RU2006146997A - METHOD FOR PRODUCING BASIC OIL - Google Patents

METHOD FOR PRODUCING BASIC OIL Download PDF

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Publication number
RU2006146997A
RU2006146997A RU2006146997/04A RU2006146997A RU2006146997A RU 2006146997 A RU2006146997 A RU 2006146997A RU 2006146997/04 A RU2006146997/04 A RU 2006146997/04A RU 2006146997 A RU2006146997 A RU 2006146997A RU 2006146997 A RU2006146997 A RU 2006146997A
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Russia
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fischer
tropsch
product
solvent
stage
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RU2006146997/04A
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Russian (ru)
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Жерар БЕНАР (FR)
Жерар БЕНАР
Жильбер Робер Бернар ЖЕРМЕН (FR)
Жильбер Робер Бернар Жермен
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL)
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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Publication of RU2006146997A publication Critical patent/RU2006146997A/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M109/00—Lubricating compositions characterised by the base-material being a compound of unknown or incompletely defined constitution
    • C10M109/02—Reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/02—Specified values of viscosity or viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C10M2205/173—Fisher Tropsch reaction products used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/74—Noack Volatility

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lubricants (AREA)

Abstract

1. Способ получения базового масла, имеющего кинематическую вязкость при 100°С выше 6 сСт, из воска, полученного с помощью процесса Фишера-Тропша и имеющего температуру кипения при рекуперации Т10 мас.% выше 500°С, путем выполнения следующих стадий: (а1) осуществление синтеза Фишера-Тропша для получения продукта синтеза Фишера-Тропша, (а2) выделение методом дистилляции из указанного продукта синтеза Фишера-Тропша воска Фишера-Тропша, промежуточного восковидного продукта, более чем 80 мас.% которого имеет температуру кипения от 300 до 500°С, и углеводородного растворителя, имеющего температуру рекуперации Т90 мас.% ниже 400°С, и (а3) комбинирование воска Фишера-Тропша с растворителем с целью получения сырья для стадии (а); (а) контактирование сырья, содержащего воск Фишера-Тропша и от 5 до 40 мас.% углеводородного растворителя, имеющего температуру рекуперации Т90 мас.% ниже 400°С, с катализатором гидроизомеризации в условиях гидроизомеризации,(б) депарафинизация изомеризованного продукта со стадии (а) и выделение базового масла из депарафинизированного масла.2. Способ по п.1, в котором содержание воска Фишера-Тропша в сырье для стадии (а) составляет выше 70 мас.%.3. Способ по п.1, в котором растворителем является продукт, полученный с помощью процесса Фишера-Тропша.4. Способ по п.1, в котором температура рекуперации Т10 мас.% растворителя составляет от 250 до 370°С.5. Способ по п.1, в котором катализатор изомеризации, используемый на стадии (б), содержит никель, платину или палладий.6. Способ по п.5, в котором на стадии (а) используют катализатор, содержащий носитель из диоксида кремния-оксида алюминия, а на стадии (б) используют катализатор �1. A method of obtaining a base oil having a kinematic viscosity at 100 ° C above 6 cSt from wax obtained using the Fischer-Tropsch process and having a boiling point during recovery of T10 wt.% Above 500 ° C, by performing the following steps: (a1 ) the implementation of the Fischer-Tropsch synthesis to obtain the product of the Fischer-Tropsch synthesis, (a2) isolation by distillation from the specified product of the Fischer-Tropsch synthesis Fischer-Tropsch wax, an intermediate waxy product, more than 80 wt.% which has a boiling point of from 300 to 500 ° C, and carbohydrate . Native solvent having a T90 wt% recovery point below 400 ° C, and (a3) combining a Fischer-Tropsch wax with a solvent to obtain a raw material for step (a); (a) contacting a feed containing Fischer-Tropsch wax and from 5 to 40 wt.% a hydrocarbon solvent having a recovery temperature T90 wt.% below 400 ° C. with a hydroisomerization catalyst under hydroisomerization conditions, (b) dewaxing the isomerized product from step ( a) and the selection of base oil from dewaxed oil. 2. The method according to claim 1, wherein the Fischer-Tropsch wax content in the feed for step (a) is greater than 70% by weight. The method according to claim 1, wherein the solvent is a product obtained using the Fischer-Tropsch process. The method according to claim 1, in which the recovery temperature T10 wt.% Solvent is from 250 to 370 ° C. The method according to claim 1, wherein the isomerization catalyst used in step (b) comprises nickel, platinum or palladium. The method according to claim 5, in which at the stage (a) a catalyst is used containing a carrier of silica-alumina, and at the stage (b) a catalyst is used

Claims (8)

1. Способ получения базового масла, имеющего кинематическую вязкость при 100°С выше 6 сСт, из воска, полученного с помощью процесса Фишера-Тропша и имеющего температуру кипения при рекуперации Т10 мас.% выше 500°С, путем выполнения следующих стадий: (а1) осуществление синтеза Фишера-Тропша для получения продукта синтеза Фишера-Тропша, (а2) выделение методом дистилляции из указанного продукта синтеза Фишера-Тропша воска Фишера-Тропша, промежуточного восковидного продукта, более чем 80 мас.% которого имеет температуру кипения от 300 до 500°С, и углеводородного растворителя, имеющего температуру рекуперации Т90 мас.% ниже 400°С, и (а3) комбинирование воска Фишера-Тропша с растворителем с целью получения сырья для стадии (а); (а) контактирование сырья, содержащего воск Фишера-Тропша и от 5 до 40 мас.% углеводородного растворителя, имеющего температуру рекуперации Т90 мас.% ниже 400°С, с катализатором гидроизомеризации в условиях гидроизомеризации,1. A method of obtaining a base oil having a kinematic viscosity at 100 ° C above 6 cSt from wax obtained using the Fischer-Tropsch process and having a boiling point during recovery of T10 wt.% Above 500 ° C, by performing the following steps: (a1 ) the implementation of the Fischer-Tropsch synthesis to obtain the product of the Fischer-Tropsch synthesis, (a2) isolation by distillation from the specified product of the Fischer-Tropsch synthesis Fischer-Tropsch wax, an intermediate waxy product, more than 80 wt.% which has a boiling point of from 300 to 500 ° C, and carbohydrate . Native solvent having a T90 wt% recovery point below 400 ° C, and (a3) combining a Fischer-Tropsch wax with a solvent to obtain a raw material for step (a); (a) contacting a feed containing Fischer-Tropsch wax and from 5 to 40 wt.% a hydrocarbon solvent having a recovery temperature T90 wt.% below 400 ° C. with a hydroisomerization catalyst under hydroisomerization conditions, (б) депарафинизация изомеризованного продукта со стадии (а) и выделение базового масла из депарафинизированного масла.(b) dewaxing the isomerized product from step (a) and isolating the base oil from the dewaxed oil. 2. Способ по п.1, в котором содержание воска Фишера-Тропша в сырье для стадии (а) составляет выше 70 мас.%.2. The method according to claim 1, in which the content of the Fischer-Tropsch wax in the feed for stage (a) is above 70 wt.%. 3. Способ по п.1, в котором растворителем является продукт, полученный с помощью процесса Фишера-Тропша.3. The method according to claim 1, in which the solvent is a product obtained using the Fischer-Tropsch process. 4. Способ по п.1, в котором температура рекуперации Т10 мас.% растворителя составляет от 250 до 370°С.4. The method according to claim 1, in which the temperature of recovery of T10 wt.% Solvent is from 250 to 370 ° C. 5. Способ по п.1, в котором катализатор изомеризации, используемый на стадии (б), содержит никель, платину или палладий.5. The method according to claim 1, in which the isomerization catalyst used in stage (b), contains Nickel, platinum or palladium. 6. Способ по п.5, в котором на стадии (а) используют катализатор, содержащий носитель из диоксида кремния-оксида алюминия, а на стадии (б) используют катализатор депарафинизации, содержащий платину или палладий и ZSM-48, и в котором стадии (а) и (б) выполняют в последовательном потоке.6. The method according to claim 5, in which at the stage (a) use a catalyst containing a carrier of silicon dioxide-alumina, and at the stage (b) use a dewaxing catalyst containing platinum or palladium and ZSM-48, and in which stage (a) and (b) are performed in a sequential stream. 7. Способ по п.1, в котором базовое масло, полученное способом, имеет кинематическую вязкость при 100°С выше 8 сСт, индекс вязкости выше 140 и Noack летучесть ниже 7 мас.%.7. The method according to claim 1, in which the base oil obtained by the method has a kinematic viscosity at 100 ° C above 8 cSt, a viscosity index above 140 and Noack volatility below 7 wt.%. 8. Способ по любому одному из предшествующих пп.1-7, в котором сырье для стадии (а) готовят путем осуществления процесса синтеза Фишера-Тропша с получением продукта синтеза Фишера-Тропша; выделения методом дистилляции из указанного продукта синтеза Фишера-Тропша воска Фишера-Тропша, промежуточного восковидного продукта, более 80 мас.% которого имеет температуру кипения от 300 до 500°С и растворителя; комбинирования воска Фишера-Тропша с растворителем с целью получения сырья для стадии (а) и хранения промежуточного восковидного продукта отдельно от сырья для стадии (а).8. The method according to any one of the preceding claims 1 to 7, in which the raw materials for stage (a) are prepared by implementing the Fischer-Tropsch synthesis process to obtain a Fischer-Tropsch synthesis product; distillation of the Fischer-Tropsch synthesis wax of the Fischer-Tropsch wax, an intermediate waxy product, more than 80% by weight of which has a boiling point of 300 to 500 ° C. and a solvent, by distillation from said product; combining the Fischer-Tropsch wax with a solvent to obtain raw materials for stage (a) and storing the intermediate waxy product separately from the raw materials for stage (a).
RU2006146997/04A 2004-06-08 2005-06-07 METHOD FOR PRODUCING BASIC OIL RU2006146997A (en)

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EP04291433 2004-06-08
EP04291433.3 2004-06-08

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US (1) US20080045614A1 (en)
EP (1) EP1758969A1 (en)
JP (1) JP2008501838A (en)
CN (1) CN101006163A (en)
RU (1) RU2006146997A (en)
WO (1) WO2005121280A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2621685C2 (en) * 2011-11-01 2017-06-07 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Paraffin wax

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007011462A1 (en) 2005-07-19 2007-01-25 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
GB2455995B (en) * 2007-12-27 2012-09-26 Statoilhydro Asa A method of producing a lube oil from a Fischer-Tropsch wax
JP5981685B2 (en) * 2008-02-08 2016-08-31 Ｊｘエネルギー株式会社 Hydroisomerization catalyst and method for producing the same, method for dewaxing hydrocarbon oil, and method for producing lubricating base oil
DE102010044319A1 (en) * 2010-09-03 2012-03-08 Sasol Wax Gmbh Wax blends comprising long-chain hydrocarbons and alcohols, printing ink compositions and thermal transfer ribbons containing such wax blends and use of wax blends
WO2014020007A1 (en) 2012-08-01 2014-02-06 Shell Internationale Research Maatschappij B.V. Cable fill composition
WO2017034659A1 (en) 2015-08-21 2017-03-02 Exxonmobil Chemical Patents Inc. Lubricant base stock blends
US10059898B2 (en) 2015-08-21 2018-08-28 Exxonmobil Chemical Patents Inc. High-viscosity metallocene polyalpha-olefins with high electrohydrodynamic performance
US10611980B2 (en) 2015-10-15 2020-04-07 Exxonmobil Chemical Patents Inc. Lubricant containing high-viscosity metallocene polyalpha-olefins
CN105647575A (en) * 2016-02-18 2016-06-08 惠生工程（中国）有限公司 Natural gasoline upgrading and utilizing technology
US10144894B2 (en) 2016-07-20 2018-12-04 Exxonmobil Chemical Patents Inc. Shear-stable oil compositions and processes for making the same
WO2018026406A1 (en) 2016-08-02 2018-02-08 Exxonmobil Chemical Patents Inc. Unsaturated polyalpha-olefin materials
US10351488B2 (en) 2016-08-02 2019-07-16 Exxonmobil Chemical Patents Inc. Unsaturated polyalpha-olefin materials
WO2018182984A1 (en) 2017-03-28 2018-10-04 Exxonmobil Chemical Patents Inc. Metallocene compounds
WO2018182982A2 (en) 2017-03-28 2018-10-04 Exxonmobil Chemical Patents Inc. Metallocene-catalyzed polyalpha-olefins
CA3091510A1 (en) 2018-02-19 2019-08-22 Exxonmobil Chemical Patents Inc. Functional fluids comprising low-viscosity, low-volatility polyalpha-olefin base stock
CN109517626A (en) * 2018-12-29 2019-03-26 大连隆星新材料有限公司 A kind of preparation method of high-quality Fischer-Tropsch wax
CN109486524A (en) * 2018-12-29 2019-03-19 大连隆星新材料有限公司 A kind of device producing high-quality Fischer-Tropsch wax
CN109486528A (en) * 2018-12-29 2019-03-19 大连隆星新材料有限公司 A kind of device producing Fischer-Tropsch wax crude product
US11661465B2 (en) 2019-10-28 2023-05-30 Exxonmobil Chemical Patents Inc. Dimer selective metallocene catalysts, non-aromatic hydrocarbon soluble activators, and processes to produce poly alpha-olefin oligmers therewith

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2230760C (en) * 1995-11-14 2004-07-20 Mobil Oil Corporation Integrated lubricant upgrading process
US5766274A (en) * 1997-02-07 1998-06-16 Exxon Research And Engineering Company Synthetic jet fuel and process for its production
ZA989528B (en) * 1997-12-03 2000-04-19 Schuemann Sasol S A Pty Ltd "Production of lubricant base oils".
US6179994B1 (en) * 1998-09-04 2001-01-30 Exxon Research And Engineering Company Isoparaffinic base stocks by dewaxing fischer-tropsch wax hydroisomerate over Pt/H-mordenite
US6332974B1 (en) * 1998-09-11 2001-12-25 Exxon Research And Engineering Co. Wide-cut synthetic isoparaffinic lubricating oils
US7704379B2 (en) * 2002-10-08 2010-04-27 Exxonmobil Research And Engineering Company Dual catalyst system for hydroisomerization of Fischer-Tropsch wax and waxy raffinate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2621685C2 (en) * 2011-11-01 2017-06-07 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Paraffin wax

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CN101006163A (en) 2007-07-25
JP2008501838A (en) 2008-01-24
EP1758969A1 (en) 2007-03-07
WO2005121280A1 (en) 2005-12-22
US20080045614A1 (en) 2008-02-21

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