RU2002129804A - OXIDATIVE COMPOSITION FOR PROCESSING KERATIN FIBERS CONTAINING A SPECIFIC AMINOSILICONE - Google Patents

OXIDATIVE COMPOSITION FOR PROCESSING KERATIN FIBERS CONTAINING A SPECIFIC AMINOSILICONE

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RU2002129804A
RU2002129804A RU2002129804/15A RU2002129804A RU2002129804A RU 2002129804 A RU2002129804 A RU 2002129804A RU 2002129804/15 A RU2002129804/15 A RU 2002129804/15A RU 2002129804 A RU2002129804 A RU 2002129804A RU 2002129804 A RU2002129804 A RU 2002129804A
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composition
composition according
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formula
hair
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RU2002129804/15A
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RU2229281C1 (en
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Фредерик ЛЕГРАН
Жан-Мари МИЛЛЕКАН
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Л'Ореаль
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1. Косметическая композиция, предназначенная для обработки кератиновых волокон человека, более конкретно, волос, отличающаяся тем, что она содержит в косметически приемлемой среде:1. Cosmetic composition intended for the treatment of keratin fibers of a person, more specifically, hair, characterized in that it contains in a cosmetically acceptable medium: (i) по меньшей мере один окислитель и(i) at least one oxidizing agent; and (ii) по меньшей мере один аминосиликон следующих формул (I) или (II):(ii) at least one aminosilicon of the following formulas (I) or (II):
Figure 00000001
Figure 00000001
 в которой m и n обозначают такие числа, что сумма (m+n) составляет, от 1 до 1000, преимущественно от 50 до 250, более конкретно, от 100 до 200, при этом n обозначает число от 0 до 999, в частности от 49 до 249, более конкретно от 125 до 175, а m обозначает число от 1 до 1000, в частности от 1 до 10, более конкретно от 1 до 5;in which m and n denote such numbers that the sum (m + n) is from 1 to 1000, preferably from 50 to 250, more specifically, from 100 to 200, while n denotes a number from 0 to 999, in particular from 49 to 249, more specifically from 125 to 175, and m denotes a number from 1 to 1000, in particular from 1 to 10, more specifically from 1 to 5; R1, R2, R3, одинаковые или разные, обозначают гидрокси или алкокси-радикал с 1-4 атомами С, при этом по меньшей мере один из радикалов R1-R3 обозначает алкокси-радикал;R 1 , R 2 , R 3 , identical or different, denote a hydroxy or alkoxy radical with 1 to 4 C atoms, wherein at least one of the radicals R 1 -R 3 is an alkoxy radical;
Figure 00000002
Figure 00000002
 в которой p и q обозначают такие числа, что сумма (p+q) составляет от 1 до 1000, в частности от 50 до 350, более конкретно от 150 до 250, при этом p обозначает число от 0 до 999, в частности от 49 до 349, более конкретно от 159 до 239, а q обозначает число от 1 до 1000, в частности от 1 до 10, более конкретно от 1 до 5;in which p and q denote such numbers that the sum (p + q) is from 1 to 1000, in particular from 50 to 350, more specifically from 150 to 250, with p denoting a number from 0 to 999, in particular from 49 to 349, more specifically from 159 to 239, and q denotes a number from 1 to 1000, in particular from 1 to 10, more specifically from 1 to 5; R1, R2, являются разными и обозначают гидрокси- или алкокси-радикал с 1-4 атомами С, при этом по меньшей мере один из радикалов R1-R2 обозначает алкокси-радикал.R 1 , R 2 are different and represent a hydroxy or alkoxy radical with 1 to 4 C atoms, with at least one of the radicals R 1 -R 2 being an alkoxy radical. 2. Композиция по п.1, отличающаяся тем, что алкокси-радикал с 1-4 атомами С обозначает метокси-радикал.2. The composition according to claim 1, characterized in that the alkoxy radical with 1-4 atoms C represents a methoxy radical. 3. Композиция по одному из предыдущих пунктов, отличающаяся тем, что для аминосиликонов формулы (I) молярное соотношение гидрокси/алкокси составляет от 0,2:1 до 0,4:1, преимущественно от 0,25:1 до 0,35:1, более предпочтительно равно 0,3.3. The composition according to one of the preceding paragraphs, characterized in that for the amino silicones of formula (I) the molar ratio of hydroxy / alkoxy is from 0.2: 1 to 0.4: 1, mainly from 0.25: 1 to 0.35: 1, more preferably equal to 0.3. 4. Композиция по одному из пп.1 и 2, отличающаяся тем, что для аминосиликонов формулы (II) молярное соотношение гидрокси/алкокси предпочтительно составляет от 1:0,8 до 1:1,1, преимущественно от 1:0,9 до 1:1, более предпочтительно 1:0,95.4. The composition according to one of claims 1 and 2, characterized in that for the amino silicones of formula (II) the molar ratio of hydroxy / alkoxy is preferably from 1: 0.8 to 1: 1.1, mainly from 1: 0.9 to 1: 1, more preferably 1: 0.95. 5. Композиция по одному из пп.1-3, отличающаяся тем, что аминосиликон формулы (I) имеет средневесовую молекулярную массу от 2000 до 1000000, предпочтительно от 3500 до 200000.5. The composition according to one of claims 1 to 3, characterized in that the amino silicone of formula (I) has a weight average molecular weight of from 2000 to 1,000,000, preferably from 3,500 to 200,000. 6. Композиция по одному из предыдущих пп.1, 2 и 4, отличающаяся тем, что аминосиликон формулы (II) имеет средневесовую молекулярную массу от 2000 до 200000, предпочтительно от 5000 до 100000, более предпочтительно от 10000 до 50000.6. The composition according to one of the preceding claims 1, 2 and 4, characterized in that the amino silicone of formula (II) has a weight average molecular weight of from 2000 to 200000, preferably from 5000 to 100000, more preferably from 10000 to 50,000. 7. Композиция по одному из предыдущих пунктов, отличающаяся тем, что аминосиликон формулы (I) или (II) имеет форму эмульсии масло-в-воде, содержащей поверхностно-активные вещества.7. The composition according to one of the preceding paragraphs, characterized in that the amino silicone of formula (I) or (II) is in the form of an oil-in-water emulsion containing surfactants. 8. Композиция по п.7, отличающаяся тем, что эмульсия содержит по меньшей мере одно катионное и/или неионное поверхностно-активное вещество.8. The composition according to claim 7, characterized in that the emulsion contains at least one cationic and / or nonionic surfactant. 9. Композиция по одному из п.7 или 8, отличающаяся тем, что частицы силикона в эмульсии имеют размер от 3 до 500 нм, предпочтительно то 5 до 60 нм, более предпочтительно от 10 до 50 нм.9. The composition according to one of claim 7 or 8, characterized in that the silicone particles in the emulsion have a size of from 3 to 500 nm, preferably 5 to 60 nm, more preferably from 10 to 50 nm. 10. Композиция по одному из предыдущих пунктов, отличающаяся тем, что аминосиликон формулы (I) или (II) выбирают таким образом, что угол соприкосновения с водой волоса, обработанного композицией, содержащей 2% АВ (активных веществ) указанного силикона, составляет от 90 до 180° включительно.10. The composition according to one of the preceding paragraphs, characterized in that the amino silicone of formula (I) or (II) is selected so that the contact angle with water of the hair treated with a composition containing 2% AB (active substances) of said silicone is from 90 up to 180 ° inclusive. 11. Композиция по п.10, отличающаяся тем, что аминосиликон формулы (I) или (II) выбирают таким образом, что угол соприкосновения с водой волоса, обрабатываемого композицией, содержащей 2% АВ (активных веществ) указанного силикона согласно изобретению, составляет от 90 до 130° включительно.11. The composition of claim 10, wherein the aminosilicon of formula (I) or (II) is selected so that the contact angle with water of the hair treated with a composition containing 2% AB (active substances) of said silicone according to the invention is from 90 to 130 ° inclusive. 12. Композиция по одному из пп.1-9, отличающаяся тем, что композицию, содержащую по меньшей мере один аминосиликон формулы (I) или (II), выбирают таким образом, что угол соприкосновения волоса, обработанного указанной композицией, составляет от 90 до 180° включительно.12. The composition according to one of claims 1 to 9, characterized in that the composition containing at least one aminosilicone of the formula (I) or (II) is selected so that the contact angle of the hair treated with the specified composition is from 90 to 180 ° inclusive. 13. Композиция по одному из предыдущих пунктов, отличающаяся тем, что аминосиликон формулы (I) или (II) присутствует в композиции для окрашивания в количестве от 0,01 до 20 мас.% от общей массы композиции.13. The composition according to one of the preceding paragraphs, characterized in that the aminosilicon of the formula (I) or (II) is present in the composition for staining in an amount of from 0.01 to 20 wt.% Of the total weight of the composition. 14. Композиция по п.13, отличающаяся тем, что он присутствует в количестве от 0,1 до 15 мас.% от общей массы композиции.14. The composition according to p. 13, characterized in that it is present in an amount of from 0.1 to 15 wt.% Of the total weight of the composition. 15. Композиция по п.14, отличающаяся тем, что он присутствует в количестве от 0,5 до 10 мас.% от общей массы композиции.15. The composition according to p. 14, characterized in that it is present in an amount of from 0.5 to 10 wt.% From the total weight of the composition. 16. Композиция по одному из предыдущих пунктов, отличающаяся тем, что окислитель выбирают из группы, образованной перекисью водорода, пероксидом мочевины, перборатами, персульфатами или их смесями.16. The composition according to one of the preceding paragraphs, characterized in that the oxidizing agent is selected from the group formed by hydrogen peroxide, urea peroxide, perborates, persulfates or mixtures thereof. 17. Композиция по п.16, отличающаяся тем, что окислителем является перекись водорода.17. The composition according to clause 16, wherein the oxidizing agent is hydrogen peroxide. 18. Композиция по п.17, отличающаяся тем, что концентрация перекиси водорода составляет от 0,5 до 40 объемов, предпочтительно от 2 до 30 объемов.18. The composition according to 17, characterized in that the concentration of hydrogen peroxide is from 0.5 to 40 volumes, preferably from 2 to 30 volumes. 19. Композиция по п.18, отличающаяся тем, что окислителем является раствор перекиси водорода.19. The composition according to p. 18, characterized in that the oxidizing agent is a solution of hydrogen peroxide. 20. Композиция по п.19, отличающаяся тем, что раствор перекиси водорода содержит стабилизатор.20. The composition according to claim 19, characterized in that the hydrogen peroxide solution contains a stabilizer. 21. Композиция по п.20, отличающаяся тем, что стабилизатор выбирают из группы, образованной пирофосфатами щелочных или щелочноземельных металлов, станнатами щелочных или щелочноземельных металлов, фенацетином или солями кислот и оксина.21. The composition according to claim 20, characterized in that the stabilizer is selected from the group formed by pyrophosphates of alkali or alkaline earth metals, stannates of alkali or alkaline earth metals, phenacetin or salts of acids and oxine. 22. Композиция по п.20, отличающаяся тем, что стабилизатором является станнат или станнат в сочетании с пирофосфатом.22. The composition according to claim 20, characterized in that the stabilizer is a stannate or stannate in combination with pyrophosphate. 23. Композиция по одному из пп.20-22, отличающаяся тем, что концентрация стабилизатора составляет от 0,0001 до 5 мас.%, предпочтительно от 0,01 до 2 мас.% по отношению к общей массе композиции.23. The composition according to one of paragraphs.20-22, characterized in that the concentration of the stabilizer is from 0.0001 to 5 wt.%, Preferably from 0.01 to 2 wt.% With respect to the total weight of the composition. 24. Композиция по одному из пп.20-23, отличающаяся тем, что соотношение концентраций перекиси водорода и стабилизаторов составляет от 0,05 до 1000, предпочтительно от 0,1 до 500, более предпочтительно от 1 до 200.24. The composition according to one of paragraphs.20-23, characterized in that the ratio of the concentrations of hydrogen peroxide and stabilizers is from 0.05 to 1000, preferably from 0.1 to 500, more preferably from 1 to 200. 25. Композиция по одному из пп.20-24, отличающаяся тем, что соотношение концентраций одного или нескольких аминосиликонов, определенных в пп.1-12, и стабилизаторов составляет от 0,05 до 1000, предпочтительно от 0,1 до 500, более предпочтительно от 1 до 200.25. The composition according to one of paragraphs.20-24, characterized in that the ratio of the concentrations of one or more amino silicones defined in claims 1-12, and stabilizers is from 0.05 to 1000, preferably from 0.1 to 500, more preferably from 1 to 200. 26. Композиция по одному из предыдущих пунктов, отличающаяся тем, что соотношение концентраций одного или нескольких аминосиликонов, определенных в пп.1-12, и окислителей составляет от 0,001 до 10, предпочтительно от 0,1 до 5, более предпочтительно от 0,02 до 1.26. The composition according to one of the preceding paragraphs, characterized in that the concentration ratio of one or more amino silicones defined in claims 1-12, and oxidizing agents is from 0.001 to 10, preferably from 0.1 to 5, more preferably from 0.02 to 1. 27. Композиция по одному из предыдущих пунктов, отличающаяся тем, что концентрация окислителя составляет от 0,1 до 25 мас.% по отношению к общей массе композиции.27. The composition according to one of the preceding paragraphs, characterized in that the concentration of the oxidizing agent is from 0.1 to 25 wt.% In relation to the total weight of the composition. 28. Композиция по одному из предыдущих пунктов, отличающаяся тем, что она является водной и что рН всей композиции в целом составляет от 1 до 13, предпочтительно от 2 до 12.28. The composition according to one of the preceding paragraphs, characterized in that it is aqueous and that the pH of the whole composition is from 1 to 13, preferably from 2 to 12. 29. Способ окислительного окрашивания кератиновых волокон человека и, более конкретно, волос с использованием красящей композиции, содержащей в косметически приемлемой среде по меньшей мере один окислительный краситель и одну окислительную композицию, такую как определена в одном из пп.1-28.29. A method for the oxidative dyeing of human keratin fibers and, more specifically, hair using a dye composition containing in a cosmetically acceptable medium at least one oxidative dye and one oxidative composition, such as defined in one of claims 1 to 28. 30. Способ окрашивания по п.29, согласно которому смешивают в момент применения красящую композицию с окислительной композицией, полученную смесь затем наносят на кератиновые волокна и оставляют на время примерно от 3 до 50 мин, предпочтительно примерно от 5 до 30 мин, после чего волокна ополаскивают, моют шампунем, снова ополаскивают и сушат.30. The dyeing method according to clause 29, according to which the dye composition is mixed with the oxidizing composition at the time of application, the resulting mixture is then applied to keratin fibers and left for a period of about 3 to 50 minutes, preferably about 5 to 30 minutes, after which rinse, wash with shampoo, rinse and dry again. 31. Способ окрашивания по п.30, согласно которому последовательно наносят красящую композицию и окислительную композицию с промежуточным ополаскиванием или без промежуточного ополаскивания.31. The staining method of claim 30, wherein the dye composition and the oxidizing composition are sequentially applied with or without intermediate rinsing. 32. Способ обработки кератиновых волокон человка, более конкретно волос, для получения постоянной деформации последних, в частности, в виде перманентной завивки волос, при этом указанный способ состоит из следующих стадий: (i) на кератиновый материал, подлежащий обработке, наносят восстанавливающую композицию, при этом кератиновое волокно подвергается механическому натяжению до, во время или после указанного нанесения, (ii) возможно ополаскивают кератиновое волокно, (iii) наносят на кератиновое волокно после возможного ополаскивания окислительную композицию такую, как определена в одном из пп.1-28, (iv) возможно снова ополаскивают кератиновое волокно.32. A method for treating human keratin fibers, more specifically hair, to obtain permanent deformation of the latter, in particular in the form of permanent hair curling, wherein the method consists of the following steps: (i) a restorative composition is applied to the keratin material to be processed, the keratin fiber is subjected to mechanical tension before, during or after the indicated application, (ii) it is possible to rinse the keratin fiber, (iii) it is applied to the keratin fiber after a possible rinse An integral composition as defined in one of claims 1 to 28, (iv) it is possible to rinse the keratin fiber again. 33. Способ обесцвечивания кератиновых волокон человека, более конкретно волос, состоящий из следующих стадий: i) на кератиновое волокно наносят окислительную композицию по одному из пп.1-28, ii) ополаскивают обработанное таким образом кератиновое волокно.33. A method for bleaching human keratin fibers, more specifically hair, consisting of the following steps: i) an oxidizing composition is applied to a keratin fiber according to one of claims 1 to 28, ii) the keratin fiber thus treated is rinsed. 34. Применение по меньшей мере одного аминосиликона формул (I) или (II) такого, как определен в одном из пп.1-12, в косметической композиции, содержащей по меньшей мере один окислитель, для улучшения косметического состояния кератиновых волокон человека.34. The use of at least one aminosilicon of the formulas (I) or (II) as defined in one of claims 1-12, in a cosmetic composition containing at least one oxidizing agent to improve the cosmetic state of human keratin fibers.
RU2002129804/15A 2001-11-08 2002-11-06 Oxidizing composition containing certain aminosilicone for treating keratin fibers RU2229281C1 (en)

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FR0114474 2001-11-08
FR0114474A FR2831818B1 (en) 2001-11-08 2001-11-08 OXIDIZING COMPOSITION FOR THE TREATMENT OF KERATINIC FIBERS COMPRISING A PARTICULAR AMINO SILICONE

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