ламинат, и лист подложки удаляется, оставляя ламинат на своем месте на поверхности формы без своего листа подложки.24. The method of laying on the mold surface a curable flexible laminate resistant to electromagnetic effects according to any one of claims 1-17, wherein the outer surface of the laminate includes a removable substrate sheet in contact with the polymer, where the laminate is fed automatically from the roll to the mold surface using a tool head so that the outer surface of the laminate, including the adhesive curable thermosetting polymer, comes into contact with the surface of the mold, and the laminate is attached to the surface of the mold when the tool t imposes laminate sheet and the substrate is removed, leaving the laminate in place on the surface of the mold without its backing sheet. 25. Способ по п.24, за которым следует стадия укладки на открытую поверхность уложенного ламината ряда препрегов, включающих структурные волокна и термореактивный полимер.25. The method according to paragraph 24, followed by the stage of laying on the open surface of the laid laminate a number of prepregs, including structural fibers and a thermosetting polymer. 26. Способ по п.25, в котором конструкцию отверждают при воздействии повышенной температуры и, необязательно, повышенного давления, получая устойчивый к электромагнитному воздействию отвержденный ламинат.26. The method according A.25, in which the structure is cured by exposure to elevated temperature and, optionally, increased pressure, obtaining a cured laminate resistant to electromagnetic effects. 27. Устойчивый к электромагнитному воздействию отвержденный ламинат, получаемый способом по п.26.27. A cured laminate resistant to electromagnetic effects obtained by the method according to p. 26. 28. Компонент корпуса аэрокосмического летательного аппарата, включающий отвержденный ламинат по п.27. 28. Component of the hull of an aerospace aircraft, including the cured laminate according to item 27.
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