RU2009143973A - METHOD FOR JOINT PRODUCTION OF METHANOL AND AMMONIA FROM ORIGINAL HYDROCARBON RAW MATERIAL - Google Patents

METHOD FOR JOINT PRODUCTION OF METHANOL AND AMMONIA FROM ORIGINAL HYDROCARBON RAW MATERIAL Download PDF

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RU2009143973A
RU2009143973A RU2009143973/05A RU2009143973A RU2009143973A RU 2009143973 A RU2009143973 A RU 2009143973A RU 2009143973/05 A RU2009143973/05 A RU 2009143973/05A RU 2009143973 A RU2009143973 A RU 2009143973A RU 2009143973 A RU2009143973 A RU 2009143973A
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methanol
ammonia
synthesis
synthesis gas
production
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RU2009143973/05A
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RU2534092C2 (en
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Пат А. ХАН (DK)
Пат А. ХАН
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Хальдор Топсеэ А/С (DK)
Хальдор Топсеэ А/С
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/04—Preparation of ammonia by synthesis in the gas phase
    • C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/04—Preparation of ammonia by synthesis in the gas phase
    • C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
    • C01C1/0488—Processes integrated with preparations of other compounds, e.g. methanol, urea or with processes for power generation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/068—Ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1. Способ совместного производства метанола и аммиака из исходного углеводородного сырья, содержащий последовательные этапы: ! а) получение синтез-газа производства метанола, содержащего водород, оксиды углерода и азот, посредством парового риформинга исходного углеводородного сырья на первичной стадии риформинга и затем на вторичной стадии риформинга с воздушным дутьем; ! (b) каталитическая конверсия оксидов углерода и водорода синтез-газа производства метанола на однопроходной стадии синтеза метанола и отведение выходящего продукта, содержащего метанол, и отходящего газового потока, содержащего азот, водород и неконвертированные оксиды углерода; ! (c) получение синтез-газа производства аммиака без применения реакции сдвига с водяным паром и без применения удаления диоксида углерода путем удаления неконвертированных оксидов углерода газового потока этапа (b) на стадии каталитической метанации и отведение синтез-газа производства аммиака, имеющего молярное отношение H2:N2, равное 3:1; ! (d) каталитическая конверсия азота и водорода синтез-газа производства аммиака на стадии синтеза аммиака и отведение выходящего продукта, содержащего аммиак, и отходящего газового потока, содержащего водород, азот и метан. ! 2. Способ по п.1, в котором исходное углеводородное сырье представляет собой природный газ или заменитель природного газа (SNG). ! 3. Способ по п.1, в котором стадия синтеза метанола на этапе (b) проводится посредством пропускания синтез-газа через один кипящий водяной реактор и затем через адиабатический реактор с неподвижным слоем катализатора, или посредством пропускания синтез-газа через каскад кипящих � 1. A method for the joint production of methanol and ammonia from a hydrocarbon feedstock, comprising successive steps:! a) obtaining synthesis gas for the production of methanol containing hydrogen, carbon oxides and nitrogen, through steam reforming of the hydrocarbon feedstock in the primary reforming stage and then in the secondary reforming phase with air blasting; ! (b) the catalytic conversion of carbon monoxide and hydrogen synthesis gas of methanol production in a single-pass methanol synthesis step and the removal of the methanol-containing effluent and the exhaust gas stream containing nitrogen, hydrogen and unconverted carbon oxides; ! (c) producing synthesis gas of ammonia production without applying a water-shear reaction and without using carbon dioxide removal by removing unconverted carbon oxides from the gas stream of step (b) in the catalytic methanation step and removing synthesis gas from ammonia production having a molar ratio of H2: N2 equal to 3: 1; ! (d) the catalytic conversion of nitrogen and hydrogen from the synthesis gas of ammonia production in the ammonia synthesis stage and the removal of the effluent containing ammonia and the exhaust gas stream containing hydrogen, nitrogen and methane. ! 2. The method of claim 1, wherein the hydrocarbon feed is natural gas or a natural gas substitute (SNG). ! 3. The method according to claim 1, in which the methanol synthesis stage in step (b) is carried out by passing synthesis gas through one boiling water reactor and then through an adiabatic reactor with a fixed catalyst bed, or by passing synthesis gas through a cascade of boiling �

Claims (7)

1. Способ совместного производства метанола и аммиака из исходного углеводородного сырья, содержащий последовательные этапы:1. A method for the joint production of methanol and ammonia from a hydrocarbon feedstock, comprising successive steps: а) получение синтез-газа производства метанола, содержащего водород, оксиды углерода и азот, посредством парового риформинга исходного углеводородного сырья на первичной стадии риформинга и затем на вторичной стадии риформинга с воздушным дутьем;a) obtaining synthesis gas for the production of methanol containing hydrogen, carbon oxides and nitrogen, through steam reforming of the hydrocarbon feedstock in the primary reforming stage and then in the secondary reforming phase with air blasting; (b) каталитическая конверсия оксидов углерода и водорода синтез-газа производства метанола на однопроходной стадии синтеза метанола и отведение выходящего продукта, содержащего метанол, и отходящего газового потока, содержащего азот, водород и неконвертированные оксиды углерода;(b) the catalytic conversion of carbon monoxide and hydrogen synthesis gas of methanol production in a single-pass methanol synthesis step and the removal of the methanol-containing effluent and the exhaust gas stream containing nitrogen, hydrogen and unconverted carbon oxides; (c) получение синтез-газа производства аммиака без применения реакции сдвига с водяным паром и без применения удаления диоксида углерода путем удаления неконвертированных оксидов углерода газового потока этапа (b) на стадии каталитической метанации и отведение синтез-газа производства аммиака, имеющего молярное отношение H2:N2, равное 3:1;(c) producing synthesis gas of ammonia production without applying a water-shear reaction and without using carbon dioxide removal by removing unconverted carbon oxides from the gas stream of step (b) in a catalytic methanation step and discharging synthesis gas of ammonia production having a molar ratio of H 2 : N 2 equal to 3: 1; (d) каталитическая конверсия азота и водорода синтез-газа производства аммиака на стадии синтеза аммиака и отведение выходящего продукта, содержащего аммиак, и отходящего газового потока, содержащего водород, азот и метан.(d) the catalytic conversion of nitrogen and hydrogen from the synthesis gas of ammonia production in the ammonia synthesis stage and the removal of the effluent containing ammonia and the exhaust gas stream containing hydrogen, nitrogen and methane. 2. Способ по п.1, в котором исходное углеводородное сырье представляет собой природный газ или заменитель природного газа (SNG).2. The method of claim 1, wherein the hydrocarbon feed is natural gas or a natural gas substitute (SNG). 3. Способ по п.1, в котором стадия синтеза метанола на этапе (b) проводится посредством пропускания синтез-газа через один кипящий водяной реактор и затем через адиабатический реактор с неподвижным слоем катализатора, или посредством пропускания синтез-газа через каскад кипящих водяных реакторов и затем через адиабатический реактор с неподвижным слоем катализатора.3. The method according to claim 1, wherein the methanol synthesis step of (b) is carried out by passing synthesis gas through one boiling water reactor and then through an adiabatic reactor with a fixed catalyst bed, or by passing synthesis gas through a cascade of boiling water reactors and then through a fixed bed catalyst adiabatic reactor. 4. Способ по п.3, в котором кипящий водяной реактор представляет собой отдельно взятый реактор конденсационного типа для метанола, который содержит внутри обычный кожух с неподвижным слоем гранулированного катализатора синтеза метанола и охлаждающие устройства, приспособленные для непрямого охлаждения синтез-газа производства метанола с охлаждающим агентом.4. The method according to claim 3, in which the boiling water reactor is a single condensation type reactor for methanol, which contains inside a conventional casing with a fixed bed of a granular methanol synthesis catalyst and cooling devices adapted for indirect cooling of the synthesis gas of methanol production with cooling agent. 5. Способ по п.3, содержащий также охлаждение синтез-газа, отводимого из каждого метанольного реактора, для конденсации метанола и пропускание газа через сепаратор, отведение нижней фракции из сепаратора, содержащей сырой метанол, отведение верхней фракции, содержащей синтез-газ, который пропускается к следующему метанольному реактору, и формирование единого выходящего жидкостного потока, содержащего метанол, посредством объединения нижних фракций из сепараторов каждого реактора, содержащих сырой метанол.5. The method according to claim 3, further comprising cooling the synthesis gas discharged from each methanol reactor to condense methanol and passing gas through a separator, discharging the lower fraction from the separator containing crude methanol, and discharging the upper fraction containing synthesis gas, which is passed to the next methanol reactor, and the formation of a single effluent liquid stream containing methanol by combining the lower fractions from the separators of each reactor containing crude methanol. 6. Способ по любому одному из пп.1-5, содержащий также отведение богатого водородом потока со стадии синтеза аммиака и добавление этого потока на этап (b).6. The method according to any one of claims 1 to 5, further comprising removing the hydrogen rich stream from the ammonia synthesis step and adding this stream to step (b). 7. Способ по любому одному из пп.1-5, в котором отходящий газовый поток на этапе (d), содержащий водород, азот и метан, возвращается на этап (а). 7. The method according to any one of claims 1 to 5, in which the exhaust gas stream in step (d) containing hydrogen, nitrogen and methane is returned to step (a).
RU2009143973/05A 2008-11-28 2009-11-27 Method of combined methanol and ammonia production from initial hydrocarbon raw material RU2534092C2 (en)

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CN101830775A (en) 2010-09-15
CN101830775B (en) 2013-09-11
US8303923B2 (en) 2012-11-06
EP2192082A1 (en) 2010-06-02
EP2192082B1 (en) 2013-07-03
US20100133472A1 (en) 2010-06-03
CA2686034C (en) 2015-04-28
RU2534092C2 (en) 2014-11-27

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