RU2005114492A - Композиционное изделие - Google Patents
Композиционное изделие Download PDFInfo
- Publication number
- RU2005114492A RU2005114492A RU2005114492/02A RU2005114492A RU2005114492A RU 2005114492 A RU2005114492 A RU 2005114492A RU 2005114492/02 A RU2005114492/02 A RU 2005114492/02A RU 2005114492 A RU2005114492 A RU 2005114492A RU 2005114492 A RU2005114492 A RU 2005114492A
- Authority
- RU
- Russia
- Prior art keywords
- product according
- composite product
- layer
- melamine
- group
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims 7
- 239000002131 composite material Substances 0.000 claims 17
- 229920000642 polymer Polymers 0.000 claims 9
- 239000011230 binding agent Substances 0.000 claims 6
- 239000003063 flame retardant Substances 0.000 claims 5
- 239000011888 foil Substances 0.000 claims 5
- 239000011159 matrix material Substances 0.000 claims 5
- 229910052751 metal Inorganic materials 0.000 claims 5
- 239000002184 metal Substances 0.000 claims 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 4
- 229920000877 Melamine resin Polymers 0.000 claims 4
- 239000004593 Epoxy Substances 0.000 claims 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims 3
- 229920000058 polyacrylate Polymers 0.000 claims 3
- -1 polydienes Polymers 0.000 claims 3
- 229920005594 polymer fiber Polymers 0.000 claims 3
- 229920001187 thermosetting polymer Polymers 0.000 claims 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims 2
- 239000004698 Polyethylene Substances 0.000 claims 2
- 229920001971 elastomer Polymers 0.000 claims 2
- 239000000806 elastomer Substances 0.000 claims 2
- 125000003700 epoxy group Chemical group 0.000 claims 2
- 239000000835 fiber Substances 0.000 claims 2
- 150000007974 melamines Chemical class 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 2
- 229920000647 polyepoxide Polymers 0.000 claims 2
- 229920000573 polyethylene Polymers 0.000 claims 2
- 229920001296 polysiloxane Polymers 0.000 claims 2
- 229920002635 polyurethane Polymers 0.000 claims 2
- 239000004814 polyurethane Substances 0.000 claims 2
- 229920005989 resin Polymers 0.000 claims 2
- 239000011347 resin Substances 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- 229920006305 unsaturated polyester Polymers 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- 238000005303 weighing Methods 0.000 claims 2
- XQMVBICWFFHDNN-UHFFFAOYSA-N 5-amino-4-chloro-2-phenylpyridazin-3-one;(2-ethoxy-3,3-dimethyl-2h-1-benzofuran-5-yl) methanesulfonate Chemical compound O=C1C(Cl)=C(N)C=NN1C1=CC=CC=C1.C1=C(OS(C)(=O)=O)C=C2C(C)(C)C(OCC)OC2=C1 XQMVBICWFFHDNN-UHFFFAOYSA-N 0.000 claims 1
- 239000004604 Blowing Agent Substances 0.000 claims 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims 1
- 239000011324 bead Substances 0.000 claims 1
- 229920001400 block copolymer Polymers 0.000 claims 1
- 239000004202 carbamide Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims 1
- XPSQBNPZMNWIPV-UHFFFAOYSA-N ethenoxyperoxyethene Chemical compound C=COOOC=C XPSQBNPZMNWIPV-UHFFFAOYSA-N 0.000 claims 1
- 230000009970 fire resistant effect Effects 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 229920000554 ionomer Polymers 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 239000012188 paraffin wax Substances 0.000 claims 1
- 229920001568 phenolic resin Polymers 0.000 claims 1
- 239000005011 phenolic resin Substances 0.000 claims 1
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims 1
- 229920002492 poly(sulfone) Polymers 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 229920001470 polyketone Polymers 0.000 claims 1
- 229920005596 polymer binder Polymers 0.000 claims 1
- 239000002491 polymer binding agent Substances 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 229920006324 polyoxymethylene Polymers 0.000 claims 1
- 229920006380 polyphenylene oxide Polymers 0.000 claims 1
- 229920006259 thermoplastic polyimide Polymers 0.000 claims 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H5/00—Armour; Armour plates
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- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31681—Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Braking Arrangements (AREA)
- Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
Claims (17)
1. Композиционное изделие, имеющее модуль упругости при изгибе, по меньшей мере, примерно 80000 ф/дюйм2 (552 МПа), предел прочности при изгибе, равный, по меньшей мере, примерно 800 ф/дюйм2 (5,52 МПа), поверхностную плотность, равную примерно от 0,9 ф/фут2 (4,40 кг/м2) до 1,5 ф/фут2 (5,86 кг/м2), и VO скорость, равную, по меньшей мере, примерно 1430 фут/с (427 м/с) при испытании с использованием пуль 44 Magnum Jacketed Hollow Point (JHP) массой 240 гран (15,6 г) и пуль 9 мм Full Metal Jacketed, Round Nose (FMJ RN) массой 124 гран (8,0 г).
2. Композиционное изделие, состоящее из множества слоев, соединенных вместе, где первый слой выполнен из металлической фольги, второй слой выполнен из огнестойкого связующего и третий слой выполнен из многих слоев, причем каждый из этих слоев содержит сетку из воспламеняющихся полимерных волокон в матрице и эти полимерные волокна имеют прочность, равную, по меньшей мере, примерно 17 г/денье, модуль упругости при растяжении, равный, по меньшей мере, примерно 500 г/денье и энергию разрушения, равную, по меньшей мере, примерно 20 Дж/г.
3. Композиционное изделие по п.2, отличающееся тем, что оно дополнительно содержит четвертый слой, выполненный из огнестойкого связующего, и пятый слой, выполненный из металлической фольги.
4. Композиционное изделие по п.2, отличающееся тем, что оно дополнительно содержит вспучивающуюся полимерную композицию между указанными первым и вторым слоями.
5. Композиционное изделие по п.4, отличающееся тем, что оно дополнительно содержит пятый слой, состоящий из вспучивающейся полимерной композиции, шестой слой, состоящий из огнестойкого связующего, и седьмой слой, выполненный из металлической фольги.
6. Композиционное изделие по п.2 или по п.4, отличающееся тем, что металлическая фольга представляет собой алюминиевую фольгу толщиной от 0,0005 дюймов (12,7 мкм) до 0,005 дюймов (127 мкм).
7. Композиционное изделие по п.2 или 4, отличающееся тем, что указанное огнестойкое связующее представляет собой полимерное связующее, выбранное из группы, состоящей из полиолефинов, полидиенов, сложных полиэфиров, полиамидов, виниловых полимеров, иономеров, акриловых полимеров, полиакрилатов, полисульфонов, полифениленоксида, полиацеталей, силиконов, термопластичных полиуретанов, термопластичных полиимидов, поликетонов, фенольных полимеров, меламиновых смол, эпоксидных смол, ненасыщенных сложных полиэфиров, термореактивных полиуретанов и их сополимеров и галогенсодержащих производных, и по меньшей мере одно соединение из группы антипиренов.
8. Композиционное изделие по п.2 или 4, отличающееся тем, что огнестойкое связующее представляет собой смесь окиси сурьмы (Sb2О3), декабромдифенилового эфира и полихлорированного парафинового воска в полиакрилатном связующем.
9. Композиционное изделие по п.2 или 4, отличающееся тем, что воспламеняющиеся полимерные волокна являются полиэтиленовыми.
10. Композиционное изделие по п.9, отличающееся тем, что полиэтиленовые волокна ориентированы в слое в одном направлении, и волокна в соседних слоях ориентированы под углом друг к другу примерно 90°.
11. Композиционное изделие по п.2 или 4, отличающееся тем, что матрица является эластомером, имеющим первоначальный модуль упругости при растяжении менее примерно 6000 ф/дюйм2 (41,4 МПа).
12. Композиционное изделие по п.11, отличающееся тем, что матрица представляет собой эластомер, являющийся блок-сополимером сопряженного диена и винилароматического мономера.
13. Композиционное изделие по п.2 или 4, отличающееся тем, что матрица представляет собой термореактивную смолу с модулем упругости при растяжении, равным по меньшей мере 300 кф/дюйм2 (2,1 ГПа).
14. Композиционное изделие по п.13, отличающееся тем, что матрица является полимером эпоксивинилового эфира.
15. Композиционное изделие по п.3, отличающееся тем, что вспучивающаяся полимерная композиция представляет собой вспениватель, выбранный из группы, состоящей из меламина, солей меламина, производных меламина, мочевины, дициандиамида и гуанидина, диспергированный в смоле, выбранной из группы, состоящей из фенольных полимеров, меламиновых полимеров, эпоксидных смол, силиконов, ненасыщенных сложных полиэфиров и термореактивных полиуретанов.
16. Композиционное изделие по п.4, отличающееся тем, что вспучивающаяся полимерная композиция состоит, по меньшей мере, из одного вещества, выбранного из группы, состоящей из пирофосфата меламина (C3H6N6·H4P2O7) и бис(меламинпирофосфорной)кислоты (C6H12N12·H4P2O7), и вещества, выбранного из группы, состоящей из формальдегид-фурфураль-резорцин-фенольной смолы и эпоксидной смолы.
17. Композиционное изделие по п.12, отличающееся тем, что вспучивающаяся полимерная композиция дополнительно содержит 2-35 вес.% стеклянных шариков.
Applications Claiming Priority (4)
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US41759602P | 2002-10-10 | 2002-10-10 | |
US60/417,596 | 2002-10-10 | ||
US10/287,929 | 2002-11-05 | ||
US10/287,929 US6890638B2 (en) | 2002-10-10 | 2002-11-05 | Ballistic resistant and fire resistant composite articles |
Publications (1)
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RU2005114492A true RU2005114492A (ru) | 2006-01-20 |
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US (1) | US6890638B2 (ru) |
EP (1) | EP1560709B1 (ru) |
JP (1) | JP4431108B2 (ru) |
CN (1) | CN102514305B (ru) |
AR (1) | AR041591A1 (ru) |
AU (1) | AU2003300349A1 (ru) |
CA (1) | CA2501955C (ru) |
IL (1) | IL167937A (ru) |
MX (1) | MXPA05003833A (ru) |
MY (1) | MY138775A (ru) |
RU (1) | RU2005114492A (ru) |
TW (1) | TW200427578A (ru) |
WO (1) | WO2004033196A2 (ru) |
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2002
- 2002-11-05 US US10/287,929 patent/US6890638B2/en not_active Expired - Lifetime
-
2003
- 2003-10-09 WO PCT/US2003/031964 patent/WO2004033196A2/en active Application Filing
- 2003-10-09 AU AU2003300349A patent/AU2003300349A1/en not_active Abandoned
- 2003-10-09 CN CN201110334814.5A patent/CN102514305B/zh not_active Expired - Fee Related
- 2003-10-09 EP EP03808186.5A patent/EP1560709B1/en not_active Expired - Lifetime
- 2003-10-09 MX MXPA05003833A patent/MXPA05003833A/es unknown
- 2003-10-09 CA CA 2501955 patent/CA2501955C/en not_active Expired - Fee Related
- 2003-10-09 RU RU2005114492/02A patent/RU2005114492A/ru not_active Application Discontinuation
- 2003-10-09 JP JP2005501135A patent/JP4431108B2/ja not_active Expired - Fee Related
- 2003-10-10 MY MYPI20033882A patent/MY138775A/en unknown
- 2003-10-10 AR ARP030103713 patent/AR041591A1/es unknown
- 2003-10-13 TW TW92128297A patent/TW200427578A/zh unknown
-
2005
- 2005-04-10 IL IL167937A patent/IL167937A/en active IP Right Grant
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JP4431108B2 (ja) | 2010-03-10 |
JP2006503258A (ja) | 2006-01-26 |
IL167937A (en) | 2011-08-31 |
AR041591A1 (es) | 2005-05-26 |
MY138775A (en) | 2009-07-31 |
AU2003300349A8 (en) | 2004-05-04 |
CN102514305A (zh) | 2012-06-27 |
MXPA05003833A (es) | 2005-06-22 |
US20040086729A1 (en) | 2004-05-06 |
WO2004033196A3 (en) | 2004-06-17 |
US6890638B2 (en) | 2005-05-10 |
AU2003300349A1 (en) | 2004-05-04 |
CA2501955A1 (en) | 2004-04-22 |
WO2004033196A2 (en) | 2004-04-22 |
CN102514305B (zh) | 2016-03-16 |
EP1560709A2 (en) | 2005-08-10 |
CA2501955C (en) | 2014-03-18 |
EP1560709B1 (en) | 2019-02-27 |
TW200427578A (en) | 2004-12-16 |
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