PL564B1 - The method of preparation of vegetable fibers for the pre-cutting and paper industries. - Google Patents

The method of preparation of vegetable fibers for the pre-cutting and paper industries. Download PDF

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Publication number
PL564B1
PL564B1 PL564A PL56420A PL564B1 PL 564 B1 PL564 B1 PL 564B1 PL 564 A PL564 A PL 564A PL 56420 A PL56420 A PL 56420A PL 564 B1 PL564 B1 PL 564B1
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PL
Poland
Prior art keywords
water
preparation
kerosene
fibers
paper industries
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Application number
PL564A
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Polish (pl)
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Publication date
Application filed filed Critical
Publication of PL564B1 publication Critical patent/PL564B1/en

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KI. 29 b 5.Wynalazek dotyczy sposobu przygo¬ towywania roslinnych wlókien dla prze- ¦ dzalnictwa i papiernictwa. Sposób prze¬ widuje dla tego celu zastosowanie na¬ stepujacych 5 odczynników, dotychczas jeszcze nie uzywanych: Dwuchloroetylenu . . . C2H2C12 Nadchloroetylenu. . . . C2 Cl4 Trójchloroetylenu . . . C2H Cl3 Czworochloroetanu . . C2 H2 Cl4 Pieciochloroetanu . . . C2 H Cl5.Giala te mozna uzywac pojedynczo, albo w mieszaninie wzajemnej dla obrabiania surowców wlóknistych.Bylo juz proponowane uzywanie nie¬ których ze wspomnianych srodków np., do odtluszczania welny, albo do usuwa¬ nia plam z materjalów, ale dotychczas nigdzie nie stosowano ich do preparo¬ wania wlókien roslinnych.Znane jest juz obrabianie roslinnych materji chlorowanemi weglowodorami przy wysokich temperaturach. Sposób ten nie mial jednakze na celu przygoto¬ wania materji jak np., bawelny, albo tez welny dla przedzalnictwa, albo papier¬ nictwa. Temperatury stosowane przy tym sposobie (70° C) nie sa zreszta do¬ statecznie wysokie, aby osiagnac dziala¬ nie (które zreszta nie bylo zamierzone) przewidziane w niniejszym wynalazku.Proponowano takze do oczyszczania wló¬ kien uzyc niektórych cial weglowodoro¬ wych np. nafty.Niniejszy wynalazek stwierdza nowe spostrzezenie, ze chlorowane weglowo¬ dory zupelnie nadaja sie do przeprowa¬ dzenia reakcji, zachodzacych w tym wy¬ padku. Te chlorowane pochodne roz¬ puszczaja nietylko tluszcze, oleje, zywi-ce, ale tez i inne skladniki wlókien ro- wytwarzajacego emulsje, jak np., rozcien^ slinnych, wystawianych na ich dzialanie, czone roztwory mydla, oleiste emulsje tak predko i gruntownie, ze osiaga sie i t. p., za taki uznano równiez wode za- w stosunkowo krótkim czasie zupelne wierajaca 3% nafty. W tak otrzyma- oczyszczenie.Próby wykazaly, ze wlókna dla fabry¬ kacji papieru, traktowane wedlug wyna¬ lazku chlorowanemi weglowodorami, do¬ brze sie rozdzielaly i dawaly materjal latwo dajacy sie zemlec. Przygotowa¬ niem wlókien wedlug sposobu zglosze¬ nia osiaga sie te korzysc, w porównaniu ze sposobem, gdzie pracuje sie niechlo- rowanemi weglowodorami, ze obce ciala z wlókien zupelnie sa usuwane. nym plynie ogrzewa sie surowiec w za- mknietem naczyniu do wysokiej tempe¬ ratury.Nie da sie oznaczyc dokladnie zgóry w jakich ilosciach trzeba uzyc rozpuszczal¬ nika, mozna jednak stosowac do 10% na wage traktowanego surowca. Takze temperatura, uzyte cisnienie i czas trwa¬ nia traktowania wahaja sie od przypad¬ ku do przypadku.Najlepsze warunki roboty, które moz- Wyjasnia sie to tak, ze w znanym na ustanowic w kazdym pojedynczym sposobie skladniki tworzace skorupe przypadku, wynikaja z rodzaju surowca^ wprawdzie rozpuszczaja sie, ale trudno z wieku traktowanych roslin, z czasu, jest pozbyc sie z wlókna emulsji we- który uplynal od sciecia tychze i t. p. glowodorowej, zawierajacej jeszcze bez watpienia rozpuszczone skladniki two¬ rzace skorupe.Postepujac jednak wedlug tego wy¬ nalazku mozna latwo otrzymac zupelnie PLKI. 29b 5. The invention relates to a method of preparing vegetable fibers for the purpose of processing and papermaking. For this purpose, the method provides for the use of the following reagents, hitherto not used: dichloroethylene. . . C2H2C12 Perchlorethylene. . . . C2 Cl4 Trichlorethylene. . . C2H Cl3 Tetrachloroethane. . C2 H2 Cl4 Pichchloroethane. . . C2 H Cl5. These gels can be used individually or in a cross-mixture for the treatment of fibrous raw materials. It has already been proposed to use some of the above-mentioned agents, for example, for degreasing wool or for removing stains from materials, but so far has not been used. They are used for the preparation of vegetable fibers. It is already known to treat plant matter with chlorinated hydrocarbons at high temperatures. This method was not, however, intended to prepare a matter such as, for example, cotton or wool for pre-folding or papermaking. The temperatures used in this process (70 ° C.) are not, moreover, high enough to achieve the action (which, moreover, was not intended) as envisaged in the present invention. It has also been proposed to use certain hydrocarbon bodies for cleaning the fibers, e.g. kerosene. The present invention provides a new insight that chlorinated hydrocarbons are perfectly suitable for carrying out the reactions which take place in this case. These chlorinated derivatives dissolve not only fats, oils, and nourishing substances, but also other components of the emulsifying fibers, such as, for example, the diluted saline exposed to them, combined soap solutions, oily emulsions so quickly and thoroughly, that there is also tp, water was also considered as such in a relatively short time, completely containing 3% of kerosene. In this way, the purification was obtained. Trials showed that the fibers for the manufacture of paper, treated according to the invention with chlorinated hydrocarbons, separated well and gave a material that could be easily chipped. The preparation of the fibers according to the filing method has these advantages, compared to the method where non-chlorinated hydrocarbons are used, that the foreign bodies in the fibers are completely removed. With this liquid, the raw material is heated in a sealed vessel to a high temperature. It is not possible to determine exactly in what amounts the solvent should be used, but it is possible to use up to 10% by weight of the raw material treated. Also the temperature, the pressure used, and the duration of the treatment vary from case to case. The best working conditions that can be explained are that in each individual method the ingredients that make up the shell of a case are known to establish the shell-forming components of the case, resulting from the nature of the raw material. Although they dissolve, it is difficult for the age of the plants to be treated, with time it is difficult to get rid of the fiber of the emulsion that has drained from the cutting of these and other hydrocarbons, which still undoubtedly contains dissolved ingredients forming a crust. you can get completely PL

Claims (3)

Zastrzezenia patentowe. 1. Sposób przygotowania wlókien ro¬ slinnych dla przemyslu przedzalniczego i papierniczego, tern znamienny, ze su- oczyszczone wlókna. Zjawisko to pole- rowiec traktuje sie w otwartych, albo ga czesciowo na znanej samej przez sie zamknietych naczyniach plynem, sklada- wiekszej zdolnosci rozpuszczania przez jacym sie z dwuchloroetylenu, trójchlo- chlorowane pochodne tluszczów i olei. Inna przyczyna zachodzacych tu dzia¬ lan jest ta, ze pochodne chlorowane roz¬ dzielaja sie dokladniej w wodzie niz nafta i weglowodory. Wskutek tego osia¬ gaja wplyw zupelnie drobne kropelki roetylenu, nadchloroetylenu, czworochlo- roetanu, pieciochloroetanu dodanych po¬ jedynczo, albo w mieszaninie wzajemnej do czystej wody.Patent claims. 1. Method for the preparation of vegetable fibers for the pre-mashing and paper industries, characterized by the use of dried fibers. This phenomenon is treated in open or partially on a self-known closed vessel with a liquid that has a greater dissolving power due to a mixture of dichloroethylene, trichlorinated derivatives of fats and oils. Another reason for the action taking place here is that the chlorinated derivatives are more finely divided in water than kerosene and hydrocarbons. As a result, completely fine droplets of roethylene, perchlorethylene, tetrachloroethane, pentachloroethane are influenced either individually or in a mixture with pure water. 2. Sposób wykonania sposobu we¬ dlug zastrz. 1, tern znamienny, ze uzy- rozpuszczalnika tak, ze osiaga sie silniej- wa sie rozpuszczalnika nie w czystej sze dzialanie. wodzie, ale w roztworze mydla, lub Metode niniejszego zgloszenia prze- w oleistych emulsjach, prowadza sie nastepujaco: jeden, albo2. The method of carrying out the method according to claim The method of claim 1, characterized by the fact that the solvent is used more strongly than purely for action. in water but in a soap solution, or The method of this declaration in oily emulsions, is carried out as follows: one, or 3. Sposób wykonania sposobu we- wiecej powyzej wspomnianych skladni- dlug zastrz. 1, tern znamienny, ze do ków daje sie do wody, albo do plynu, wody dodaje sie 3% nafty. Societe Anonyme des Brevets Peufaillit Zastepca: M. Kryzan, rzecznik patentowy. ZAKl.GRAF.KOZIANSKICH W WARSZAWIE PL3. A method for carrying out a method according to the above-mentioned components of claim 1, a tern characterized by the fact that 3% kerosene is added to the water or the liquid. Societe Anonyme des Brevets Peufaillit Deputy: M. Kryzan, patent attorney. KOSIANSKI GRAPHICS DEPARTMENT IN WARSAW PL
PL564A 1920-06-25 The method of preparation of vegetable fibers for the pre-cutting and paper industries. PL564B1 (en)

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PL564B1 true PL564B1 (en) 1924-09-30

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