RU2007139334A - METHOD FOR STABILIZING CELLULOSE FIBERS, ESPECIALLY TEXTILE FABRIC CONTAINING CELLULOSE FIBERS - Google Patents

METHOD FOR STABILIZING CELLULOSE FIBERS, ESPECIALLY TEXTILE FABRIC CONTAINING CELLULOSE FIBERS Download PDF

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RU2007139334A
RU2007139334A RU2007139334/04A RU2007139334A RU2007139334A RU 2007139334 A RU2007139334 A RU 2007139334A RU 2007139334/04 A RU2007139334/04 A RU 2007139334/04A RU 2007139334 A RU2007139334 A RU 2007139334A RU 2007139334 A RU2007139334 A RU 2007139334A
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cellulosic fibers
water
binding component
solution
fibers
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RU2007139334/04A
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Томас БЕХТОЛЬД (AT)
Томас БЕХТОЛЬД
Константа ИБАНЕСКУ (AT)
Константа ИБАНЕСКУ
Кристиан ШИМПЕР (AT)
Кристиан ШИМПЕР
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Беннингер Аг (Ch)
Беннингер Аг
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/60—Ammonia as a gas or in solution
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/67—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with cyanogen or compounds thereof, e.g. with cyanhydric acid, cyanic acid, isocyanic acid, thiocyanic acid, isothiocyanic acid or their salts, or with cyanamides; with carbamic acid or its salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/45—Shrinking resistance, anti-felting properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Method for stabilizing cellulose fibers (A) and/or materials, particularly textile fabrics, made from them, by treatment with a solution containing a water-binding component (I); a swelling agent (II) and water.

Claims (13)

1. Способ стабилизации целлюлозных волокон и/или материала, содержащих целлюлозные волокна, особенно текстильного полотна ткани, содержащего целлюлозные волокна, характеризующийся тем, что целлюлозные волокна приводят в контакт с раствором для обработки, содержащим:1. A method for stabilizing cellulosic fibers and / or material containing cellulosic fibers, especially a textile fabric web containing cellulosic fibers, characterized in that the cellulosic fibers are brought into contact with a treatment solution containing: (a) водосвязывающий компонент,(a) a water binding component, (b) агент, вызывающий набухание, и(b) a swelling agent, and (c) воду,(c) water материал, содержащий целлюлозные волокна, особенно текстильное полотно ткани, содержащее целлюлозные волокна, существенно, предпочтительно полностью, свободны от нитей и волокон, основанных на регенерированной целлюлозе, и фракция раствора для обработки, которая относится к водосвязывающему компоненту (а) составляет, по меньшей мере, 10% по массе и предпочтительно 10-90% по массе, и компоненты (а), (b) и (с) и их фракции в растворе для обработки выбирают так, чтобы осуществить набухание целлюлозных волокон преимущественно в аморфных зонах.a material containing cellulosic fibers, especially a textile fabric containing cellulosic fibers, is substantially, preferably completely free of filaments and fibers based on regenerated cellulose, and the fraction of the treatment solution that relates to the water-binding component (a) is at least , 10% by weight and preferably 10-90% by weight, and components (a), (b) and (c) and their fractions in the treatment solution are selected so as to swell cellulose fibers predominantly in amorphous zones. 2. Способ по п.1, характеризующийся тем, что материал, содержащий целлюлозные волокна, особенно текстильное полотно ткани, содержит, по существу, только целлюлозные волокна.2. The method according to claim 1, characterized in that the material containing cellulosic fibers, especially the textile fabric, contains essentially only cellulosic fibers. 3. Способ по п.1, характеризующийся тем, что один водосвязывающий компонент (а) содержит спирт, в частности многоатомный, предпочтительно алифатический спирт, более предпочтительно, выбранный из группы, состоящей из метанола, этанола, 1-пропанола, 2-пропанола, 1,3-пропандиола, 1,2-пропандиола, 1,2,3-пропантриола, 1-бутанола,2-бутанола,трет-бутанола, 1,2-бутандиола, 1,3-бутандиола, 1,4-бутандиола, 2,3-бутандиола и их смесей.3. The method according to claim 1, characterized in that one water-binding component (a) contains an alcohol, in particular a polyhydric, preferably aliphatic alcohol, more preferably selected from the group consisting of methanol, ethanol, 1-propanol, 2-propanol, 1,3-propanediol, 1,2-propanediol, 1,2,3-propanetriol, 1-butanol, 2-butanol, tert-butanol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol and mixtures thereof. 4. Способ по п.1, характеризующийся тем, что один водосвязывающий компонент (а) смешивают с раствором для обработки, целиком выбранным из группы, состоящей из углеводов, мочевины, неорганических солей и их смесей.4. The method according to claim 1, characterized in that one water-binding component (a) is mixed with a solution for processing, entirely selected from the group consisting of carbohydrates, urea, inorganic salts and mixtures thereof. 5. Способ по п.1, характеризующийся тем, что 1,2,3-пропантриол, NaCl и их смеси применяют в качестве водосвязывающего компонента (а).5. The method according to claim 1, characterized in that 1,2,3-propanetriol, NaCl and mixtures thereof are used as the water-binding component (a). 6. Способ по п.1, где фракцию раствора для обработки, которая относится к водосвязывающему компоненту и/или типу водосвязывающего компонента (а), выбирают так, чтобы в результате иметь доступное свободное содержание воды в растворе для обработки не более 35 моль/л, предпочтительно не более 25 моль/л и более предпочтительно не более 15 моль/л.6. The method according to claim 1, where the fraction of the solution for processing, which refers to the water-binding component and / or type of water-binding component (a), is chosen so that as a result have an available free water content in the solution for processing of not more than 35 mol / l preferably not more than 25 mol / L and more preferably not more than 15 mol / L. 7. Способ по п.1, характеризующийся тем, что агент, вызывающий набухание включает реактив или смесь реактивов, которые, особенно, концентрации, по меньшей мере, 1 моль/л в растворе для обработки приводят к рН≥9, предпочтительно рН≥11 и более предпочтительно рН≥13.7. The method according to claim 1, characterized in that the agent causing the swelling includes a reagent or a mixture of reagents, which, especially, a concentration of at least 1 mol / L in the solution for processing lead to pH≥9, preferably pH≥11 and more preferably pH≥13. 8. Способ по п.1, характеризующийся тем, что агент, вызывающий набухание (b), содержит, по меньшей мере, один реагент, выбранный из группы, состоящей из гидроксидов щелочных металлов, гидроксидов щелочноземельных металлов, аминов, тиоцианатов, иодидов, комплексов, раствора аммиака и их смесей.8. The method according to claim 1, characterized in that the swelling agent (b) contains at least one reagent selected from the group consisting of alkali metal hydroxides, alkaline earth metal hydroxides, amines, thiocyanates, iodides, complexes ammonia solution and mixtures thereof. 9. Способ по п.1, характеризующийся тем, что стабилизацию осуществляют при температуре 10°С-180°С и предпочтительно при температуре 15°С-105°С.9. The method according to claim 1, characterized in that the stabilization is carried out at a temperature of 10 ° C-180 ° C and preferably at a temperature of 15 ° C-105 ° C. 10. Способ по п.1, характеризующийся тем, что обработку с целью разбухания проводят перед заключительной отделкой/операцией по высококачественной отделке на целлюлозных волокнах или, в частности, на материале, содержащем, по существу, только целлюлозные волокна, в частности, способом сушки/шоковой конденсации или предпочтительно способом влажной сшивки.10. The method according to claim 1, characterized in that the swelling treatment is carried out before the final finishing / high-quality finishing operation on cellulose fibers or, in particular, on a material containing essentially only cellulose fibers, in particular, by a drying method shock condensation, or preferably wet crosslinking. 11. Способ по п.10, характеризующийся тем, что в зависимости от свойства, достижимого после заключительной отделки/операции по высококачественной отделке выбирают компоненты (а), (b) и (с) раствора для обработки и/или взаимно согласовывают их фракции в растворе для обработки.11. The method according to claim 10, characterized in that, depending on the property attainable after the final finishing / high-quality finishing operation, components (a), (b) and (c) of the treatment solution are selected and / or their fractions are mutually agreed upon solution for processing. 12. Способ по п.1, характеризующийся тем, что стабилизацию осуществляют как непрерывную операцию и с материалом, который вынужденно закреплен, в частности, с материалом, который вынужденно закреплен.12. The method according to claim 1, characterized in that the stabilization is carried out as a continuous operation with a material that is forcedly fixed, in particular, with a material that is forcedly fixed. 13. Применение водосвязывающего компонента в качестве добавки в растворе для обработки для стабилизации целлюлозных волокон или особенно материалов, содержащих, по существу, только целлюлозные волокна, для увеличения получающейся в результате фракции целлюлозных волокон, набухших в аморфных зонах, и/или для уменьшения получающейся в результате фракции целлюлозных волокон, набухших в кристаллических зонах, где целлюлозные волокна существенно, предпочтительно полностью, свободные от нитей и волокон, основанных на регенерированной целлюлозе, и фракция раствора для обработки, которая может относиться к водосвязывающему компоненту (а) составляет, по меньшей мере, 10% по массе и предпочтительно 10-90% по массе.13. The use of a water-binding component as an additive in a treatment solution for stabilizing cellulosic fibers or especially materials containing essentially only cellulosic fibers to increase the resulting fraction of cellulosic fibers swollen in amorphous zones and / or to reduce the resulting the result is a fraction of cellulosic fibers swollen in crystalline zones where the cellulosic fibers are substantially, preferably completely, free from filaments and fibers based on regenerated cellulose the vine, and the fraction of the solution for processing, which may relate to the water-binding component (a) is at least 10% by weight and preferably 10-90% by weight.
RU2007139334/04A 2005-03-24 2006-03-21 METHOD FOR STABILIZING CELLULOSE FIBERS, ESPECIALLY TEXTILE FABRIC CONTAINING CELLULOSE FIBERS RU2007139334A (en)

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Application Number Priority Date Filing Date Title
EP05102374A EP1705285B1 (en) 2005-03-24 2005-03-24 Process for the stabilisation of cellulosic fibres, especially of a textile web comprising cellulosic fibres
EP05102374.5 2005-03-24

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EP (1) EP1705285B1 (en)
CN (1) CN101146949A (en)
AT (1) ATE490367T1 (en)
BR (1) BRPI0609467A2 (en)
DE (1) DE502005010612D1 (en)
RU (1) RU2007139334A (en)
WO (1) WO2006100249A1 (en)

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