PL441555A1 - Magnesium-glass laminate and method of its production - Google Patents

Magnesium-glass laminate and method of its production

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Publication number
PL441555A1
PL441555A1 PL441555A PL44155522A PL441555A1 PL 441555 A1 PL441555 A1 PL 441555A1 PL 441555 A PL441555 A PL 441555A PL 44155522 A PL44155522 A PL 44155522A PL 441555 A1 PL441555 A1 PL 441555A1
Authority
PL
Poland
Prior art keywords
thickness
magnesium
layer
glass fibers
glass laminate
Prior art date
Application number
PL441555A
Other languages
Polish (pl)
Other versions
PL243793B1 (en
Inventor
Monika Ostapiuk
Jarosław Bieniaś
Patryk Jakubczak
Original Assignee
Politechnika Lubelska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Politechnika Lubelska filed Critical Politechnika Lubelska
Priority to PL441555A priority Critical patent/PL243793B1/en
Publication of PL441555A1 publication Critical patent/PL441555A1/en
Publication of PL243793B1 publication Critical patent/PL243793B1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/092—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B18/00—Layered products essentially comprising ceramics, e.g. refractory products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/12—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B32B2260/023—Two or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/762—Self-repairing, self-healing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)

Abstract

Przedmiotem wynalazku jest laminat magnez-szkło i sposób jego wytwarzania. Laminat magnez-szkło charakteryzuje się tym, że w części środkowej laminatu znajdują się cztery jednakowe warstwy samonaprawiające się (4) o grubości od 1,5 mm do 2,3 mm każda, składające się z włókien szklanych wypełnionych diizocyjanianem izoforonu i połączonych żywicą epoksydową. Do zewnętrznych powierzchni skrajnych warstw samonaprawiających się (4) przylega adhezyjnie warstwa żywicy polimerowej (3) o grubości od 10 µm do 30 µm, która nałożona jest na warstwę ceramiczną (2) o grubości od 8 µm do 15 µm znajdującą się na arkuszu blachy (1) ze stopu magnezu o grubości od 0,3 mm do 0,5 mm. Sposób wytwarzania laminatu magnez-szkło, polega na tym, że na dwa arkusze blachy (1) ze stopu magnezu o grubości od 0,3 mm do 0,5 mm posiadające na obu powierzchniach warstwę ceramiczną (2) o grubości od 8 µm do 15 µm nakłada się obustronnie warstwę żywicy polimerowej (3) o grubości od 10 µm do 30 µm, po czym pozostawia się na czas 3 h w temperaturze 23°C. Następnie na jeden z arkuszy blachy (1) ze stopu magnezu o grubości od 0,3 mm do 0,5 mm posiadający na obu powierzchniach warstwę ceramiczną (2) o grubości od 8 µm do 15 µm i warstwę żywicy polimerowej (3) o grubości od 10 µm do 30 µm nakłada się kolejno cztery jednakowe warstwy włókien szklanych wypełnionych diizocyjanianem izoforonu o grubości od 0,25 mm do 1 mm każda. Każdą warstwę włókien szklanych laminuje się ręcznie żywicą epoksydową i otrzymuje się cztery jednakowe warstwy samonaprawiające się (4) o grubości od 1,5 mm do 2,3 mm każda, składające się z włókien szklanych wypełnionych diizocyjanianem izoforonu i połączonych żywicą epoksydową.The subject of the invention is a magnesium-glass laminate and a method for its production. The magnesium-glass laminate is characterized by the fact that in the central part of the laminate there are four identical self-healing layers (4) with a thickness of 1.5 mm to 2.3 mm each, consisting of glass fibers filled with isophorone diisocyanate and joined with epoxy resin. A layer of polymer resin (3) with a thickness of 10 µm to 30 µm adheres adhesively to the outer surfaces of the extreme self-healing layers (4), which is applied to a ceramic layer (2) with a thickness of 8 µm to 15 µm on a sheet of metal ( 1) Magnesium alloy with a thickness of 0.3mm to 0.5mm. The method of producing the magnesium-glass laminate consists in the fact that two metal sheets (1) made of magnesium alloy with a thickness of 0.3 mm to 0.5 mm, having a ceramic layer (2) with a thickness of 8 µm to 15 µm, a layer of polymer resin (3) with a thickness of 10 µm to 30 µm is applied on both sides, and then left for 3 h at 23°C. Then onto one of the sheets (1) made of magnesium alloy with a thickness of 0.3 mm to 0.5 mm, having on both surfaces a ceramic layer (2) with a thickness of 8 µm to 15 µm and a layer of polymer resin (3) with a thickness of from 10 µm to 30 µm, four identical layers of glass fibers filled with isophorone diisocyanate with a thickness of 0.25 mm to 1 mm each are successively applied. Each layer of glass fibers is manually laminated with epoxy resin to obtain four identical self-healing layers (4) each 1.5 mm to 2.3 mm thick, consisting of glass fibers filled with isophorone diisocyanate and bonded with epoxy resin.

PL441555A 2022-06-27 2022-06-27 Magnesium-glass laminate and method of its production PL243793B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL441555A PL243793B1 (en) 2022-06-27 2022-06-27 Magnesium-glass laminate and method of its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL441555A PL243793B1 (en) 2022-06-27 2022-06-27 Magnesium-glass laminate and method of its production

Publications (2)

Publication Number Publication Date
PL441555A1 true PL441555A1 (en) 2022-12-05
PL243793B1 PL243793B1 (en) 2023-10-09

Family

ID=84426759

Family Applications (1)

Application Number Title Priority Date Filing Date
PL441555A PL243793B1 (en) 2022-06-27 2022-06-27 Magnesium-glass laminate and method of its production

Country Status (1)

Country Link
PL (1) PL243793B1 (en)

Also Published As

Publication number Publication date
PL243793B1 (en) 2023-10-09

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