UA94207C2 - Process for making catalyst or precatalyst suitable for making alkenyl alkanoates, composition of catalyst or precatalyst for making alkenyl alkanoates and process for making alkenyl alkanoates - Google Patents
Process for making catalyst or precatalyst suitable for making alkenyl alkanoates, composition of catalyst or precatalyst for making alkenyl alkanoates and process for making alkenyl alkanoatesInfo
- Publication number
- UA94207C2 UA94207C2 UAA200606848A UAA200606848A UA94207C2 UA 94207 C2 UA94207 C2 UA 94207C2 UA A200606848 A UAA200606848 A UA A200606848A UA A200606848 A UAA200606848 A UA A200606848A UA 94207 C2 UA94207 C2 UA 94207C2
- Authority
- UA
- Ukraine
- Prior art keywords
- catalyst
- making
- alkenyl alkanoates
- precatalyst
- palladium
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 9
- 239000012041 precatalyst Substances 0.000 title abstract 6
- 125000003342 alkenyl group Chemical group 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 8
- 239000010931 gold Substances 0.000 abstract 4
- 229910052737 gold Inorganic materials 0.000 abstract 4
- 229910052763 palladium Inorganic materials 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0221—Coating of particles
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
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- B01J35/396—
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- B01J35/397—
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- B01J35/398—
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- B01J35/399—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
Abstract
The present invention addresses at least four different aspects relating to catalyst structure, methods of making those catalysts and methods of using those catalysts for making alkenyl alkanoates. Separately or together in combination, the various aspects of the invention are directed at improving the production of alkenyl alkanoates and VA in particular, including reduction of by-products and improved production efficiency. A first aspect of the present invention pertains to a unique palladium/gold catalyst or pre-catalyst (optionally calcined) that includes rhodium or another metal. A second aspect pertains to a palladium/gold catalyst i or precatalyst that is based on a layered support material where one layer of the support material is substantially free of catalytic components. A third aspect pertains to a palladium/gold catalyst or pre-catalyst on a zirconia containing support material. A fourth aspect pertains to a palladium/gold catalyst or pre-catalyst that is produced from substantially chloride free catalytic components.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US53093703P | 2003-12-19 | 2003-12-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
UA94207C2 true UA94207C2 (en) | 2011-04-26 |
Family
ID=34748749
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
UAA200606848A UA94207C2 (en) | 2003-12-19 | 2004-11-19 | Process for making catalyst or precatalyst suitable for making alkenyl alkanoates, composition of catalyst or precatalyst for making alkenyl alkanoates and process for making alkenyl alkanoates |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP1694434A1 (en) |
JP (2) | JP5096003B2 (en) |
KR (1) | KR100897641B1 (en) |
CN (1) | CN100464844C (en) |
AU (1) | AU2004311901B2 (en) |
BR (1) | BRPI0417164A (en) |
CA (1) | CA2547313C (en) |
NO (1) | NO20062529L (en) |
NZ (1) | NZ547071A (en) |
PL (1) | PL380019A1 (en) |
RU (1) | RU2397017C2 (en) |
UA (1) | UA94207C2 (en) |
WO (1) | WO2005065819A1 (en) |
ZA (1) | ZA200604361B (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4835011B2 (en) * | 2005-03-17 | 2011-12-14 | 東ソー株式会社 | Novel structure containing silica alumina and method for producing the same. |
DE102007022052A1 (en) * | 2007-05-08 | 2008-11-13 | Basell Polyolefine Gmbh | Catalyst system for olefin polymerization, process for their preparation, and a process for the polymerization of α-olefins using the catalyst system |
FR2934264B1 (en) * | 2008-07-22 | 2012-07-20 | Arkema France | MANUFACTURE OF VINYL ESTERS FROM RENEWABLE MATERIALS, VINYL ESTERS OBTAINED AND USES THEREOF |
US7960503B2 (en) * | 2009-05-26 | 2011-06-14 | Solutia, Inc. | Continuous washing of poly(vinyl butyral) |
DE102011101459A1 (en) * | 2011-05-13 | 2012-11-15 | Süd-Chemie AG | Process for the preparation of a metal-containing coated catalyst without Zwischenkalzinierung |
DE102012008714A1 (en) * | 2012-05-03 | 2013-11-07 | Clariant Produkte (Deutschland) Gmbh | Pre-impregnation of coated catalysts with an acetate |
CN104549515B (en) * | 2013-10-28 | 2019-04-12 | 中国石油化工股份有限公司 | Vinyl acetate catalyst and preparation method |
DE102014224470A1 (en) | 2014-11-28 | 2016-06-02 | Wacker Chemie Ag | Removal of oxygen from hydrocarbon gases |
JP6606213B2 (en) * | 2018-03-28 | 2019-11-13 | 俊夫 小室 | Health promoting composition that generates photons and ions |
RU2744920C1 (en) * | 2019-12-05 | 2021-03-17 | Федеральное государственное автономное образовательное учреждение высшего образования "Уральский федеральный университет имени первого Президента России Б.Н. Ельцина" | Method of bimetallic palladium-rhodium catalysts preparation (versions) |
CN114433199B (en) * | 2020-10-31 | 2023-09-01 | 中国石油化工股份有限公司 | Catalyst for ammonification reaction and preparation method and application thereof |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0672453B1 (en) * | 1994-02-22 | 2005-11-02 | The Standard Oil Company | Process for the preparation of fluid bed vinyl acetate catalyst |
DE19501891C1 (en) * | 1995-01-23 | 1996-09-26 | Degussa | Process for the preparation of a supported catalyst and its use for the production of vinyl acetate |
DE19723591A1 (en) * | 1997-06-05 | 1998-12-10 | Hoechst Ag | Catalyst, process for its preparation and its use for the production of vinyl acetate |
GB9813367D0 (en) * | 1998-06-22 | 1998-08-19 | Johnson Matthey Plc | Catalyst |
DE10030039A1 (en) * | 2000-06-17 | 2002-01-10 | Celanese Chem Europe Gmbh | Preparation of catalyst, useful in gas phase production of vinyl acetate, involves impregnation with alkaline solution of palladium and other metal compounds fixed by conversion to insoluble compounds on contact with support |
-
2004
- 2004-11-19 BR BRPI0417164-0A patent/BRPI0417164A/en not_active Application Discontinuation
- 2004-11-19 UA UAA200606848A patent/UA94207C2/en unknown
- 2004-11-19 RU RU2006119184/04A patent/RU2397017C2/en not_active IP Right Cessation
- 2004-11-19 EP EP04811518A patent/EP1694434A1/en not_active Ceased
- 2004-11-19 CN CNB2004800372066A patent/CN100464844C/en not_active Expired - Fee Related
- 2004-11-19 WO PCT/US2004/038815 patent/WO2005065819A1/en not_active Application Discontinuation
- 2004-11-19 AU AU2004311901A patent/AU2004311901B2/en not_active Ceased
- 2004-11-19 PL PL380019A patent/PL380019A1/en not_active IP Right Cessation
- 2004-11-19 CA CA2547313A patent/CA2547313C/en not_active Expired - Fee Related
- 2004-11-19 ZA ZA200604361A patent/ZA200604361B/en unknown
- 2004-11-19 JP JP2006545664A patent/JP5096003B2/en not_active Expired - Fee Related
- 2004-11-19 NZ NZ547071A patent/NZ547071A/en not_active IP Right Cessation
- 2004-11-19 KR KR1020067010652A patent/KR100897641B1/en not_active IP Right Cessation
-
2006
- 2006-06-01 NO NO20062529A patent/NO20062529L/en not_active Application Discontinuation
-
2012
- 2012-06-01 JP JP2012125817A patent/JP2012196674A/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
EP1694434A1 (en) | 2006-08-30 |
JP2012196674A (en) | 2012-10-18 |
JP5096003B2 (en) | 2012-12-12 |
CA2547313C (en) | 2010-11-02 |
JP2007514541A (en) | 2007-06-07 |
ZA200604361B (en) | 2007-11-28 |
PL380019A1 (en) | 2006-12-11 |
CN100464844C (en) | 2009-03-04 |
CN1894034A (en) | 2007-01-10 |
AU2004311901B2 (en) | 2008-08-21 |
KR20060096092A (en) | 2006-09-05 |
CA2547313A1 (en) | 2005-07-21 |
NZ547071A (en) | 2010-05-28 |
KR100897641B1 (en) | 2009-05-14 |
WO2005065819A1 (en) | 2005-07-21 |
BRPI0417164A (en) | 2007-03-06 |
RU2397017C2 (en) | 2010-08-20 |
RU2006119184A (en) | 2007-12-20 |
NO20062529L (en) | 2006-07-03 |
AU2004311901A1 (en) | 2005-07-21 |
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