PL57397B1 - - Google Patents

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Publication number
PL57397B1
PL57397B1 PL120638A PL12063867A PL57397B1 PL 57397 B1 PL57397 B1 PL 57397B1 PL 120638 A PL120638 A PL 120638A PL 12063867 A PL12063867 A PL 12063867A PL 57397 B1 PL57397 B1 PL 57397B1
Authority
PL
Poland
Prior art keywords
petroleum coke
core
charge
crude petroleum
wet
Prior art date
Application number
PL120638A
Other languages
Polish (pl)
Inventor
inz. Miroslaw Lebiedziejewski mgr
inz.Maria Szudek mgr
inz. Janina Harmanowska mgr
inz. Bronislaw Zmudzinski mgr
inz. Sta¬nislaw Hulisz mgr
dr inz. Bohdan Kalinow¬ski prof.
inz. Rafal Wlodarski dr
Original Assignee
Zaklady Elektrod Weglowych „1 Maja"
Filing date
Publication date
Application filed by Zaklady Elektrod Weglowych „1 Maja" filed Critical Zaklady Elektrod Weglowych „1 Maja"
Priority to CS362168A priority Critical patent/CS157633B2/cs
Priority to FR1579577D priority patent/FR1579577A/fr
Publication of PL57397B1 publication Critical patent/PL57397B1/pl

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Description

W szczególnosci dobre wyniki uzyskuje sie jesli proces termicznego odsiarczania prowadzony jest 20 25 30 w sposób ciagly lub periodyczny w elektrycznym piecu oporowym, którego rdzen oporowy stanowi wilgotny surowy koks naftowy o granulacji do 40 mm. Rdzen ten charakteryzuje sie takim sto¬ sunkiem przekroju do dlugosci, ze stosunek sred¬ nicy ekwiwalentnej rdzenia do jego dlugosci wy¬ nosi 1 : 3 do 1 : 10.Proces prowadzi sie tak by gestosci pradowe w rdzeniu miescily sie w zakresie 3—7 A/cm2 w strefie maksymalnej temperatury. Okres czasu przebywania koksu w tej strefie uzalezniony jest od zawartosci siarki w surowcu wstepnym lub wymagana zawartoscia siarki w produkcie kon¬ cowym i wynosi 2—5 h.Opisany w zgloszeniu proces zapewnia uzyska¬ nie kalcynowanego koksu naftowego o zawar¬ tosci siarki ponizej dopuszczalnej w przemysle elektrodowym normy, cechujacego sie niska opor¬ noscia wlasciwa i wysokim ciezarem rzeczywi¬ stym, przy czym jego wytrzymalosc mechaniczna jest nie nizsza niz uzyskiwana w tym samym za¬ kresie temperatur przy kalcynacji gazowej. PLIn particular, good results are obtained if the thermal desulphurization process is carried out continuously or batchwise in an electric resistance furnace, the resistance core of which is wet crude petroleum coke with a grain size of up to 40 mm. This core is characterized by such a cross-section to length ratio that the ratio of the core's equivalent diameter to its length is 1: 3 to 1:10. The process is carried out so that the current densities in the core are in the range of 3 to 7 A / cm2 in the maximum temperature zone. The residence time of coke in this zone depends on the sulfur content in the initial raw material or the required sulfur content in the final product, and amounts to 2 - 5 hours. The process described in the application provides for obtaining calcined petroleum coke with a sulfur content below the permissible standard electrode industry, characterized by low specific resistance and high real weight, and its mechanical strength is not lower than that obtained in the same temperature range by gas calcination. PL

Claims (1)

1. Zastrzezenie patentowe Sposób usuwania siarki z surowego koksu naf¬ towego, znamienny tym, ze wilgotny surowy koks naftowy, zawierajacy 5—10% czesci lotnych i 0,5— 10% wilgoci poddaje sie dzialaniu pola elektrycz¬ nego w sposób ciagly lub periodyczny w urza¬ dzeniu, w którym wilgotny surowy koks naftowy stanowi rdzen oporowy o takich wymiarach, ze stosunek srednicy ekwiwalentnej rdzenia do dlu¬ gosci wynosi 1:3 do 1 :10, a gestosci pradowe mieszcza sie w czasie utrzymywania wsadu w okreslonej temperaturze w zakresie 3—7 A/cm2, przy czym czas przebywania wsadu w tempera¬ turze maksymalnej 1400° wynosi 2—5 godzin. Zaklady Kartograficzne — C/144, 240 PLClaim 1. A method of removing sulfur from crude petroleum coke, characterized in that wet crude petroleum coke containing 5-10% volatile parts and 0.5-10% moisture is subjected to the action of an electric field continuously or periodically in a device where the wet raw petroleum coke is a resistance core of such dimensions that the ratio of the equivalent diameter of the core to length is 1: 3 to 1: 10, and the current densities are within the time the charge is kept at a certain temperature in the range 3 to 7 A / cm 2, the residence time of the charge at a maximum temperature of 1400 ° is 2 to 5 hours. Zaklady Kartograficzne - C / 144, 240 PL
PL120638A 1967-05-19 1967-05-19 PL57397B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CS362168A CS157633B2 (en) 1967-05-19 1968-05-17
FR1579577D FR1579577A (en) 1967-05-19 1968-05-20

Publications (1)

Publication Number Publication Date
PL57397B1 true PL57397B1 (en) 1969-02-26

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