PL442739A1 - Combustion modifier of solid, liquid and gaseous fuels and how to modify the combustion process - Google Patents
Combustion modifier of solid, liquid and gaseous fuels and how to modify the combustion processInfo
- Publication number
- PL442739A1 PL442739A1 PL442739A PL44273922A PL442739A1 PL 442739 A1 PL442739 A1 PL 442739A1 PL 442739 A PL442739 A PL 442739A PL 44273922 A PL44273922 A PL 44273922A PL 442739 A1 PL442739 A1 PL 442739A1
- Authority
- PL
- Poland
- Prior art keywords
- amount
- modifier
- oxide nanoparticles
- mixture
- combustion
- Prior art date
Links
- 239000003607 modifier Substances 0.000 title abstract 5
- 238000002485 combustion reaction Methods 0.000 title abstract 4
- 239000007788 liquid Substances 0.000 title abstract 3
- 239000000446 fuel Substances 0.000 title 1
- 239000007787 solid Substances 0.000 title 1
- 239000002105 nanoparticle Substances 0.000 abstract 5
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000004094 surface-active agent Substances 0.000 abstract 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 abstract 1
- 229940084778 1,4-sorbitan Drugs 0.000 abstract 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 abstract 1
- 238000005054 agglomeration Methods 0.000 abstract 1
- 230000002776 aggregation Effects 0.000 abstract 1
- 229910000420 cerium oxide Inorganic materials 0.000 abstract 1
- 239000003245 coal Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000008034 disappearance Effects 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 150000002605 large molecules Chemical class 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 229940031182 nanoparticles iron oxide Drugs 0.000 abstract 1
- 229910000480 nickel oxide Inorganic materials 0.000 abstract 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 239000004449 solid propellant Substances 0.000 abstract 1
- 239000001593 sorbitan monooleate Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 238000010186 staining Methods 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
Wielofunkcyjny modyfikator spalania paliw stałych zawiera w swoim składzie frakcję naftową w zakresie destylacji od 170 do 380°C, temperaturze zapłonu 70°C w ilości 10 – 50% (m/m), korzystnie 30 – 50% (m/m) i/lub mieszaniny 2 etyloheksanolu oraz związków wysokocząsteczkowych (>C9) z produkcji 2 etyloheksanolu w ilości 10 – 50% (m/m), korzystnie 20 - 30% (m/m) i/lub nanocząstki tlenku żelaza w ilości od 0,1 do 20% (m/m), korzystnie 1 do 15% (m/m) i/lub nanocząstki tlenku ceru w ilości 0,1 do 20% (m/m), korzystnie od 0,5 do 10% (m/m) i/lub nanocząstki tlenku magnezu w ilości od 0,1 do 3% (m/m), korzystnie od 0,5 do 2% (m/m) i/lub nanocząstki tlenku niklu w ilości 0,1 do 15% (m/m), korzystnie 1 do 10% (m/m) i/lub 0,1 do 0,5% (m/m) monooleinianu 1,4 sorbitanu rozpuszczonego w toluenie, korzystnie 0,2 do 0,4% (m/m) i/lub 0,1 do 0,3% (m/m) propoksylowany dodecylofenol jako środek zapobiegający akumulacji osadów, dyspergujący i emulgujący. Mieszanina modyfikatora ma formę koloidalnej zawiesiny nanocząstek w cieczy nośnej np. w oleju czy węglowodorach. Do mieszaniny tej dodaje się związki powierzchniowo czynne (surfaktanty). Właściwości dielektryczne surfaktantu i cieczy nośnej są tak dobierane, aby były do siebie zbliżone, co powoduje zanik oddziaływań van der Waalsa między cząsteczkami i w rezultacie brak aglomeracji nanocząstek tlenków metali. Dozowanie modyfikatora do kotła węglowego odbywa się poprzez natrysk na węgiel i/lub wtrysk modyfikatora do powietrza pierwotnego lub wtórnego przez pole magnetyczne utworzone przy pomocy magnesów zamontowanych na rurociągach dolotowych powietrza do komory spalania o własnościach magnetycznych.The multifunctional solid fuel combustion modifier contains petroleum fraction in the distillation range from 170 to 380°C, ignition temperature 70°C in an amount of 10 - 50% (m/m), preferably 30 - 50% (m/m) and/ or a mixture of 2 ethylhexanol and high molecular weight compounds (>C9) from the production of 2 ethylhexanol in an amount of 10 - 50% (m/m), preferably 20 - 30% (m/m) and/or iron oxide nanoparticles in an amount from 0.1 to 20% (m/m), preferably 1 to 15% (m/m) and/or cerium oxide nanoparticles in an amount of 0.1 to 20% (m/m), preferably from 0.5 to 10% (m/m ) and/or magnesium oxide nanoparticles in an amount of 0.1 to 3% (m/m), preferably 0.5 to 2% (m/m) and/or nickel oxide nanoparticles in an amount of 0.1 to 15% ( m/m), preferably 1 to 10% (m/m) and/or 0.1 to 0.5% (m/m) of 1,4-sorbitan monooleate dissolved in toluene, preferably 0.2 to 0.4% ( m/m) and/or 0.1 to 0.3% (m/m) propoxylated dodecylphenol as an anti-staining, dispersing and emulsifying agent. The modifier mixture takes the form of a colloidal suspension of nanoparticles in a carrier liquid, e.g. oil or hydrocarbons. Surface-active compounds (surfactants) are added to this mixture. The dielectric properties of the surfactant and the carrier liquid are selected to be similar to each other, which results in the disappearance of van der Waals interactions between the particles and, as a result, no agglomeration of metal oxide nanoparticles. The modifier is dosed into a coal-fired boiler by spraying the coal and/or injecting the modifier into the primary or secondary air through a magnetic field created by magnets mounted on the air intake pipelines to the combustion chamber with magnetic properties.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL442739A PL442739A1 (en) | 2022-11-03 | 2022-11-03 | Combustion modifier of solid, liquid and gaseous fuels and how to modify the combustion process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL442739A PL442739A1 (en) | 2022-11-03 | 2022-11-03 | Combustion modifier of solid, liquid and gaseous fuels and how to modify the combustion process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL442739A1 true PL442739A1 (en) | 2024-05-06 |
Family
ID=90971210
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL442739A PL442739A1 (en) | 2022-11-03 | 2022-11-03 | Combustion modifier of solid, liquid and gaseous fuels and how to modify the combustion process |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL442739A1 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL410028A1 (en) * | 2014-11-03 | 2016-05-09 | Instytut Nafty I Gazu - Państwowy Instytut Badawczy | Improving agent for biogenic solid fuels, improving their performance properties |
| PL421754A1 (en) * | 2017-05-30 | 2018-12-03 | Tomaszek Bogdan | Modifying agent for burning liquid fuels such as pyrolysis oils, oils from tyre thermolysis and refinery residual oils |
-
2022
- 2022-11-03 PL PL442739A patent/PL442739A1/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL410028A1 (en) * | 2014-11-03 | 2016-05-09 | Instytut Nafty I Gazu - Państwowy Instytut Badawczy | Improving agent for biogenic solid fuels, improving their performance properties |
| PL421754A1 (en) * | 2017-05-30 | 2018-12-03 | Tomaszek Bogdan | Modifying agent for burning liquid fuels such as pyrolysis oils, oils from tyre thermolysis and refinery residual oils |
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