PL90605B1 - - Google Patents

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Publication number
PL90605B1
PL90605B1 PL17613671A PL17613671A PL90605B1 PL 90605 B1 PL90605 B1 PL 90605B1 PL 17613671 A PL17613671 A PL 17613671A PL 17613671 A PL17613671 A PL 17613671A PL 90605 B1 PL90605 B1 PL 90605B1
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PL
Poland
Prior art keywords
group
formula
general formula
compound
carbon atoms
Prior art date
Application number
PL17613671A
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Polish (pl)
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Publication of PL90605B1 publication Critical patent/PL90605B1/pl

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D243/00Heterocyclic compounds containing seven-membered rings having two nitrogen atoms as the only ring hetero atoms
    • C07D243/06Heterocyclic compounds containing seven-membered rings having two nitrogen atoms as the only ring hetero atoms having the nitrogen atoms in positions 1 and 4
    • C07D243/10Heterocyclic compounds containing seven-membered rings having two nitrogen atoms as the only ring hetero atoms having the nitrogen atoms in positions 1 and 4 condensed with carbocyclic rings or ring systems
    • C07D243/141,4-Benzodiazepines; Hydrogenated 1,4-benzodiazepines
    • C07D243/161,4-Benzodiazepines; Hydrogenated 1,4-benzodiazepines substituted in position 5 by aryl radicals
    • C07D243/181,4-Benzodiazepines; Hydrogenated 1,4-benzodiazepines substituted in position 5 by aryl radicals substituted in position 2 by nitrogen, oxygen or sulfur atoms
    • C07D243/24Oxygen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Plural Heterocyclic Compounds (AREA)

Claims (3)

Zastrzezenia patentowe 1. Sposób wytwarzania nowych pochodnych benzodiazepiny o ogólnym wzorze 1, w którym Rt oznacza grupe cyjanowa, R2 oznacza grupe pirydylowa lub grupe o ogólnym wzorze 2, w którym R5 i R6 sa jednakowe lub rózne i oznaczaja atomy wodoru, atomy chlorowca, rodniki alkilowe o 1—4 atomach wegla lub rodniki trójfluorometylowe, R3 oznacza rodnik aralkilowy, R4 oznacza grupe czterowodoropiranyloksylowa lub czterowodorofuranyloksylowa, m oznacza zero lub 1, a n oznacza liczbe calkowita 1-4, albo addycyjnych soli tych zwiazków z kwasami, znamienny tym, ze zwiazek o ogólnym wzorze 3, w którym Rt, R2, R4 i n maja wyzej podane znaczenie, poddaje sie reakcji ze zwiazkiem o ogólnym wzorze 4, w którym R3 ma wyzej podane znaczenie, a X oznacza atom tlenu lub siarki.Claims 1. A method for the preparation of new benzodiazepine derivatives of the general formula 1, in which Rt is a cyano group, R2 is a pyridyl group or a group of the general formula 2, in which R5 and R6 are the same or different and represent hydrogen atoms, halogen atoms, radicals alkyl with 1-4 carbon atoms or trifluoromethyl radicals, R3 is an aralkyl radical, R4 is a tetrahydro-pyranyloxy or tetrahydrofuranyloxy group, m is zero or 1, and n is an integer of 1-4 or addition salts of these compounds with acids, characterized by the compound is reacted with a compound of general formula IV in which R3 is as defined above and X is oxygen or sulfur. 2. Sposób, wedlug zastrz. 1, znamienny tym, ze reakcje prowadzi sie w obecnosci kwasu.2. The method according to claim The process of claim 1, wherein the reactions are carried out in the presence of an acid. 3. Sposób wytwarzania nowych pochodnych benzodiazepiny o ogólnym wzorze 1, w którym Ri oznacza* 90605 3 atom wodoru lub chlorowca, grupe nitrowa, grupe alkoksylowa o 1—4 atomach wegla lub grupe trójfluoromety- lowa, R2 oznacza grupe pirydylowa lub grupe o ogólnym wzorze 2, w którym R5 i R6 sa jednakowe lub rózne i oznaczaja atomy wodoru, atomy chlorowca, rodniki alkilowe o T—4 atomach wegla lub rodniki trójfluoromety- lowe, R3 oznacza atom wodoru lub rodnik alkilowy o 1—4 atomach wegla, R4 oznacza grupe aryloksylowa, aralkoksylowa lub alkoksyalkoksylowa, m oznacza zero, a n oznacza liczbe calkowita11—4, albo addycyjnych soli tych zwiazków z kwasami, znamienny tym, ze zwiazek o ogólnym wzorze 3, w którym Rlf R2, R4 i n maja wyzej podane znaczenie, poddaje sie reakcji ze zwiazkiem o ogólnym wzorze 4, w którym R3 ma wyzej podane znaczenie, a X oznacza atom tlenu. Ri CnH2n 0 Ci X R2 WzóM (0)m Wzór 2 R j^NH-CnH2n-R4 i Wzór3 R3-CH-C( Wzór k PL3. Process for the preparation of new benzodiazepine derivatives of the general formula I, in which R 1 is a hydrogen or halogen atom, a nitro group, an alkoxy group with 1-4 carbon atoms or a trifluoromethyl group, R2 is a pyridyl group or a group of the general formula 2, in which R5 and R6 are the same or different and represent hydrogen atoms, halogen atoms, alkyl radicals with T -4 carbon atoms or trifluoromethyl radicals, R3 is a hydrogen atom or an alkyl radical of 1-4 carbon atoms, R4 is a group aryloxy, aralkoxy or alkoxyalkoxy, m is zero, and n is the integer 11-4, or acid addition salts of these compounds, characterized in that a compound of general formula III, wherein R1f, R2, R4, and n are as defined above, is reacted with a compound of formula IV wherein R3 is as defined above and X is oxygen. Ri CnH2n 0 Ci X R2 Formula (0) m Formula 2 R j ^ NH-CnH2n-R4 and Formula 3 R3-CH-C (Formula k PL
PL17613671A 1970-09-02 1971-08-31 PL90605B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7732370A JPS4831120B1 (en) 1970-09-02 1970-09-02

Publications (1)

Publication Number Publication Date
PL90605B1 true PL90605B1 (en) 1977-01-31

Family

ID=13630711

Family Applications (1)

Application Number Title Priority Date Filing Date
PL17613671A PL90605B1 (en) 1970-09-02 1971-08-31

Country Status (5)

Country Link
JP (1) JPS4831120B1 (en)
AT (1) AT312620B (en)
CH (1) CH583207A5 (en)
PL (1) PL90605B1 (en)
SU (1) SU584772A3 (en)

Also Published As

Publication number Publication date
AT312620B (en) 1973-12-15
JPS4831120B1 (en) 1973-09-26
SU584772A3 (en) 1977-12-15
CH583207A5 (en) 1976-12-31

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