RU2001119059A - METHOD FOR USING ELECTROCHEMICAL NOISE IN CORROSION - Google Patents

METHOD FOR USING ELECTROCHEMICAL NOISE IN CORROSION

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Publication number
RU2001119059A
RU2001119059A RU2001119059/28A RU2001119059A RU2001119059A RU 2001119059 A RU2001119059 A RU 2001119059A RU 2001119059/28 A RU2001119059/28 A RU 2001119059/28A RU 2001119059 A RU2001119059 A RU 2001119059A RU 2001119059 A RU2001119059 A RU 2001119059A
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RU
Russia
Prior art keywords
electrode
working electrode
potential
electrochemical noise
period
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RU2001119059/28A
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Russian (ru)
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RU2222001C2 (en
Inventor
Владимир Йованчичевич
Original Assignee
Бэйкер Хьюз Инкорпорейтед
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Publication of RU2001119059A publication Critical patent/RU2001119059A/en
Application granted granted Critical
Publication of RU2222001C2 publication Critical patent/RU2222001C2/en

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Claims (9)

1. Способ, предусматривающий использование электрохимического шума для определения скорости коррозии электропроводного изделия, заключающийся в том, что размещают рабочий электрод, электрод сравнения и противоэлектрод в интересующей коррозионной окружающей среде, причем упомянутый рабочий электрод имеет, по существу, тот же состав, что и изделие, измеряют потенциал в разомкнутой цепи между рабочим электродом и электродом сравнения в течение первого периода времени, осуществляют потенциостатическое управление рабочим электродом, и измеряют ток между рабочим электродом и противоэлектродом в течение второго периода времени.1. The method involving the use of electrochemical noise to determine the corrosion rate of an electrically conductive product, which consists in placing a working electrode, a reference electrode and a counter electrode in a corrosive environment of interest, said working electrode having substantially the same composition as the product , measure the potential in an open circuit between the working electrode and the reference electrode for the first time period, perform potentiostatic control of the working electrode, and from measure the current between the working electrode and the counter electrode for a second period of time. 2. Способ, предусматривающий использование электрохимического шума для определения скорости коррозии по п.1, при котором упомянутый первый период времени и упомянутый второй период времени, по существу, эквивалентны.2. A method involving the use of electrochemical noise to determine the corrosion rate according to claim 1, wherein said first time period and said second time period are essentially equivalent. 3. Способ, предусматривающий использование электрохимического шума для определения скорости коррозии по п.1, при котором рабочий электрод при осуществлении потенциостатического управления поддерживают при, по существу, установившемся потенциале, по существу, эквивалентном измеренному потенциалу.3. A method involving the use of electrochemical noise to determine the corrosion rate according to claim 1, wherein the working electrode, when performing potentiostatic control, is maintained at a substantially steady state potential substantially equivalent to the measured potential. 4. Способ, предусматривающий использование электрохимического шума для определения скорости коррозии по п.3, при котором установившийся потенциал, по существу, эквивалентен измеренному потенциалу в конце первого периода времени.4. A method involving the use of electrochemical noise to determine the corrosion rate according to claim 3, in which the steady state potential is essentially equivalent to the measured potential at the end of the first time period. 5. Способ, предусматривающий использование электрохимического шума для определения скорости коррозии по п.1, при котором упомянутый противоэлектрод и упомянутый электрод сравнения состоят из материала, который, по существу, инертен в упомянутой коррозионной окружающей среде.5. A method involving the use of electrochemical noise to determine the corrosion rate according to claim 1, wherein said counter electrode and said reference electrode consist of a material that is substantially inert in said corrosive environment. 6. Способ, предусматривающий использование электрохимического шума по п.1, заключающийся в том, что осуществляют повторение измерения потенциала в разомкнутой цели между рабочим электродом и электродом сравнения в течение первого периода времени, потенциального управления рабочим электродом и повторяют измерение тока между рабочим электродом и противоэлектродом в течение второго периода времени.6. The method involving the use of electrochemical noise according to claim 1, which consists in repeating the measurement of the potential in an open target between the working electrode and the reference electrode for a first period of time, potential control of the working electrode, and repeating the current measurement between the working electrode and the counter electrode during the second period of time. 7. Система для измерения коррозии, предусматривающая использование электрохимического шума, по существу, состоящая из рабочего электрода, который состоит из интересующего материала, противоэлектрода, который инертен в интересующей окружающей среде, электрода сравнения, который инертен в интересующей окружающей среде, и измерительной системы, соединенной с упомянутым рабочим электродом, противоэлектродом и упомянутым электродом сравнения, причем упомянутая измерительная система выполнена с возможностью контроля потенциала между упомянутым рабочим электродом и упомянутым электродом для сравнения и контроля тока в разомкнутой цепи между упомянутым противоэлектродом и упомянутым рабочим электродом.7. A system for measuring corrosion, involving the use of electrochemical noise, essentially consisting of a working electrode, which consists of a material of interest, a counter electrode that is inert in the environment of interest, a reference electrode that is inert in the environment of interest, and a measurement system connected with said working electrode, a counter electrode and said reference electrode, said measuring system being configured to control the potential between a crushed working electrode and said electrode for comparing and monitoring an open circuit current between said counter electrode and said working electrode. 8. Система для измерения коррозии, предусматривающая использование электрохимического шума по п.7, в которой упомянутый противоэлектрод и упомянутый электрод сравнения состоят из материала, который инертен в упомянутой коррозионной окружающей среде.8. A system for measuring corrosion, comprising the use of electrochemical noise according to claim 7, in which said counter electrode and said reference electrode consist of a material that is inert in said corrosive environment. 9. Система для измерения коррозии, предусматривающая использование электрохимического шума по п.7, дополнительно содержащая блок обработки, который выполнен с возможностью автоматического измерения потенциала в разомкнутой цепи между рабочим электродом и электродом сравнения в течение первого периода времени, осуществления потенциостатического управления рабочим электродом, и измерения тока между рабочим электродом и противоэлектродом в течение второго периода времени.9. The system for measuring corrosion, comprising the use of electrochemical noise according to claim 7, further comprising a processing unit that is configured to automatically measure the potential in an open circuit between the working electrode and the reference electrode for a first period of time, performing potentiostatic control of the working electrode, and measuring current between the working electrode and the counter electrode for a second period of time.
RU2001119059/28A 1998-12-10 1999-12-09 Procedure foreseeing utilization of electrochemical noise under corrosion RU2222001C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11173598P 1998-12-10 1998-12-10
US60/111,735 1998-12-10

Publications (2)

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RU2001119059A true RU2001119059A (en) 2003-07-10
RU2222001C2 RU2222001C2 (en) 2004-01-20

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US (1) US6280603B1 (en)
EP (1) EP1137926B1 (en)
JP (1) JP2002532681A (en)
CN (1) CN100385231C (en)
AT (1) ATE262169T1 (en)
AU (1) AU758336B2 (en)
BR (1) BR9915977A (en)
CA (1) CA2353946C (en)
DE (1) DE69915679T2 (en)
DK (1) DK1137926T3 (en)
ES (1) ES2220142T3 (en)
ID (1) ID28879A (en)
MX (1) MXPA01005642A (en)
NO (1) NO319344B1 (en)
RU (1) RU2222001C2 (en)
WO (1) WO2000034760A1 (en)

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