PL445789A1 - Polimery pełniące rolę membran anionowymiennych oparte o 9,10-dihydroakrydynę - Google Patents
Polimery pełniące rolę membran anionowymiennych oparte o 9,10-dihydroakrydynęInfo
- Publication number
- PL445789A1 PL445789A1 PL445789A PL44578923A PL445789A1 PL 445789 A1 PL445789 A1 PL 445789A1 PL 445789 A PL445789 A PL 445789A PL 44578923 A PL44578923 A PL 44578923A PL 445789 A1 PL445789 A1 PL 445789A1
- Authority
- PL
- Poland
- Prior art keywords
- group
- anion exchange
- exchange functional
- reaction
- aryl
- Prior art date
Links
- HJCUTNIGJHJGCF-UHFFFAOYSA-N 9,10-dihydroacridine Chemical compound C1=CC=C2CC3=CC=CC=C3NC2=C1 HJCUTNIGJHJGCF-UHFFFAOYSA-N 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 4
- 239000003011 anion exchange membrane Substances 0.000 title 1
- 238000005349 anion exchange Methods 0.000 abstract 4
- 125000000524 functional group Chemical group 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000003277 amino group Chemical group 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- BMTADKZCRRGXRW-UHFFFAOYSA-N C1C=CC=C1.[CH-]1C=CC=C1.[Co+2] Chemical group C1C=CC=C1.[CH-]1C=CC=C1.[Co+2] BMTADKZCRRGXRW-UHFFFAOYSA-N 0.000 abstract 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical group NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical group C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical group [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 abstract 2
- 125000001188 haloalkyl group Chemical group 0.000 abstract 2
- 125000002883 imidazolyl group Chemical group 0.000 abstract 2
- 125000001841 imino group Chemical group [H]N=* 0.000 abstract 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 abstract 2
- 125000005496 phosphonium group Chemical group 0.000 abstract 2
- 125000004076 pyridyl group Chemical group 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 125000000950 dibromo group Chemical group Br* 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000003930 superacid Substances 0.000 abstract 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D219/00—Heterocyclic compounds containing acridine or hydrogenated acridine ring systems
- C07D219/02—Heterocyclic compounds containing acridine or hydrogenated acridine ring systems with only hydrogen, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D219/00—Heterocyclic compounds containing acridine or hydrogenated acridine ring systems
- C07D219/14—Heterocyclic compounds containing acridine or hydrogenated acridine ring systems with hydrocarbon radicals, substituted by nitrogen atoms, attached to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
- C08G2/18—Copolymerisation of aldehydes or ketones
- C08G2/26—Copolymerisation of aldehydes or ketones with compounds containing carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/12—Copolymers
- C08G2261/122—Copolymers statistical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/14—Side-groups
- C08G2261/149—Side-chains having heteroaromatic units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
- C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
- C08G2261/3241—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more nitrogen atoms as the only heteroatom, e.g. carbazole
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
- C08G2261/334—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing heteroatoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Przedmiotem zgłoszenia jest polimer Wzór 1 o wzorze ogólnym, gdzie R1, R2 są łańcuchami oznacza aryl albo prostą lub rozgałęzioną grupę alkilową, arylową, perfluoroalkilową, halogenoalkilową, halogenoarylową (C=1—20) z zastrzeżeniem, iż R1, R2 mogą jednocześnie być takimi samymi bądź różnymi od siebie grupami, R3 to prosta grupa alkilowa, R4 może oznaczać grupę alkilową, arylową, perfluoroalkilową, halogenoalkilową, halogenoarylową, w tym grupę zawierającą aminę lub sól amoniową, a także grupę amoniową, grupę aminową, grupę iminową, grupę sulfoniową, grupę fosfoniową, grupę pirydylową, grupę karbazolową, grupę imidazolową, grupę guanidyniową, grupę rutenową, grupę kobaltoceniową, dowolną jedną lub większą liczbę anionowymiennych grup funkcyjnych wybranych z grupy piperydyniowej lub anionowymienną grupę funkcyjną w jej stanie soli(C=1—20), Q oznacza niezależnie grupę aminową, grupę amoniową, grupę aminową, grupę iminową, grupę sulfoniową, grupę fosfoniową, grupę pirydylową, grupę karbazolową, grupę imidazolową, grupę guanidyniową, grupę rutenową, grupę kobaltoceniową, dowolną jedną lub większą liczbę anionowymiennych grup funkcyjnych wybranych z grupy piperydyniowej lub anionowymienną grupę funkcyjną w jej stanie soli. W polimerze tym liczby merów: n, m, o są liczbami w zakresie 0-1, najlepiej gdy n=m=o. Zgłoszenie obejmuje też sposób wytwarzania polimeru Wzór 1 poprzez reakcję polihydroksyalkilacji, znamienny tym, że reakcja jest przeprowadzana przy użyciu superkwasu, gdzie przykładem jest kwas trifliowy. W warunkach temperatur w zakresie -78 do 40 st. Celsjusza. Przedmiotem zgłoszenia jest też sposób wytwarzania monomerów typu m i o, znamienny tym, że reakcja przeprowadzana jest w temperaturze -40 - 120 stopni, gdzie zwykle jest to temperatura wrzenia rozpuszczalnika, przy użyciu rozpuszczalnika typu aceton lub toluen i udziale dibromopochodnej w stosunku 1-20 krotnie większym do użytej 9,10-dihydroakrydyny.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL445789A PL445789A1 (pl) | 2023-08-08 | 2023-08-08 | Polimery pełniące rolę membran anionowymiennych oparte o 9,10-dihydroakrydynę |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL445789A PL445789A1 (pl) | 2023-08-08 | 2023-08-08 | Polimery pełniące rolę membran anionowymiennych oparte o 9,10-dihydroakrydynę |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL445789A1 true PL445789A1 (pl) | 2025-02-10 |
Family
ID=94479918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL445789A PL445789A1 (pl) | 2023-08-08 | 2023-08-08 | Polimery pełniące rolę membran anionowymiennych oparte o 9,10-dihydroakrydynę |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL445789A1 (pl) |
-
2023
- 2023-08-08 PL PL445789A patent/PL445789A1/pl unknown
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