RU2000121898A - METHOD FOR CATALYTIC PRE-REFORMING OF HYDROCARBON RAW MATERIAL CONTAINING HIGHER HYDROCARBONS - Google Patents

METHOD FOR CATALYTIC PRE-REFORMING OF HYDROCARBON RAW MATERIAL CONTAINING HIGHER HYDROCARBONS

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Publication number
RU2000121898A
RU2000121898A RU2000121898/04A RU2000121898A RU2000121898A RU 2000121898 A RU2000121898 A RU 2000121898A RU 2000121898/04 A RU2000121898/04 A RU 2000121898/04A RU 2000121898 A RU2000121898 A RU 2000121898A RU 2000121898 A RU2000121898 A RU 2000121898A
Authority
RU
Russia
Prior art keywords
reforming
noble metal
raw material
higher hydrocarbons
catalyst
Prior art date
Application number
RU2000121898/04A
Other languages
Russian (ru)
Other versions
RU2250873C2 (en
Inventor
Мартин ЭСТБЕРГ
Йенс-Хенрик Бак ХАНСЕН
НИЛЬСЕН Поль Эрик ХЕЙЛЮНД
Ким Аасберг-Петерсен
Original Assignee
Хальдор Топсеэ А/С
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Publication date
Application filed by Хальдор Топсеэ А/С filed Critical Хальдор Топсеэ А/С
Publication of RU2000121898A publication Critical patent/RU2000121898A/en
Application granted granted Critical
Publication of RU2250873C2 publication Critical patent/RU2250873C2/en

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Claims (3)

1. Способ каталитического предварительного реформинга углеводородного сырья, содержащего высшие углеводороды, который предусматривает пропускание указанного углеводородного сырья через зону катализатора (представляющую собой неподвижный слой, содержащий, по меньшей мере, часть, по меньшей мере, одного благородного металла) в присутствии кислорода и водяного пара, отличающийся тем, что указанное углеводородное сырье пропускают через указанную зону катализатора, содержащую указанный благородный металл, поддерживаемый на оксиде магния (MgO) и/или шпинели (MgAl2O4).1. The method of catalytic preliminary reforming of hydrocarbons containing higher hydrocarbons, which comprises passing said hydrocarbons through a catalyst zone (which is a fixed bed containing at least a portion of at least one noble metal) in the presence of oxygen and water vapor characterized in that said hydrocarbon feed is passed through said catalyst zone containing said noble metal supported on magnesium oxide. (MgO) and / or spinel (MgAl 2 O 4). 2. Способ по п. 1, отличающийся тем, что в качестве катализатора, содержащего благородный металл, используют родий. 2. The method according to p. 1, characterized in that rhodium is used as a catalyst containing a noble metal. 3. Способ по п. 1 или 2, отличающийся тем, что указанный катализатор, содержащий благородный металл, используют в качестве верхнего слоя на обычном неподвижном катализаторе предварительного реформинга. 3. The method according to p. 1 or 2, characterized in that said catalyst containing a noble metal is used as the upper layer on a conventional fixed pre-reforming catalyst.
RU2000121898/04A 1999-08-19 2000-08-18 Method of catalytic preliminary reforming of hydrocarbon raw materials containing higher hydrocarbons RU2250873C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA199901137 1999-08-19
DKPA199901137 1999-08-19

Publications (2)

Publication Number Publication Date
RU2000121898A true RU2000121898A (en) 2002-07-10
RU2250873C2 RU2250873C2 (en) 2005-04-27

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2000121898/04A RU2250873C2 (en) 1999-08-19 2000-08-18 Method of catalytic preliminary reforming of hydrocarbon raw materials containing higher hydrocarbons

Country Status (9)

Country Link
US (1) US6335474B1 (en)
EP (1) EP1077198A3 (en)
JP (1) JP2001080907A (en)
CN (1) CN1165597C (en)
AU (1) AU769128B2 (en)
CA (1) CA2316043A1 (en)
NO (1) NO329966B1 (en)
RU (1) RU2250873C2 (en)
ZA (1) ZA200004258B (en)

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JP2004079262A (en) * 2002-08-13 2004-03-11 Mitsubishi Heavy Ind Ltd Hydrogen-supply system and mobile hydrogen production equipment
US6977067B2 (en) 2003-02-12 2005-12-20 Engelhard Corporation Selective removal of olefins from hydrocarbon feed streams
US7427388B2 (en) 2004-03-19 2008-09-23 Air Products And Chemicals, Inc. Process for improving prereforming and reforming of natural gas containing higher hydrocarbons along with methane
TWI398406B (en) * 2005-09-21 2013-06-11 Nippon Oil Corp Automatic starting method of thermal reformer
JP5224651B2 (en) 2006-03-31 2013-07-03 Ｊｘ日鉱日石エネルギー株式会社 Solid oxide fuel cell
JP4933818B2 (en) 2006-04-07 2012-05-16 Ｊｘ日鉱日石エネルギー株式会社 Operation method of solid oxide fuel cell system
US7365102B1 (en) 2007-02-26 2008-04-29 Delphi Technologies, Inc. Process for pre-reforming hydrocarbon fuels
US8323365B2 (en) 2007-05-22 2012-12-04 Praxair Technology, Inc. Dual mode reactor SMR integration
US8808654B2 (en) * 2009-09-29 2014-08-19 Praxair Technology, Inc. Process for sulfur removal from refinery off gas
WO2012147317A1 (en) 2011-04-26 2012-11-01 パナソニック株式会社 Hydrogen generator, fuel cell system, and method of operating same
US9090464B2 (en) 2011-04-26 2015-07-28 Panasonic Intellectual Property Management Co., Ltd. Hydrogen generation apparatus and fuel cell system
CN104190427A (en) * 2014-09-26 2014-12-10 中国科学院上海高等研究院 Multiphase nickel-based catalyst as well as preparation methods and application thereof
BR102021007738A2 (en) 2021-04-22 2022-11-01 Petróleo Brasileiro S.A. - Petrobras METHOD OF MAINTENANCE OF THE ACTIVITY OF PRE-REFORM CATALYST

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JPS5274591A (en) * 1975-12-17 1977-06-22 Nippon Soken Catalysts for reforming hydrocarbon fuels
US4844837A (en) * 1982-09-30 1989-07-04 Engelhard Corporation Catalytic partial oxidation process
JPS63248444A (en) * 1987-04-03 1988-10-14 Tokyo Gas Co Ltd Steam reforming and/or partial oxidation catalyst for hydrocarbon
JPH0733242B2 (en) * 1988-12-15 1995-04-12 川崎重工業株式会社 Fuel reforming method for fuel cell
JP4226684B2 (en) * 1997-04-11 2009-02-18 千代田化工建設株式会社 Method for producing synthesis gas by partial oxidation method
EP0974550B1 (en) * 1997-04-11 2004-08-11 Chiyoda Corporation Catalyst for preparation of synthesis gas and process for preparing carbon monoxide
US6254807B1 (en) 1998-01-12 2001-07-03 Regents Of The University Of Minnesota Control of H2 and CO produced in partial oxidation process
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