RO86972B - Process for the separation of phenol from water - Google Patents
Process for the separation of phenol from waterInfo
- Publication number
- RO86972B RO86972B RO109856A RO10985683A RO86972B RO 86972 B RO86972 B RO 86972B RO 109856 A RO109856 A RO 109856A RO 10985683 A RO10985683 A RO 10985683A RO 86972 B RO86972 B RO 86972B
- Authority
- RO
- Romania
- Prior art keywords
- phenol
- water
- extraction agent
- bisphenol
- isopropenylphenol
- Prior art date
Links
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title abstract 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000000926 separation method Methods 0.000 title 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 238000000605 extraction Methods 0.000 abstract 3
- JAGRUUPXPPLSRX-UHFFFAOYSA-N 4-prop-1-en-2-ylphenol Chemical compound CC(=C)C1=CC=C(O)C=C1 JAGRUUPXPPLSRX-UHFFFAOYSA-N 0.000 abstract 2
- 229930185605 Bisphenol Natural products 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 150000004985 diamines Chemical class 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Inventia se refera la un procedeu de separare a fenolului din apa prin extractia acestuia cu un agent de extractie, prin care, în scopul recuperarii fenolului prin reducerea concentratiei sale în apa de la 6...10% pâna la 0,3...2%, eventual pâna la 0,1...1% în greutate, se agita la o temperatura de 80...100 degree C emulsie formata din solutie apoasa fenolica si agentul de extractie constituit din fractiunea de produse secundare rezultata la fabricarea bisfenolului, din care, eventual, s-a distilat fenolul si care contine 0,6% fenol, 0,1...12% p-izopropenilfenol, 0,4...7% 1,3,3-trimetil-6-hidroxiinden-1, 5...11% diamina, 14...21% dimeri de p-izopropenilfenol, 0,8...23,6% trisfenoli, 4...8% bisfenol A si izomerii sai, la un raport gavrimetric de 1:2,3...4 agent de extractie:solutie fenolica, adaugîndu-se eventual un schimbator cationic cu continut de hidrogen.The invention relates to a process for separating phenol from water by extracting it with an extraction agent, whereby, in order to recover the phenol by reducing its concentration in water from 6 ... 10% to 0.3 ... 2%, possibly up to 0.1 ... 1% by weight, is stirred at a temperature of 80-100 ° C, an emulsion composed of phenolic aqueous solution and the extraction agent consisting of the by-product fraction resulting from the manufacture of bisphenol , from which the phenol has been distilled and contains 0.6% phenol, 0.1 ... 12% p-isopropenylphenol, 0.4 ... 7% 1,3,3-trimethyl-6-hydroxyinden- 1, 5 ... 11% diamine, 14 ... 21% p-isopropenylphenol dimers, 0.8 ... 23.6% trisphenols, 4 ... 8% bisphenol A and its isomers at a gavimetric ratio 1: 2,3 ... 4 extraction agent: phenolic solution, eventually adding a hydrogen-containing cation exchanger.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL23490282A PL137490B1 (en) | 1982-01-30 | 1982-01-30 | Method of isolating phenol from phenolic process effluents |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO86972A RO86972A (en) | 1985-05-20 |
| RO86972B true RO86972B (en) | 1985-05-31 |
Family
ID=20011383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO109856A RO86972B (en) | 1982-01-30 | 1983-01-28 | Process for the separation of phenol from water |
Country Status (4)
| Country | Link |
|---|---|
| CS (1) | CS245780B2 (en) |
| DD (1) | DD207543A5 (en) |
| PL (1) | PL137490B1 (en) |
| RO (1) | RO86972B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4720596A (en) * | 1986-12-09 | 1988-01-19 | General Electric Company | Process for removing phenols from water |
| CN105176556A (en) * | 2015-09-11 | 2015-12-23 | 波露明（北京）科技有限公司 | Method for separating phenol from coal tar phenol-containing distillate oil |
-
1982
- 1982-01-30 PL PL23490282A patent/PL137490B1/en unknown
-
1983
- 1983-01-19 CS CS83382A patent/CS245780B2/en unknown
- 1983-01-28 RO RO109856A patent/RO86972B/en unknown
- 1983-01-28 DD DD24755183A patent/DD207543A5/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS245780B2 (en) | 1986-10-16 |
| RO86972A (en) | 1985-05-20 |
| PL137490B1 (en) | 1986-06-30 |
| PL234902A1 (en) | 1983-08-01 |
| DD207543A5 (en) | 1984-03-07 |
| CS38283A2 (en) | 1985-12-16 |
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