RO85049B - Procedeu de preparare a unor derivati organofosfonotioici - Google Patents
Procedeu de preparare a unor derivati organofosfonotioiciInfo
- Publication number
- RO85049B RO85049B RO105809A RO10580981A RO85049B RO 85049 B RO85049 B RO 85049B RO 105809 A RO105809 A RO 105809A RO 10580981 A RO10580981 A RO 10580981A RO 85049 B RO85049 B RO 85049B
- Authority
- RO
- Romania
- Prior art keywords
- alkyl radical
- organo
- derivatives
- preparation
- carbon atoms
- Prior art date
Links
- 125000000962 organic group Chemical group 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 abstract 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 abstract 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 230000001069 nematicidal effect Effects 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/42—Halides thereof
- C07F9/425—Acid or estermonohalides thereof, e.g. RP(=X)(YR)(Hal) (X, Y = O, S; R = H, or hydrocarbon group)
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4075—Esters with hydroxyalkyl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4084—Esters with hydroxyaryl compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lubrication Details And Ventilation Of Internal Combustion Engines (AREA)
Abstract
Inventia se refera la un procedeu pentru prepararea unor derivati organo-fosfonotioici cu formula mgenerala I: (vezi foemula) în care R reprezinta un radical alchil inferior, R1 reprezinta un radical alchil cu 1...8 atomi de carbon sau un radical fenil, eventual, substituit cu metil, halogen sau trifluormetil, R2 reprezinta un radical alchil tertiar cu 4...8 atomi de acarbon, compusi cu activitatea insecticida si nematocida, carcatwerizat prin aceea ca alchilfosfonotioc cu formula generala Ii: (vezi formula) în care R si R2 au semnificatiile de mai sus, iar X reprezinta un atom de halogen, reactioneaza cu un compus cu formula henerala III: (vezi formula) în care R1 prezinta semnificatiile sus-mentionate, la emperaturi cuprinse între 20 si 100 degree C, într-un nsolvent organic, ales dintre benzen, toluen, ciclohexan si butan-2-ona, în prezenta unei amine tertiare, aleasa dintre trimetilamina, trietilamina, dimetilanilina, dietilanilina sau piridina sau o solutie apoasa de hidroxid de sodiu.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US20909380A | 1980-11-21 | 1980-11-21 | |
| US20909480A | 1980-11-21 | 1980-11-21 | |
| US06/221,642 US4391760A (en) | 1980-12-31 | 1980-12-31 | S-(Tertiary alkyl) alkylphosphonothioic halides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO85049A RO85049A (ro) | 1984-08-17 |
| RO85049B true RO85049B (ro) | 1984-09-30 |
Family
ID=27395322
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO81114686A RO87258A (ro) | 1980-11-21 | 1981-11-18 | Procedeu pentru preparare unor derivati organofosforici |
| RO114687A RO90683B (ro) | 1980-11-21 | 1981-11-18 | Compozitie insecticida si/sau nematocida |
| RO105809A RO85049B (ro) | 1980-11-21 | 1981-11-18 | Procedeu de preparare a unor derivati organofosfonotioici |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO81114686A RO87258A (ro) | 1980-11-21 | 1981-11-18 | Procedeu pentru preparare unor derivati organofosforici |
| RO114687A RO90683B (ro) | 1980-11-21 | 1981-11-18 | Compozitie insecticida si/sau nematocida |
Country Status (19)
| Country | Link |
|---|---|
| AT (1) | AT380885B (ro) |
| AU (1) | AU553581B2 (ro) |
| BG (1) | BG36349A3 (ro) |
| BR (1) | BR8107581A (ro) |
| CA (1) | CA1224474A (ro) |
| CH (2) | CH650002A5 (ro) |
| DD (1) | DD202167A5 (ro) |
| DE (1) | DE3146056A1 (ro) |
| DK (1) | DK515181A (ro) |
| ES (2) | ES8307831A1 (ro) |
| GB (2) | GB2087891B (ro) |
| IL (1) | IL64186A0 (ro) |
| IT (1) | IT1140285B (ro) |
| LU (1) | LU83780A1 (ro) |
| MA (1) | MA19336A1 (ro) |
| NL (1) | NL8105228A (ro) |
| OA (1) | OA06955A (ro) |
| PH (2) | PH18262A (ro) |
| RO (3) | RO87258A (ro) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4472391A (en) * | 1980-11-21 | 1984-09-18 | Rhone-Poulenc Agrochimie | O-Aryl-s-(tertiary alkyl) alkylphosphonothioate insecticides and nematocides |
-
1981
- 1981-11-02 IL IL64186A patent/IL64186A0/xx unknown
- 1981-11-18 RO RO81114686A patent/RO87258A/ro unknown
- 1981-11-18 NL NL8105228A patent/NL8105228A/nl not_active Application Discontinuation
- 1981-11-18 RO RO114687A patent/RO90683B/ro unknown
- 1981-11-18 RO RO105809A patent/RO85049B/ro unknown
- 1981-11-19 BG BG054210A patent/BG36349A3/xx unknown
- 1981-11-19 PH PH26514A patent/PH18262A/en unknown
- 1981-11-19 AU AU77631/81A patent/AU553581B2/en not_active Ceased
- 1981-11-19 GB GB8134877A patent/GB2087891B/en not_active Expired
- 1981-11-19 CA CA000390415A patent/CA1224474A/en not_active Expired
- 1981-11-20 DE DE19813146056 patent/DE3146056A1/de not_active Withdrawn
- 1981-11-20 DK DK515181A patent/DK515181A/da not_active Application Discontinuation
- 1981-11-20 ES ES507318A patent/ES8307831A1/es not_active Expired
- 1981-11-20 CH CH7469/81A patent/CH650002A5/fr not_active IP Right Cessation
- 1981-11-20 IT IT25205/81A patent/IT1140285B/it active
- 1981-11-20 LU LU83780A patent/LU83780A1/fr unknown
- 1981-11-20 DD DD81235018A patent/DD202167A5/de unknown
- 1981-11-20 BR BR8107581A patent/BR8107581A/pt unknown
- 1981-11-20 AT AT0501181A patent/AT380885B/de not_active IP Right Cessation
- 1981-11-20 MA MA19540A patent/MA19336A1/fr unknown
- 1981-11-20 CH CH5245/84A patent/CH651575A5/fr not_active IP Right Cessation
- 1981-11-21 OA OA57551A patent/OA06955A/xx unknown
-
1982
- 1982-10-13 ES ES516464A patent/ES8400751A1/es not_active Expired
-
1983
- 1983-09-26 PH PH29595A patent/PH19084A/en unknown
- 1983-12-05 GB GB08332398A patent/GB2140808B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AU553581B2 (en) | 1986-07-24 |
| CH651575A5 (fr) | 1985-09-30 |
| RO87258B (ro) | 1985-08-31 |
| AU7763181A (en) | 1982-05-27 |
| CH650002A5 (fr) | 1985-06-28 |
| GB2087891B (en) | 1985-02-06 |
| GB2087891A (en) | 1982-06-03 |
| GB2140808A (en) | 1984-12-05 |
| ES516464A0 (es) | 1983-11-01 |
| GB8332398D0 (en) | 1984-01-11 |
| ES507318A0 (es) | 1983-02-16 |
| RO87258A (ro) | 1985-08-31 |
| NL8105228A (nl) | 1982-06-16 |
| OA06955A (fr) | 1983-07-31 |
| PH19084A (en) | 1985-12-19 |
| ATA501181A (de) | 1985-12-15 |
| RO90683B (ro) | 1987-01-31 |
| RO85049A (ro) | 1984-08-17 |
| ES8400751A1 (es) | 1983-11-01 |
| AT380885B (de) | 1986-07-25 |
| IT1140285B (it) | 1986-09-24 |
| DK515181A (da) | 1982-05-22 |
| ES8307831A1 (es) | 1983-02-16 |
| RO90683A (ro) | 1987-01-30 |
| DE3146056A1 (de) | 1982-06-16 |
| MA19336A1 (fr) | 1982-07-01 |
| CA1224474A (en) | 1987-07-21 |
| PH18262A (en) | 1985-05-14 |
| IL64186A0 (en) | 1982-02-28 |
| BR8107581A (pt) | 1982-08-17 |
| IT8125205A0 (it) | 1981-11-20 |
| DD202167A5 (de) | 1983-08-31 |
| GB2140808B (en) | 1985-06-19 |
| BG36349A3 (en) | 1984-10-15 |
| LU83780A1 (fr) | 1983-09-01 |
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