RU2004131492A - Фотоуправляемые фотохромные электролюминесцирующие и электропроводящие полимеры для фотоники - Google Patents
Фотоуправляемые фотохромные электролюминесцирующие и электропроводящие полимеры для фотоники Download PDFInfo
- Publication number
- RU2004131492A RU2004131492A RU2004131492/04A RU2004131492A RU2004131492A RU 2004131492 A RU2004131492 A RU 2004131492A RU 2004131492/04 A RU2004131492/04 A RU 2004131492/04A RU 2004131492 A RU2004131492 A RU 2004131492A RU 2004131492 A RU2004131492 A RU 2004131492A
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- RU
- Russia
- Prior art keywords
- photochromic
- polyazomethines
- monomers
- producing
- photonics
- Prior art date
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- 239000002322 conducting polymer Substances 0.000 title 1
- 229920001940 conductive polymer Polymers 0.000 title 1
- 239000000178 monomer Substances 0.000 claims 6
- 229920000343 polyazomethine Polymers 0.000 claims 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 3
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 claims 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 2
- 150000004984 aromatic diamines Chemical class 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims 2
- 238000006068 polycondensation reaction Methods 0.000 claims 2
- 230000010933 acylation Effects 0.000 claims 1
- 238000005917 acylation reaction Methods 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 150000001720 carbohydrates Chemical class 0.000 claims 1
- 230000000747 cardiac effect Effects 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- HKYGSMOFSFOEIP-UHFFFAOYSA-N dichloro(dichloromethoxy)methane Chemical compound ClC(Cl)OC(Cl)Cl HKYGSMOFSFOEIP-UHFFFAOYSA-N 0.000 claims 1
- 125000005594 diketone group Chemical group 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 230000003287 optical effect Effects 0.000 claims 1
- YVOFTMXWTWHRBH-UHFFFAOYSA-N pentanedioyl dichloride Chemical compound ClC(=O)CCCC(Cl)=O YVOFTMXWTWHRBH-UHFFFAOYSA-N 0.000 claims 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 1
- 230000005855 radiation Effects 0.000 claims 1
- 238000007363 ring formation reaction Methods 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/14—Macromolecular compounds
- C09K2211/1408—Carbocyclic compounds
- C09K2211/1425—Non-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/14—Macromolecular compounds
- C09K2211/1441—Heterocyclic
- C09K2211/1458—Heterocyclic containing sulfur as the only heteroatom
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Claims (8)
1. Фотохромные мономеры общей формулы
2. Способ получения фотохромных мономеров по п.1, включающий ацилирование бензотиофена дихлорангидридом глутаровой кислоты в хлористом метилене в присутствии хлористого алюминия и последующую восстановительную циклизацию полученных дикетонов под действием TiCL4, Zn в ТГФ в присутствии пиридина с дальнейшим формилированием продуктов реакции дихлорметиловым эфиром в нитробензоле в присутствии хлористого алюминия.
3. Фотохромные полиазометины на основе фотохромных мономеров по п.1, имеющие молекулярную массу от 25000 до 50000 и общую структурную формулу:
где Alk = CH3 - C10H21
y = -C=N- ; -N=C-
где n= 50-100.
4. Способ получения фотохромных полиазометинов по п.3, включающий поликонденсацию в растворе фотохромного мономера по п.1 с ароматическими диаминами или диальдегидами при температуре примерно от 20 до 200°С.
5. Фотохромные кардовые полиазометины на основе фотохромных мономеров по п.1, имеющие молекулярную массу от 30000 до 50000 и общую структурную формулу
где Alk = CH3 - C10H21
y = -C=N- ; -N=C-
где n=50-100.
6. Способ получения кардовых фотохромных полиазометинов по п.5, включающий поликонденсацию в растворе фотохромных мономеров по п.1 с кардовыми ароматическими диаминами или альдегидами при температуре примерно 20-200°С.
7. Применение фотохромных полиазометинов по п.3 в устройствах фотоники.
8. Применение фотохромных кардовых полиазометинов по п.5 в устройствах фотоники, особенно в фотоуправляемых дисплеях, а также трехмерной оперативной оптической памяти, линейных и нелинейно-оптических фотопереключателях излучения.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2004131492/04A RU2345998C2 (ru) | 2004-10-28 | 2004-10-28 | Фотоуправляемые фотохромные электролюминесцирующие и электропроводящие полимеры для фотоники |
| KR1020050073123A KR101222146B1 (ko) | 2004-10-28 | 2005-08-10 | 광제어 광색성 전계발광 및 광기술용 도전성 폴리머 |
| US11/259,281 US7297751B2 (en) | 2004-10-28 | 2005-10-27 | Photocontrolled photochromic electroluminescent and electroconductive polymers for photonics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2004131492/04A RU2345998C2 (ru) | 2004-10-28 | 2004-10-28 | Фотоуправляемые фотохромные электролюминесцирующие и электропроводящие полимеры для фотоники |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2004131492A true RU2004131492A (ru) | 2006-04-10 |
| RU2345998C2 RU2345998C2 (ru) | 2009-02-10 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2004131492/04A RU2345998C2 (ru) | 2004-10-28 | 2004-10-28 | Фотоуправляемые фотохромные электролюминесцирующие и электропроводящие полимеры для фотоники |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US7297751B2 (ru) |
| KR (1) | KR101222146B1 (ru) |
| RU (1) | RU2345998C2 (ru) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1888553A4 (en) * | 2005-05-25 | 2010-03-10 | Switch Materials Inc | ELECTROCHROMIC AND PHOTOCHROMIC COMPOUNDS AND SYNTHESIS AND USE THEREOF |
| US8394917B2 (en) * | 2009-07-02 | 2013-03-12 | University Of Florida Research Foundation, Inc. | Soluble alternating donor-acceptor conjugated polymer electrochromes |
| US10451195B2 (en) | 2016-10-25 | 2019-10-22 | International Business Machines Corporation | Hose with tunable flexibility using cyclizable, photochromic molecules |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030025622A (ko) | 2001-09-21 | 2003-03-29 | 한국화학연구원 | 비닐기 함유 디아릴에텐 단량체 및 이를 이용하여 제조한광활성 고분자 |
| RU2345997C2 (ru) * | 2004-09-24 | 2009-02-10 | Самсунг Электроникс Ко., Лтд. | Фотохромные полимеры для трехмерной оперативной оптической памяти |
-
2004
- 2004-10-28 RU RU2004131492/04A patent/RU2345998C2/ru active
-
2005
- 2005-08-10 KR KR1020050073123A patent/KR101222146B1/ko active IP Right Grant
- 2005-10-27 US US11/259,281 patent/US7297751B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR101222146B1 (ko) | 2013-01-14 |
| KR20060050357A (ko) | 2006-05-19 |
| RU2345998C2 (ru) | 2009-02-10 |
| US7297751B2 (en) | 2007-11-20 |
| US20060091364A1 (en) | 2006-05-04 |
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