PL737B1 - Method of obtaining alloys of metals, iron and chromium with silicon or its compounds - Google Patents
Method of obtaining alloys of metals, iron and chromium with silicon or its compounds Download PDFInfo
- Publication number
- PL737B1 PL737B1 PL737A PL73720A PL737B1 PL 737 B1 PL737 B1 PL 737B1 PL 737 A PL737 A PL 737A PL 73720 A PL73720 A PL 73720A PL 737 B1 PL737 B1 PL 737B1
- Authority
- PL
- Poland
- Prior art keywords
- metals
- iron
- silicon
- chromium
- alloys
- Prior art date
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 19
- 229910045601 alloy Inorganic materials 0.000 title claims description 9
- 239000000956 alloy Substances 0.000 title claims description 9
- 229910052742 iron Inorganic materials 0.000 title claims description 9
- 150000001875 compounds Chemical class 0.000 title claims description 7
- 229910052710 silicon Inorganic materials 0.000 title claims description 7
- 239000010703 silicon Substances 0.000 title claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title claims description 6
- 229910052804 chromium Inorganic materials 0.000 title claims description 4
- 239000011651 chromium Substances 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 4
- 229910052751 metal Inorganic materials 0.000 title claims 6
- 239000002184 metal Substances 0.000 title claims 6
- 150000002739 metals Chemical class 0.000 title claims 5
- 150000003377 silicon compounds Chemical class 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- -1 silicon metals Chemical class 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 229910000640 Fe alloy Inorganic materials 0.000 claims 1
- 206010026749 Mania Diseases 0.000 claims 1
- 238000012993 chemical processing Methods 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 230000035935 pregnancy Effects 0.000 claims 1
- 230000035484 reaction time Effects 0.000 claims 1
- 238000007670 refining Methods 0.000 claims 1
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Description
Skutecznym skladnikiem znanych stopów kwasotrwalych grupy zelaza i chromu z krzemem, t. j. temi czastkami, które wy¬ woluja odpornosc przeciwko kwasom, sa zwiazki krzemowe wymienionych grup. Ja¬ ko zwiazki krzemowe zelaizia sa, nip. 'znane: Fe2 Siy Fe, Si2, Fe Si i Fe Si2.Z tych zwiazków znajduje sie, np. w sto¬ pach zelaizo-krzemowych kwasoitrwalych i do¬ tychczas znanych kilka zwiazków równo- czesmiie, jiaik to mazana stwierdzic z&pomoca chemicznych i metalograifilciznych doswiad¬ czen. W znaczeniu odlewniczem i techniki formierskiej napotyka otrzymanie tych sto¬ pów, jak wiadomo, na liczne trudnosci. Od¬ lewy posiadaja tylko niewielka mechaniczna wytrzymalosc i pekaja bardzo czesto, przez ogromne skurczenie i wewnetrzne natezenie materjalu, juz podczas tezenia w formach.Ostatni sziczegól pociaga za soba podrozenie wyrobu w powaznym stopniu, zmuszajac do odrzucania braków.Wynalazca stwierdzil natomiast, ze obja¬ wy powyzsze spowodowane'sa równocizeisna zawartoscia zwiazków krzemowych, które pomiedzy soba wyfeaizuja powazne róznice w wartosciach skurcizeniaj i roizciaglosea. a prócz tego wywoluja, z powodu nieregu¬ larnego ulozemiaJ ich w „enteoticium" zelazo- krzemowym, uklad stopów tak ohenBczniie jako i mechaniczniie metaistiaibilny. Ta me- taistajbilmosc ukladiu dazy do stamru równo- wiajgi, wywolujac peikaoie odlewu albo juz poidcizais tezenia i situdizieoia., ailfbo tez np. podcziaJs pózniejszego rozgrzewania, któ¬ remu podlegaja Oidlewy bardzo czesto z po¬ wodu ich uzycia w przemysle1 chieniiicz- nyim. Stwierdzono nastepnie, ze moznausunac powyzej wyszczególnione trudno- chromowej, jak: chrom, wolfram itd.; krzem sci, jezeli stopy skiaidaija sie calkowicie, stosuje sie przytem z korzyscia w formie albo tez praewaznie, ze zwiazku krize- jego 'zwiazków jak: krzem zelaza, mangan mowego, jednolitego oraz iz- „teutecticuim", krzemowy 1 t, d. o ile to jest mozliwem do osiagniecia sto- chiometrycznie ze skladowych z uwzglednie- r r z y ik l a a. niem statyki chemicznej, oraz. jezeli nie do- Celem otrzymania 1000 kg stopu zeltajza. pusci sie do wytworzenia innych zwiazków o zawartosci 20°/0 krzemu, doprowadza sie krzemowych innego uklaldu. Zapomoca do- 780 kg zelaza, i 220 kg zelaza makrzemio- tychczas uzywanych i wchodzacych tu w ra- nego (90°/o) do reakcji wedlug podanego1 spo- chube sposobów topienia w kopniakach, pie- sobu, w ten sposób otrzymuje sie stop, który cach mairtenoskiich, elektrycznych i tu d. nie odpowiada jednolicie zwiazkowi krzemowe- mozna przeprowadzic w praktyce tych za- mu zelaza wedlug formuly Fe2 Si. sad, poniewaz podczas topienia odgrywa role przewaznie przebieg fizyiklalny, do tworze¬ nia natomiast zwiazków krzemowych prze- * ^ PLSilicon compounds of the groups mentioned are an effective component of the known acid-resistant alloys of the iron and chromium group with silicon, i.e. the particles which cause resistance to acids. As silicon compounds of irons are, nip. known: Fe2 Siy Fe, Si2, Fe Si and Fe Si2. These compounds are found, for example, in iron-silicon alloys and several compounds known at the same time, it is necessary to find out with the aid of chemical and metalogical experience. In the sense of the foundry and molding technique, it is known that obtaining these alloys is difficult to obtain. Castings have only a low mechanical strength and break very often, due to the tremendous shrinkage and internal material intensity, already during the thesis in the molds. The last of the casts entails a serious travel of the product, forcing one to reject the deficiencies. the above is due to the equality of the content of silicon compounds, which between them lead to significant differences in the values of contractions and complexities. and besides, they evolve, due to the irregular arrangement of them in the iron-silicon "entheoticium", a system of alloys that is as close as and mechanically metaistia-ineffective. ., but also, for example, during the subsequent heating, which Oidlewy is subject to very often due to their use in the Chinese industry. It was then found that the above-mentioned hard-chromium, such as chromium, tungsten, etc., can be removed; , if the alloys are completely skiaid, they are also used for the benefit of the form or also in the form of a kithium compound such as: iron silicon, speech manganese, homogeneous and is- "teutecticuim", silicon 1 t, d. it is possible to achieve stoichiometrically from the components including and la a. chemical statics, and. if not - To obtain 1000 kg of melt. is forced to produce other compounds with a content of 20% silicon, then silicon is fed to a different structure. Save up to 780 kg of iron, and 220 kg of macro iron, which are then used and entered here in the wound (90%) to react according to the given1 method of melting in the mines, in this way an alloy is obtained which mairtenoskiich, electric and here d. do not correspond uniformly to the silicon compound - in practice these iron chromas can be carried out according to the Fe2 Si formula. carbon black, because during melting it is usually the physical course that plays a role, while the formation of silicon compounds is
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL737B1 true PL737B1 (en) | 1924-10-31 |
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