PL76589B2 - - Google Patents
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- PL76589B2 PL76589B2 PL12714968A PL12714968A PL76589B2 PL 76589 B2 PL76589 B2 PL 76589B2 PL 12714968 A PL12714968 A PL 12714968A PL 12714968 A PL12714968 A PL 12714968A PL 76589 B2 PL76589 B2 PL 76589B2
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- PL
- Poland
- Prior art keywords
- parts
- group
- general formula
- hydrogen
- dyes
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- 229910052801 chlorine Chemical group 0.000 claims description 9
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-M ethanimidate Chemical compound CC([O-])=N DLFVBJFMPXGRIB-UHFFFAOYSA-M 0.000 claims description 3
- 238000004043 dyeing Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 239000000975 dye Substances 0.000 claims 6
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 2
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical group CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 claims 2
- 125000005041 acyloxyalkyl group Chemical group 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 125000004093 cyano group Chemical group *C#N 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 5
- -1 acetyloxyethyl groups Chemical group 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- QQBMCNRNUZBNNF-BZKIHGKGSA-L disodium;hexadecyl sulfate;[(z)-octadec-9-enyl] sulfate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O.CCCCCCCC\C=C/CCCCCCCCOS([O-])(=O)=O QQBMCNRNUZBNNF-BZKIHGKGSA-L 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000010979 ruby Substances 0.000 description 1
- 229910001750 ruby Inorganic materials 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
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- Coloring (AREA)
Description
Calosc podgrzewa sie wciagu 30-45 minut do temperatury 130-140° i barwi w tych warunkach w ciagu 1-1,5 godziny. Wybarwione wlókno plucze sie w wodzie, pierze w 20000 czesciach kapieli, zawierajacej 40 czesci podsiarczynu sodowego, 60 czesci 32% roztworu lugu sodowego i 20 czesci Preteponu G, w temperaturze 75-85° wciagu 15-30 minut, a nastepnie w goracej i zimnej wodzie z dodatkiem 1-2 czesci 30%kwasu_octowego. . • Otrzymuje sie równe i glebokie wybarwienie koloru granatowego o wybitnych odpornosciach na czynniki mokre swiatlo i obróbke cieplna.Przyklad II. Do 6000 czesci wody dodaje sie 3 czesci Dyspergatora NNO i dysperguje w tej kapieli 15 czesci mieszaniny, zawierajacej 5 czesci barwnika o ogólnym wzorze 1, w którym X oznacza grupe nitrowa, Y oznacza atom chloru, Z oznacza grupe etoksylowa, a R oznacza grupe metylowa i 10 czesci Dyspergatora NNO, 15 czesci mieszaniny, zawierajacej 5 czesci barwnika o ogólnym wzorze 2 w którym X oznacza grupe nitrowa, Y oznacza atom chloru, Z oznacza grupe metoksylowa, V oznacza grupe acetyloamidowa, a Rt i R2 oznaczaja grupy acetyloksyetylowe i 10 czesci Klutanu, 25 czesci mieszaniny, zawierajacej 8 czesci barwnika o ogólnym wzorze 2, w którym X i Y oznaczaja atomy chloru, Z i V oznaczaja atomy wodoru, Ri oznacza grupe acetylooksyetylowa, aR2 oznacza grupe 0-cyjanoetylowa i 17 czesci Klutanu oraz 15 czesci mieszaniny, zawierajacej 5 czesci barwnika o ogólnym wzorze 2, n którym X oznacza atom chloru, Y Z i V oznaczaja atomy wodoru, Rr oznacza grupe acetylooksyetylowa, a Ra oznacza grupe 0-cyjanoetylowa i 10 czesci Dyspergatora76 589 3 SS. Do otrzymanej w ten sposób zawiesiny dodaje sie 12 czesci 85% kwasu mrówkowego oraz 12 czesci siarczanu amonowego i barwi w tej kapieli 500 czesci wlókna poliestrowego w aparacie cisnieniowym sposobem, opisanym w przykladzie I.Otrzymuje sie glebokie i równe wybawienie koloru czarnego o bardzo dobrych odpornosciach na czynniki mokre, swiatlo, i obróbke cieplna.Przyklad III. 10 czesci pasty, zawierajacej 1,5 czesci barwnika o ogólnym wzorze 1, w którym X oznacza atom chloru i Y i Z oznaczaja atomy wodoru, a R oznacza grupe metylowa, 3 czesci Dyspergatora NNO i 5,5 czesci wody, miesza sie z 20 czesciami pasty, zawierajacej 3 czesci barwnika o ogólnym wzorze 2, w którym X oznacza atom chloru, Y V i Z oznaczaja atomy wodoru, Ri oznacza grupe acetylooksyetylowa, a R2 oznacza grupe j3-cyjanoetylowa, 3 czesci Dyspergatora SS i 14 czesci wody, w mlynie attritorowym w ciagu 5—7 godzin w celu uzyskania jednorodnej mieszaniny. Mieszanine past barwników rozciencza sie 6000 czesci wody, po czym barwi sie w otrzymanej kapieli 500 czesci wlókna poliestrowego w aparacie cisnieniowym sposobem, opisanym w przykladzie I.Otrzymuje sie wybarwienie koloru szkarlatnego o doskonalych odpornosciach na czynniki mokre i swiat¬ lo.Przyklad IV. W 6000 czesci wody dysperguje sie 5 czesci pasty, zawierajacej 0,75 czesci barwnika o ogólnym wzorze 1, w którym X oznacza grupe nitrowa YiZ oznaczaja atomy wodoru, a R oznacza grupe metylowa, 1,5 czesci Dyspergatora SS i 2,75 czesci wody oraz 25 czesci pasty, zawierajacej 3,75 czesci barwnika o ogólnym wzorze 2, w którym X oznacza grupe nitrowa, Y, Z i V oznaczaja atomy wodoru, Ri oznacza grupe etylowa, a R2 oznacza grupe 0-cyjanoetylowa. Przygotowana kapiela barwi sie 500 czesci wlókna poliestrowego w aparacie cisnieniowym sposobem, opisanym w przykladzie I.Otrzymuje sie równe i intensywne wybarwnienie koloru rubinowego odporne na swiatlo, czynniki mokre i obróbke cieplna. PL PLThe whole is heated in 30-45 minutes to a temperature of 130-140 ° and stained under these conditions for 1-1.5 hours. The dyed fiber is washed in water, washed in 20,000 parts of a bath containing 40 parts of sodium dithionite, 60 parts of 32% sodium hydroxide solution and 20 parts of Pretepon G, at 75-85 ° for 15-30 minutes, then hot and cold water with the addition of 1-2 parts of 30% acetic acid. . • An even and deep dark blue color is obtained with outstanding resistance to wet light and heat treatment. Example II. 3 parts of NNO Dispersant are added to 6000 parts of water and 15 parts of a mixture containing 5 parts of dye of general formula 1 are dispersed in this bath, where X is nitro, Y is chlorine, Z is ethoxy and R is methyl and 10 parts of NNO Dispersant, 15 parts of a mixture containing 5 parts of a dye of general formula 2 in which X is nitro, Y is chlorine, Z is methoxy, V is acetylamide, Rt and R2 are acetyloxyethyl groups and 10 parts Klutan, 25 parts of a mixture containing 8 parts of a dye of general formula 2, where X and Y are chlorine, Z and V are hydrogen, Ri is acetyloxyethyl, aR2 is 0-cyanoethyl and 17 parts of Klutan and 15 parts of mixture , containing 5 parts of a dye of general formula II, where X is chlorine, YZ and V are hydrogen, Rr is acetyloxyethyl and Ra is O-cyanoethyl and 10 parts of the Disperser 76 589 3 SS. 12 parts of 85% formic acid and 12 parts of ammonium sulphate are added to the suspension obtained in this way and 500 parts of polyester fiber are dyed in this bath in a pressure apparatus as described in example I. A deep and even black color with very good resistance is obtained. to wet factors, light and heat treatment. Example III. 10 parts of paste, containing 1.5 parts of a dye of general formula 1, where X is chlorine and Y and Z are hydrogen and R is methyl, 3 parts of NNO Dispersant and 5.5 parts of water are mixed with 20 parts of a paste containing 3 parts of a dye of general formula 2, in which X is chlorine, YV and Z are hydrogen, Ri is acetyloxyethyl and R2 is i3-cyanoethyl, 3 parts of SS Dispersant and 14 parts of water in the mill attritor for 5-7 hours in order to obtain a homogeneous mixture. The mixture of dye pastes is diluted with 6,000 parts of water, and then 500 parts of polyester fiber are dyed in the resulting bath in a pressure apparatus as described in example I. A scarlet-colored dyeing is obtained with excellent resistance to wet agents and light. Example IV. 5 parts of a paste are dispersed in 6000 parts of water, containing 0.75 parts of a dye of the general formula 1, where X is a nitro group, YiZ denote hydrogen atoms and R denotes a methyl group, 1.5 parts of SS Dispersant and 2.75 parts of water and 25 parts of a paste containing 3.75 parts of a dye of general formula II, where X is nitro, Y, Z and V are hydrogen, Ri is ethyl and R2 is O-cyanoethyl. The prepared bath is dyed with a pressure apparatus of 500 parts of polyester fiber using the method described in example 1. An even and intense ruby dye is obtained, resistant to light, wet agents and heat treatment. PL PL
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL12714968A PL76589B2 (en) | 1968-05-24 | 1968-05-24 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL12714968A PL76589B2 (en) | 1968-05-24 | 1968-05-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL76589B2 true PL76589B2 (en) | 1975-02-28 |
Family
ID=19950013
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL12714968A PL76589B2 (en) | 1968-05-24 | 1968-05-24 |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL76589B2 (en) |
-
1968
- 1968-05-24 PL PL12714968A patent/PL76589B2/pl unknown
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