RU2001115188A - Silane compounds as additives in electrolytes for galvanic cells - Google Patents

Silane compounds as additives in electrolytes for galvanic cells Download PDF

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Publication number
RU2001115188A
RU2001115188A RU2001115188/09A RU2001115188A RU2001115188A RU 2001115188 A RU2001115188 A RU 2001115188A RU 2001115188/09 A RU2001115188/09 A RU 2001115188/09A RU 2001115188 A RU2001115188 A RU 2001115188A RU 2001115188 A RU2001115188 A RU 2001115188A
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RU
Russia
Prior art keywords
additives
electrolyte
silane compounds
lithium
group
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RU2001115188/09A
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Russian (ru)
Inventor
Михаэль ШМИДТ (DE)
Михаэль Шмидт
Андреас КЮНЕР (DE)
Андреас КЮНЕР
Дагмар ПЕТИГК (DE)
Дагмар ПЕТИГК
Original Assignee
Мерк Патент ГмбХ (DE)
Мерк Патент Гмбх
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Publication of RU2001115188A publication Critical patent/RU2001115188A/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • H01M10/0567Liquid materials characterised by the additives
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/16Cells with non-aqueous electrolyte with organic electrolyte
    • H01M6/162Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
    • H01M6/164Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by the solvent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0025Organic electrolyte
    • H01M2300/0028Organic electrolyte characterised by the solvent
    • H01M2300/0034Fluorinated solvents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Secondary Cells (AREA)
  • Primary Cells (AREA)

Claims (11)

1. Электролит, состоящий из литийсодержащей неорганической электролитной соли или литийсодержащей органической электролитной соли, растворенной в апротонных растворителях, отличающийся тем, что содержит, по крайней мере одно соединение силана в качестве добавки.1. An electrolyte consisting of a lithium-containing inorganic electrolyte salt or a lithium-containing organic electrolyte salt dissolved in aprotic solvents, characterized in that it contains at least one silane compound as an additive. 2. Электролит по п.1, отличающийся тем, что добавки выбирают из группы, состоящей из силановых соединений с тетраэдрической координацией.2. The electrolyte according to claim 1, characterized in that the additives are selected from the group consisting of silane compounds with tetrahedral coordination. 3. Электролит по п.1 или 2, отличающийся тем, что добавки представляют собой соединения силана с формулой3. The electrolyte according to claim 1 or 2, characterized in that the additives are compounds of silane with the formula SiR1R2R3R4 (I),SiR 1 R 2 R 3 R 4 (I), где каждый R1-R4 представляет Н, CyF2y+1-zHz, OCyF2y+1-zHz, OC(O)CyF2y.+1-zHz, OSO2CyF2y+1-zHz, 1≤x≤6, 1≤y≤8, 0≤z≤2y+l, при этом R1-R4 могут быть одинаковыми или различными, и каждый из них представляет собой ароматическое кольцо, выбранное из группы, состоящей из фенила или нафтила, которые могут быть незамещенными, а также монозамещенными или полизамещенными F, CyF2y+1-zHz или OCyF2y+1-zHz, ОС(O)CyF2y+1-zHz, OSO2CyF2y+l-zHz, N(CnF2n+l-zHz)2 илиwhere each R 1 -R 4 represents H, C y F 2y + 1-z H z , OC y F 2y + 1-z H z , OC (O) C y F 2y. + 1-z H z , OSO 2 C y F 2y + 1-z H z , 1≤x≤6, 1≤y≤8, 0≤z≤2y + l, while R 1 -R 4 may be the same or different, and each of them represents aromatic ring selected from the group consisting of phenyl or naphthyl, which may be unsubstituted, as well as monosubstituted or polysubstituted F, C y F 2y + 1-z H z or OC y F 2y + 1-z H z , OS (O ) C y F 2y + 1-z H z , OSO 2 C y F 2y + lz H z , N (C n F 2n + lz H z ) 2 or гетероциклическое ароматическое кольцо, выбранное из группы, состоящей из пиридила, пиразила и пиримидила, каждый из которых может быть монозамещенным или полизамещенным F, CyF2y+1-zHz или OCyF2y+1-zHz, ОС(O)CyF2y+1-zHz, OSO2CyF2y+1-zHz, N(CnF2n+1-zHz)2.heterocyclic aromatic ring selected from the group consisting of pyridyl, pyrazyl and pyrimidyl, each of which can be monosubstituted or polysubstituted F, C y F 2y + 1-z H z or OCyF 2y + 1-z H z , OS (O) C y F 2y + 1-z H z , OSO 2 C y F 2y + 1-z H z , N (C n F 2n + 1-z H z ) 2 . 4. Электролит по любому из пп.1-3, отличающийся тем, что добавки выбирают из группы, состоящей из тетраметоксисилана, этилтриацетоксисилана, дифенилметоксисилана, дифтордифенилсилана и триэтилсилил-фторметансульфоната.4. The electrolyte according to any one of claims 1 to 3, characterized in that the additives are selected from the group consisting of tetramethoxysilane, ethyltriacetoxysilane, diphenylmethoxysilane, difluorodiphenylsilane and triethylsilyl fluoromethanesulfonate. 5. Электролит по любому из пп.1-4, отличающийся тем, что добавки присутствуют в электролите в концентрациях от 0,01 до 10 вес.%.5. The electrolyte according to any one of claims 1 to 4, characterized in that the additives are present in the electrolyte in concentrations from 0.01 to 10 wt.%. 6. Электролит по любому из пп.1-5, отличающийся тем, что добавки присутствуют в электролите в концентрациях от 0,1 до 5 вес.%.6. The electrolyte according to any one of claims 1 to 5, characterized in that the additives are present in the electrolyte in concentrations from 0.1 to 5 wt.%. 7. Электрохимический элемент, состоящий из катода, анода, сепаратора и электролита, отличающийся тем, что содержит электролит по любому из пп.1-6.7. An electrochemical cell consisting of a cathode, anode, separator and electrolyte, characterized in that it contains an electrolyte according to any one of claims 1 to 6. 8. Применение соединений силана в качестве добавок в электрохимических элементах, источниках тока и вторичных литиевых источниках.8. The use of silane compounds as additives in electrochemical cells, current sources and secondary lithium sources. 9. Применение соединений силана, которые описываются формулой9. The use of silane compounds, which are described by the formula SiR1R2R3R4(I)SiR 1 R 2 R 3 R 4 ( I) где R1, R2, R3 и R4 определены выше,where R 1 , R 2 , R 3 and R 4 are as defined above, в качестве добавок в электрохимических элементах, источниках тока и вторичных литиевых источниках.as additives in electrochemical cells, current sources and secondary lithium sources. 10. Применение соединений силана по п.8 или 9 для растворения фторида лития.10. The use of silane compounds of claim 8 or 9 for dissolving lithium fluoride. 11. Применение соединений силана по п.8 или 9 в комбинации с другими солями лития.11. The use of silane compounds according to claim 8 or 9 in combination with other lithium salts.
RU2001115188/09A 2000-06-07 2001-06-06 Silane compounds as additives in electrolytes for galvanic cells RU2001115188A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10027626A DE10027626A1 (en) 2000-06-07 2000-06-07 Electrolyte comprising a lithium containing inorganic or organic conductive salt contains a silane compound as an additive useful in electrochemical cells, batteries and secondary lithium batteries
DE10027626.1 2000-06-07

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US (1) US20020012850A1 (en)
EP (1) EP1162682A1 (en)
JP (1) JP2002033127A (en)
KR (1) KR20010110330A (en)
CN (1) CN1328355A (en)
BR (1) BR0102280A (en)
CA (1) CA2349727A1 (en)
DE (1) DE10027626A1 (en)
RU (1) RU2001115188A (en)
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CA2349727A1 (en) 2001-12-07
KR20010110330A (en) 2001-12-13
EP1162682A1 (en) 2001-12-12
TW510062B (en) 2002-11-11
BR0102280A (en) 2002-02-19
US20020012850A1 (en) 2002-01-31
DE10027626A1 (en) 2001-12-13
CN1328355A (en) 2001-12-26
JP2002033127A (en) 2002-01-31

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