RO85277B - PROCESS FOR THE PREPARATION OF ANY IMIDAZOLE PROPIONITRILS - Google Patents

PROCESS FOR THE PREPARATION OF ANY IMIDAZOLE PROPIONITRILS

Info

Publication number
RO85277B
RO85277B RO107928A RO10792882A RO85277B RO 85277 B RO85277 B RO 85277B RO 107928 A RO107928 A RO 107928A RO 10792882 A RO10792882 A RO 10792882A RO 85277 B RO85277 B RO 85277B
Authority
RO
Romania
Prior art keywords
carbon atoms
alkyl
imidazole
halogen
preparation
Prior art date
Application number
RO107928A
Other languages
Romanian (ro)
Other versions
RO85277A (en
Inventor
Dietrich Boumert
Carlo Skotsch
Hansjorg Krahmer
Ernst Pieroh
Original Assignee
Schering A.G.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Schering A.G. filed Critical Schering A.G.
Publication of RO85277A publication Critical patent/RO85277A/en
Publication of RO85277B publication Critical patent/RO85277B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/501,3-Diazoles; Hydrogenated 1,3-diazoles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D249/00Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/081,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Inventia se refera la un procedeu pentru prepararea unor imidazolipropionitrili cu formula generala I: în care R reprezinta un radical fenil eventual substituit, o data sau de mai multe ori, cu acelasi halogen diferiti, alchil cu 1...4 atomi de carbon alcoxi cu 1...4 atomi de carbon, alchiltio cu 1...4 atomi de carbon, trifluormetil sau cu grupa nitro si R1 reprezinta alchil 1...10 atomi de carbon, alchenil cu 3...8 atomi de carbon, alchinil cu 3...8 atomi de carbon sau un radical fenilalchil eventual substituit o data sau de mai multe ori, cu acelasi halogen sau halogeni diferiti, alchil cu 1...4 atomi de carbon, alchiltio cu 1...4 atomi de carbon, trifluormetil sau grupe nitro. Procedeul consta în aceea ca, compusi cu formula generala II: (vezi formula) în care R1 si R au semnificatia de mai sus si Y reprezinta halogen, sau eventual radicalul arilsulfoniloxi sau radicalul arilsulfoniloxi halogenat în catena laterala, reactioneaza cu imidazolul, rectia avînd loc în dimetilformamida la 140 degree C în mediu anhidru, eventual în prezenta unei baze.The invention relates to a process for the preparation of imidazolipropionitriles of the general formula I: wherein R represents a phenyl radical optionally substituted once or more times with the same different halogen, alkyl of 1-4 carbon atoms of alkoxy 1 to 4 carbon atoms, C1-4 alkylthio, trifluoromethyl or nitro and R1 is C1 to C10 alkyl, C3-8 alkenyl, alkynyl with 3 to 8 carbon atoms or a phenylalkyl radical optionally substituted once or more times with the same halogen or different halogens, alkyl of 1-4 carbon atoms, 1-4C alkylthio carbon, trifluoromethyl or nitro groups. The process consists in that compounds of the general formula II wherein R1 and R2 are as defined above and Y represents halogen or optionally the arylsulfonyloxy radical or the arylsulfonyloxy radical halogenated in the side chain is reacted with the imidazole, in dimethylformamide at 140 ° C in anhydrous medium, optionally in the presence of a base.

RO107928A 1981-06-30 1982-06-18 PROCESS FOR THE PREPARATION OF ANY IMIDAZOLE PROPIONITRILS RO85277B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19813125780 DE3125780A1 (en) 1981-06-30 1981-06-30 IMIDAZOLYL-PROPIONITRILE, METHOD FOR PRODUCING THESE COMPOUNDS AND THE BIOCIDES CONTAINING THEM

Publications (2)

Publication Number Publication Date
RO85277A RO85277A (en) 1984-09-29
RO85277B true RO85277B (en) 1984-10-30

Family

ID=6135760

Family Applications (1)

Application Number Title Priority Date Filing Date
RO107928A RO85277B (en) 1981-06-30 1982-06-18 PROCESS FOR THE PREPARATION OF ANY IMIDAZOLE PROPIONITRILS

Country Status (37)

Country Link
JP (1) JPS6055070B2 (en)
KR (1) KR840000506A (en)
AR (1) AR231440A1 (en)
AT (1) ATA247082A (en)
AU (1) AU8546482A (en)
BE (1) BE893696A (en)
BG (1) BG37373A3 (en)
BR (1) BR8203803A (en)
CA (1) CA1186317A (en)
CH (1) CH655311A5 (en)
CS (1) CS236480B2 (en)
DD (1) DD202977A5 (en)
DE (1) DE3125780A1 (en)
DK (1) DK291582A (en)
ES (1) ES8304092A1 (en)
FI (1) FI822033L (en)
FR (1) FR2519635A1 (en)
GB (1) GB2101995B (en)
GR (1) GR81396B (en)
HU (1) HU189598B (en)
IL (1) IL66164A (en)
IT (1) IT1151802B (en)
LU (1) LU84246A1 (en)
MA (1) MA19512A1 (en)
NL (1) NL8202339A (en)
NO (1) NO822231L (en)
NZ (1) NZ200967A (en)
PH (1) PH19047A (en)
PL (1) PL129716B1 (en)
PT (1) PT75147B (en)
RO (1) RO85277B (en)
SE (1) SE8204027L (en)
SU (2) SU1114334A3 (en)
TR (1) TR21402A (en)
YU (1) YU125882A (en)
ZA (1) ZA824688B (en)
ZW (1) ZW13182A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3329213A1 (en) * 1983-08-10 1985-02-21 Schering AG, 1000 Berlin und 4709 Bergkamen AZOLYL PROPANNITRILE, METHOD FOR PRODUCING THESE COMPOUNDS AND THE BIOCIDES CONTAINING THEM
DE3644616A1 (en) * 1986-12-29 1988-07-07 Lentia Gmbh IMIDAZOLE DERIVATIVES, METHOD FOR THE PRODUCTION AND USE THEREOF
JPS63120362U (en) * 1987-01-28 1988-08-04
JPH0624355U (en) * 1991-07-12 1994-03-29 株式会社三輝産業 Battery charger
RU2223646C2 (en) * 1998-12-31 2004-02-20 Селген Корпорейшн Chiral imidazole-base fungicide composition and methods for their application
USD872768S1 (en) 2016-02-19 2020-01-14 Sony Corporation Robot having display screen with animated graphical user interface

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4167576A (en) * 1977-10-06 1979-09-11 Rohm And Haas Company Cyanoaralkylheterocyclic compounds
EP0158741A3 (en) * 1980-11-19 1986-02-12 Imperial Chemical Industries Plc Intermediates for fungicidal triazole and imidazole compounds

Also Published As

Publication number Publication date
PT75147B (en) 1984-05-25
BE893696A (en) 1982-12-29
ES512949A0 (en) 1983-03-16
DD202977A5 (en) 1983-10-12
FR2519635A1 (en) 1983-07-18
YU125882A (en) 1985-03-20
CA1186317A (en) 1985-04-30
MA19512A1 (en) 1982-12-31
ES8304092A1 (en) 1983-03-16
IL66164A (en) 1985-06-30
DK291582A (en) 1982-12-31
HU189598B (en) 1986-07-28
CS236480B2 (en) 1985-05-15
PL237145A1 (en) 1983-02-14
DE3125780A1 (en) 1983-01-13
NO822231L (en) 1983-01-03
GR81396B (en) 1984-12-11
LU84246A1 (en) 1983-01-20
CH655311A5 (en) 1986-04-15
FI822033A0 (en) 1982-06-08
ZA824688B (en) 1983-04-27
GB2101995A (en) 1983-01-26
SU1114334A3 (en) 1984-09-15
NL8202339A (en) 1983-01-17
BR8203803A (en) 1983-06-28
SE8204027D0 (en) 1982-06-29
AU8546482A (en) 1984-01-05
IL66164A0 (en) 1982-09-30
SE8204027L (en) 1982-12-31
FI822033A7 (en) 1982-12-31
ZW13182A1 (en) 1982-10-20
JPS588070A (en) 1983-01-18
KR840000506A (en) 1984-02-22
PH19047A (en) 1985-12-11
RO85277A (en) 1984-09-29
ATA247082A (en) 1986-04-15
PT75147A (en) 1982-07-01
SU1245251A3 (en) 1986-07-15
GB2101995B (en) 1985-05-22
AR231440A1 (en) 1984-11-30
IT8221939A0 (en) 1982-06-18
PL129716B1 (en) 1984-06-30
BG37373A3 (en) 1985-05-15
NZ200967A (en) 1985-07-12
FI822033L (en) 1982-12-31
JPS6055070B2 (en) 1985-12-03
IT1151802B (en) 1986-12-24
FR2519635B1 (en) 1985-02-01
TR21402A (en) 1984-05-22

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