RO86901B1 - Process for the separation of cerium from trivalent lantanides - Google Patents
Process for the separation of cerium from trivalent lantanidesInfo
- Publication number
- RO86901B1 RO86901B1 RO112004A RO11200483A RO86901B1 RO 86901 B1 RO86901 B1 RO 86901B1 RO 112004 A RO112004 A RO 112004A RO 11200483 A RO11200483 A RO 11200483A RO 86901 B1 RO86901 B1 RO 86901B1
- Authority
- RO
- Romania
- Prior art keywords
- cerium
- separation
- solution
- trivalent
- carbonate
- Prior art date
Links
Landscapes
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Inventia se refera la un procedeu de separare a ceriului de lantanide trivalente prin precipitare oxidanta, aducand în contact solutia cu continut de CeO2 si Ln2O3 cu o suspensie apoasa de carbonat sau bicarbonat de amoniu Ce02 de 3:1 si cu apa în exces de 250% fata de necesarul stoichiometric, în care în scopul obtinerii unei precipitari cantitative a ceriului continut în solutie se adauga simultan cantitatile prestabilite de carbonat sau bicarbinat de amoniu si apa oxigenta în solutia supusa tratarii în care pH>3 la peste 95 degree C si se mentine sub agitare amestecul de reactie la aceasta temperatura timp de o ora.The invention relates to a process for the separation of trivalent lanthanide cerium by oxidative precipitation, bringing the solution containing CeO2 and Ln2O3 with an aqueous suspension of carbonate or ammonium bicarbonate CeO2 of 3: 1 and with water in excess of 250% to the stoichiometric requirement, wherein in order to obtain a quantitative precipitation of the cerium contained in the solution, the preset amounts of carbonate or ammonium bicarbonate and oxygenated water are simultaneously added to the solution to be treated where the pH> 3 exceeds 95 ° C and is maintained under stirring the reaction mixture at this temperature for one hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO112004A RO86901B1 (en) | 1983-09-07 | 1983-09-07 | Process for the separation of cerium from trivalent lantanides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO112004A RO86901B1 (en) | 1983-09-07 | 1983-09-07 | Process for the separation of cerium from trivalent lantanides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO86901A2 RO86901A2 (en) | 1985-06-29 |
| RO86901B1 true RO86901B1 (en) | 1985-06-30 |
Family
ID=20113602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO112004A RO86901B1 (en) | 1983-09-07 | 1983-09-07 | Process for the separation of cerium from trivalent lantanides |
Country Status (1)
| Country | Link |
|---|---|
| RO (1) | RO86901B1 (en) |
-
1983
- 1983-09-07 RO RO112004A patent/RO86901B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO86901A2 (en) | 1985-06-29 |
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