PL66246B1 - - Google Patents
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- Publication number
- PL66246B1 PL66246B1 PL129229A PL12922968A PL66246B1 PL 66246 B1 PL66246 B1 PL 66246B1 PL 129229 A PL129229 A PL 129229A PL 12922968 A PL12922968 A PL 12922968A PL 66246 B1 PL66246 B1 PL 66246B1
- Authority
- PL
- Poland
- Prior art keywords
- weight
- parts
- flame
- candles
- torches
- Prior art date
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- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 8
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 6
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 3
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 3
- 229960004011 methenamine Drugs 0.000 claims description 3
- 239000004323 potassium nitrate Substances 0.000 claims description 3
- 235000010333 potassium nitrate Nutrition 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical class OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 4
- 229930040373 Paraformaldehyde Natural products 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 229920002866 paraformaldehyde Polymers 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 244000249914 Hemigraphis reptans Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- -1 boric acid glycol ester Chemical class 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- CKFGINPQOCXMAZ-UHFFFAOYSA-N methanediol Chemical compound OCO CKFGINPQOCXMAZ-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
Description
Opublikowano: 30.X.1972 66246 KI. 23d,3 MKP Cllc 5/00 UKD Wspóltwórcy wynalazku: Wiktor Klein, Adam Piatkowski, Jerzy West- fal, Ludwik Korona, Lucyna Rabinowicz, Cze¬ slaw Zukowski, Edmund Wolski Wlasciciel patentu: Chemiczny Osrodek Badawczy przy Wojewódzkim Zwiazku Spóldzielni Pracy, Kraków (Polska) Znicze i pochodnie palace sie barwnym plomieniem Przedmiotem wynalazku sa znicze i pochodnie palace sie barwnym plomieniem. Znane sa znicze i pochodnie, w których tworzywo palne stanowi tkanina nasycona weglowodorami parafinowymi.Znane sa równiez pochodnie i znicze, w których tworzywo palne stanowi mieszanina paraformalde- hydii i glikoli etylenowych, a jako substancje bar¬ wiace stosuje sie estry kwasu borowego i alkoholi wielowodorotlenowych, sole miedzi i cyny, sole so¬ dowe kwasów organicznych. Wada znanych zniczy i pochodni, w których tworzywo palne stanowia weglowodory parafinowe, jest zóltawy plomien sa¬ mych weglowodorów, a ponadto wydzielanie sie przy spalaniu nadmiernej ilosci sadzy i iskier.Wada znanych zniczy i pochodni, w których tworzywo palne stanowi mieszanina paraformalde- hydu i glikolu etylenowego, jest bardzo przykry zapach powstajacy przy rozkladzie paraformalde- hydu w czasie spalania oraz higroskopijnosc sklad¬ ników, a szczególnie glikolu etylenowego, co po¬ woduje trudnosc zapalenia znicza lub pochodni przy przechowywaniu ich w warunkach wilgotnych.Celem wynalazku jest otrzymanie zniczy i po¬ chodni, w których -tworzywo przy spalaniu nie wydziela zadnych przykrych zapachów oraz daje sie zapalic bez trudnosci, bez wzgledu na warunki przechowywania.Cel ten zostal osiagniety przez sprasowanie w rózne, ksztaltki szesciometylenoczteroaminy z do- 10 15 20 30 2 datkiem w ilosci 10 do 15 czesci wagowych zna¬ nych substancji barwiacych plomien oraz z do¬ datkiem w ilosci 1 do 2 czesci wagowych zwiaz¬ ków utleniajacych, takich jak azotan potasu lub azotan wapnia, które przez wydzielanie tlenu zwiekszaja barwny efekt plomienia oraz zmieniaja ilosc czesci niespalonych.Ponizej podano przyklady zniczy i pochodni pa¬ lacych sie plomieniem o róznej barwie.Przyklad I. Znicz lub pochodnia palace sie plomieniem zielonym: szescciometylenoczteroamina 100 czesci wagowych ester glikolowy kwasu borowego 12 czesci wagowych azotan wapnia . 1 czesc wagowa Przyklad II. Znicz lub pochodnia palace sie plomieniem czerwonym: szesciometylenoczteroamina 100 czesci wagowych weglanlitu 12,5 czesci wagowych azotan potasu 1 czesc wagowa PLPublished: October 30, 1972 66246 IC. 23d, 3 MKP Cllc 5/00 UKD Inventors of the invention: Wiktor Klein, Adam Piatkowski, Jerzy Westfal, Ludwik Korona, Lucyna Rabinowicz, Czefaw Zukowski, Edmund Wolski Patent proprietor: Chemical Research Center at the Provincial Union of Labor Cooperatives, Krakow ( Poland) Candles and torches burn with a colored flame The subject of the invention are candles and torches that burn with a colored flame. There are candles and flares in which the combustible material is a fabric saturated with paraffin hydrocarbons. There are also flares and torches in which the combustible material is a mixture of paraformaldehyde and ethylene glycols, and esters of boric acid and polyhydric alcohols are used as coloring substances. , copper and tin salts, sodium salts of organic acids. The disadvantage of known candles and torches, in which the combustible material is paraffinic hydrocarbons, is the yellowish flame of the hydrocarbons themselves, and moreover, the emission of excessive amounts of soot and sparks during combustion. The disadvantage of known candles and torches in which the fuel is a mixture of paraformaldehyde and ethylene glycol, there is a very unpleasant odor arising from the decomposition of paraformaldehyde during combustion, and the hygroscopic nature of the components, especially ethylene glycol, which makes it difficult to ignite a candle or torch when stored in humid conditions. - cold stores, in which - the material does not emit any unpleasant odors during combustion and can be ignited without difficulty, regardless of storage conditions. This goal was achieved by pressing into various shapes of hexamethylene tetraamine with an additional 10 15 20 30 2 up to 15 parts by weight of known flame dyes and with the addition of quantities of 1 to 2 parts by weight of oxidizing compounds, such as potassium nitrate or calcium nitrate, which by the evolution of oxygen increase the color effect of the flame and change the amount of unburned parts. Below are examples of candles and flares that burn with a flame of different color. Example I A torch or a torch burns with a green flame: hexamethylene tetramine 100 parts by weight boric acid glycol ester 12 parts by weight calcium nitrate. 1 part by weight Example II. A torch or a torch burns with a red flame: hexamethylene tetramine 100 parts by weight carbonite 12.5 parts by weight potassium nitrate 1 part by weight PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL66246B1 true PL66246B1 (en) | 1972-06-30 |
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