PL446044A1 - Krystaliczna forma związku koordynacyjnego di hydrat bromku [(2-amino 5-guanidynopentano)bromo(2,2'-dipirydylo)miedzi(II)], sposób jej wytwarzania oraz zastosowanie - Google Patents

Krystaliczna forma związku koordynacyjnego di hydrat bromku [(2-amino 5-guanidynopentano)bromo(2,2'-dipirydylo)miedzi(II)], sposób jej wytwarzania oraz zastosowanie

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Publication number
PL446044A1
PL446044A1 PL446044A PL44604423A PL446044A1 PL 446044 A1 PL446044 A1 PL 446044A1 PL 446044 A PL446044 A PL 446044A PL 44604423 A PL44604423 A PL 44604423A PL 446044 A1 PL446044 A1 PL 446044A1
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PL
Poland
Prior art keywords
copper
bromo
amino
crystalline form
coordination compound
Prior art date
Application number
PL446044A
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English (en)
Inventor
Agnieszka Wojciechowska
Magdalena Fitta
Zuzanna Walkowiak
Original Assignee
Politechnika Wrocławska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Politechnika Wrocławska filed Critical Politechnika Wrocławska
Priority to PL446044A priority Critical patent/PL446044A1/pl
Publication of PL446044A1 publication Critical patent/PL446044A1/pl

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/08Copper compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C277/00Preparation of guanidine or its derivatives, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
    • C07C277/08Preparation of guanidine or its derivatives, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups of substituted guanidines
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C279/00Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
    • C07C279/04Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of guanidine groups bound to acyclic carbon atoms of a carbon skeleton
    • C07C279/14Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of guanidine groups bound to acyclic carbon atoms of a carbon skeleton being further substituted by carboxyl groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C07D213/22Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing two or more pyridine rings directly linked together, e.g. bipyridyl

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Zgłoszenie dotyczy krystalicznej formy związku koordynacyjnego di hydrat bromku [(2-amino-5-guanidynopentano)bromo(2,2'-dipirydylo)miedzi(II)], o wzorze 1 oraz jego zastosowania jako materiał spektroskopowy i magnetyczny. Wynalazek zapewnia również sposób wytwarzania krystalicznej formy związku koordynacyjnego di hydrat bromku [(2-amino-5-guanidynopentano)bromo(2,2'dipirydylo)miedzi(II)], o wzorze 1, który charakteryzuje się tym, że jedną część molową soli bromku miedzi(II), rozpuszcza się w wodzie i poddaje się reakcji z jedną lub dwoma częściami molowymi wodnego roztworu L-argininy oraz jedną częścią molową metanolowego roztworu 2,2'-bipirydylu.
PL446044A 2023-09-07 2023-09-07 Krystaliczna forma związku koordynacyjnego di hydrat bromku [(2-amino 5-guanidynopentano)bromo(2,2'-dipirydylo)miedzi(II)], sposób jej wytwarzania oraz zastosowanie PL446044A1 (pl)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL446044A PL446044A1 (pl) 2023-09-07 2023-09-07 Krystaliczna forma związku koordynacyjnego di hydrat bromku [(2-amino 5-guanidynopentano)bromo(2,2'-dipirydylo)miedzi(II)], sposób jej wytwarzania oraz zastosowanie

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL446044A PL446044A1 (pl) 2023-09-07 2023-09-07 Krystaliczna forma związku koordynacyjnego di hydrat bromku [(2-amino 5-guanidynopentano)bromo(2,2'-dipirydylo)miedzi(II)], sposób jej wytwarzania oraz zastosowanie

Publications (1)

Publication Number Publication Date
PL446044A1 true PL446044A1 (pl) 2025-03-10

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Application Number Title Priority Date Filing Date
PL446044A PL446044A1 (pl) 2023-09-07 2023-09-07 Krystaliczna forma związku koordynacyjnego di hydrat bromku [(2-amino 5-guanidynopentano)bromo(2,2'-dipirydylo)miedzi(II)], sposób jej wytwarzania oraz zastosowanie

Country Status (1)

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PL (1) PL446044A1 (pl)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL431215A1 (pl) * 2019-09-19 2020-05-18 Politechnika Wrocławska Krystaliczna forma kompleksu azydek bis(L-arginina)chloromiedzi(Il)bis(L-arginina) diazydomiedź(II) hydrat 1/7 i sposób jej wytwarzania

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL431215A1 (pl) * 2019-09-19 2020-05-18 Politechnika Wrocławska Krystaliczna forma kompleksu azydek bis(L-arginina)chloromiedzi(Il)bis(L-arginina) diazydomiedź(II) hydrat 1/7 i sposób jej wytwarzania

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
BACAREA, P. ET AL: "Rev. Chim. 63 (2012) 489-494", "CHIRAL SELECTIVITY IN THE BASIC OR ACID Α AMINO ACIDS HOMOMERIC CU(II) COMPLEXES RANGE" *
HIDEKI MASUDA AKIRA ODANI TAKAYASU YAMAZAKI TATSUO YAJIMA OSAMU YAMAUCHI: "Inorg. Chem. (1993), 32, (7), 1111–1118", "STRUCTURES AND STABILITIES OF TERNARY COPPER(II) COMPLEXES CONTAINING AN ACIDIC AND A BASIC AMINO ACID. EVIDENCE FOR ARGININE SIDE CHAIN INVOLVEMENT IN INTERMOLECULAR INTERACTIONS AND ITS BIOLOGICAL IMPLICATION", *
MOTOHARU TANAKA, MASAAKI TABATA: "Inorg. Chem. 2007, 46, 23, 9975–9978", "AN ATTEMPT TO DISCRIMINATE BETWEEN THE HYDROPHOBIC AND AROMATIC Π−Π INTERACTIONS IN THE COPPER(II) TERNARY COMPLEXES CULA WITH L = 1,10-PHENANTHROLINE OR 2,2‘-BIPYRIDYL AND A = PARA-X-SUBSTITUTED PHENYLALANINATES" *

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