UA96563C2 - Process for preparation of catalyst or precatalyst suitable for obtaining alkenyl alkanoates, composition of catalyst or precatalyst for obtaining alkenyl alkanoates and process for obtaining alkenyl alkanoates - Google Patents

Process for preparation of catalyst or precatalyst suitable for obtaining alkenyl alkanoates, composition of catalyst or precatalyst for obtaining alkenyl alkanoates and process for obtaining alkenyl alkanoates

Info

Publication number
UA96563C2
UA96563C2 UAA200606849A UAA200606849A UA96563C2 UA 96563 C2 UA96563 C2 UA 96563C2 UA A200606849 A UAA200606849 A UA A200606849A UA A200606849 A UAA200606849 A UA A200606849A UA 96563 C2 UA96563 C2 UA 96563C2
Authority
UA
Ukraine
Prior art keywords
catalyst
precatalyst
alkenyl alkanoates
palladium
obtaining
Prior art date
Application number
UAA200606849A
Other languages
Russian (ru)
Ukrainian (uk)
Inventor
Тао Ванг
Лесли Э. Вейд
Виктор Вонг
Дэвид М. Лоув
Альфред Хаджемейер
Джун Хан
Валери Соколовский
Original Assignee
Селаниз Интернэшнл Корпорейшн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Селаниз Интернэшнл Корпорейшн filed Critical Селаниз Интернэшнл Корпорейшн
Publication of UA96563C2 publication Critical patent/UA96563C2/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/398—Egg yolk like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/399—Distribution of the active metal ingredient homogeneously throughout the support particle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The present invention addresses at least four different aspects relating to catalyst structure, method of making those catalysts and methods of using those catalysts for making alkenyl alkanoates. Separately or together in combination, the various aspects of the invention are directed at improving the production of alkenyl alkanoales and VA in particular, including reduction of by-products and improved production efficiency. A first aspect of the present invention pertains to a unique palladium/gold catalyst or pre-catalyst (optionally calcined) that includes rhodium or another metal. A second aspect pertains to a palladium/gold catalyst or precatalyst that is based on a layered support material where one layer of the support materiel is substantially free of catalytic components. A third aspect pertains to a palladium/gold catalyst or precatalysts on a support material containing zirconia with BET surface area from about 10 to about 135 m/g. A fourth aspect pertains to a palladium gold catalyst or pre-catalyst that is produced from substantially chloride free catalytic components.
UAA200606849A 2003-12-19 2004-11-19 Process for preparation of catalyst or precatalyst suitable for obtaining alkenyl alkanoates, composition of catalyst or precatalyst for obtaining alkenyl alkanoates and process for obtaining alkenyl alkanoates UA96563C2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US53148603P 2003-12-19 2003-12-19

Publications (1)

Publication Number Publication Date
UA96563C2 true UA96563C2 (en) 2011-11-25

Family

ID=34710229

Family Applications (1)

Application Number Title Priority Date Filing Date
UAA200606849A UA96563C2 (en) 2003-12-19 2004-11-19 Process for preparation of catalyst or precatalyst suitable for obtaining alkenyl alkanoates, composition of catalyst or precatalyst for obtaining alkenyl alkanoates and process for obtaining alkenyl alkanoates

Country Status (14)

Country Link
EP (1) EP1694436A1 (en)
JP (1) JP4772695B2 (en)
KR (1) KR100886048B1 (en)
CN (1) CN100457257C (en)
AU (1) AU2004305515C1 (en)
BR (1) BRPI0417185A (en)
CA (1) CA2547187C (en)
NO (1) NO20062531L (en)
NZ (1) NZ547072A (en)
PL (1) PL215127B1 (en)
RU (2) RU2006119185A (en)
UA (1) UA96563C2 (en)
WO (1) WO2005061107A1 (en)
ZA (1) ZA200604362B (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8168562B2 (en) 2006-02-02 2012-05-01 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalysts
DE102007025443A1 (en) 2007-05-31 2008-12-04 Süd-Chemie AG Pd / Au coated catalyst containing HfO 2, process for its preparation and its use
DE102007025442B4 (en) 2007-05-31 2023-03-02 Clariant International Ltd. Use of a device for producing a coated catalyst and coated catalyst
DE102007025356A1 (en) * 2007-05-31 2009-01-08 Süd-Chemie AG Process for the preparation of a coated catalyst and coated catalyst
DE102007025362A1 (en) 2007-05-31 2008-12-11 Süd-Chemie AG Doped Pd / Au coated catalyst, process for its preparation and its use
DE102007025223A1 (en) * 2007-05-31 2008-12-04 Süd-Chemie AG Zirconia-doped VAM shell catalyst, process for its preparation and its use
DE102007025444A1 (en) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM shell catalyst, process for its preparation and its use
DE102007025358A1 (en) * 2007-05-31 2009-01-08 Süd-Chemie AG Process for the preparation of a coated with Pd and / or Au shell catalyst
DE102007043446B4 (en) 2007-09-12 2013-08-22 Süd-Chemie Ip Gmbh & Co. Kg Catalyst support with increased thermal conductivity
DE102007043447B4 (en) 2007-09-12 2014-02-13 Süd-Chemie Ip Gmbh & Co. Kg Catalyst support with increased thermal conductivity
DE102008058971A1 (en) * 2008-11-25 2010-07-15 Süd-Chemie AG Shell catalyst, process for its preparation and use
DE102008059342A1 (en) 2008-11-30 2010-06-10 Süd-Chemie AG Shell catalyst, process for its preparation and use
DE102008059340A1 (en) 2008-11-30 2010-06-10 Süd-Chemie AG Catalyst support, process for its preparation and its use
DE202008017277U1 (en) 2008-11-30 2009-04-30 Süd-Chemie AG catalyst support
DE102010026462A1 (en) * 2010-07-08 2012-01-12 Süd-Chemie AG Process for the preparation of a coated catalyst and coated catalyst
CN102153189A (en) * 2010-12-16 2011-08-17 哈尔滨工业大学 Method for removing organic matters in water through pumice catalytic ozonation
DE102012008714A1 (en) * 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Pre-impregnation of coated catalysts with an acetate
CN106215561B (en) * 2016-08-31 2018-04-20 苏州贝捷环保设备有限公司 A kind of coal-fired flue gas treatment method
CN107096532B (en) * 2017-05-16 2019-12-10 嘉兴学院 Au-ZrO 2 catalyst and application thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19501891C1 (en) * 1995-01-23 1996-09-26 Degussa Process for the preparation of a supported catalyst and its use for the production of vinyl acetate
US6072078A (en) * 1997-12-12 2000-06-06 Celanese International Corporation Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate
DE19843693A1 (en) * 1998-09-24 2000-03-30 Degussa Catalyst for vinyl acetate production from ethylene, acetic acid and oxygen contains palladium and other metals on a pyrogenic mixed oxide support based on silicon, aluminum, titanium and/or zirconium oxide
US6358882B1 (en) 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst
DE10030039A1 (en) * 2000-06-17 2002-01-10 Celanese Chem Europe Gmbh Preparation of catalyst, useful in gas phase production of vinyl acetate, involves impregnation with alkaline solution of palladium and other metal compounds fixed by conversion to insoluble compounds on contact with support

Also Published As

Publication number Publication date
RU2011131292A (en) 2013-02-10
AU2004305515C1 (en) 2009-06-25
AU2004305515B2 (en) 2008-08-28
JP2007514543A (en) 2007-06-07
KR100886048B1 (en) 2009-02-26
ZA200604362B (en) 2007-11-28
PL215127B1 (en) 2013-10-31
JP4772695B2 (en) 2011-09-14
RU2006119185A (en) 2007-12-20
WO2005061107A1 (en) 2005-07-07
AU2004305515A1 (en) 2005-07-07
CA2547187A1 (en) 2005-07-07
CN100457257C (en) 2009-02-04
KR20060103514A (en) 2006-10-02
EP1694436A1 (en) 2006-08-30
NZ547072A (en) 2010-05-28
BRPI0417185A (en) 2007-03-06
PL380021A1 (en) 2006-12-11
NO20062531L (en) 2006-07-03
CA2547187C (en) 2010-11-02
CN1894035A (en) 2007-01-10

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