PL441557A1 - Magnesium-glass laminate and method of its production - Google Patents

Magnesium-glass laminate and method of its production

Info

Publication number
PL441557A1
PL441557A1 PL441557A PL44155722A PL441557A1 PL 441557 A1 PL441557 A1 PL 441557A1 PL 441557 A PL441557 A PL 441557A PL 44155722 A PL44155722 A PL 44155722A PL 441557 A1 PL441557 A1 PL 441557A1
Authority
PL
Poland
Prior art keywords
thickness
magnesium
diethylenetriamine
weight
amount
Prior art date
Application number
PL441557A
Other languages
Polish (pl)
Other versions
PL243177B1 (en
Inventor
Monika Ostapiuk
Jarosław Bieniaś
Patryk Jakubczak
Magda Droździel-Jurkiewicz
Piotr Podolak
Original Assignee
Politechnika Lubelska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Politechnika Lubelska filed Critical Politechnika Lubelska
Priority to PL441557A priority Critical patent/PL243177B1/en
Publication of PL441557A1 publication Critical patent/PL441557A1/en
Publication of PL243177B1 publication Critical patent/PL243177B1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/092Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising epoxy resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/14Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/02Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B18/00Layered products essentially comprising ceramics, e.g. refractory products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/12Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/10Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/02Coating on the layer surface on fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • B32B2260/023Two or more layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/762Self-repairing, self-healing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249924Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994Fiber embedded in or on the surface of a polymeric matrix

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)

Abstract

Przedmiotem zgłoszenia jest laminat magnez-szkło i sposób jego wytwarzania. Laminat magnez-szkło, charakteryzuje się tym, że w części środkowej laminatu znajdują się cztery jednakowe warstwy samonaprawiające się (4) o grubości od 1,5 mm do 2,3 mm każda, składające się z włókien szklanych wypełnionych roztworem dietylenotriaminy składającym się z wody w ilości 10% wagowo i dietylenotriaminy w ilości 90% wagowo i połączonych żywicą epoksydową. Do zewnętrznych powierzchni skrajnych warstw samonaprawiających się (4) przylega adhezyjnie warstwa żywicy polimerowej (3) o grubości od 10 µm do 30 µm, która nałożona jest na warstwę ceramiczną (2) o grubości od 8 µm do 15 µm znajdującą się na arkuszu blachy (1) ze stopu magnezu o grubości od 0,3 mm do 0,5 mm. Sposób wytwarzania laminatu magnez-szkło, polega na tym, że na dwa arkusze blachy (1) ze stopu magnezu o grubości od 0,3 mm do 0,5 mm posiadające na obu powierzchniach warstwę ceramiczną (2) o grubości od 8 µm do 15 µm nakłada się obustronnie warstwę żywicy polimerowej (3) o grubości od 10 µm do 30 µm, po czym pozostawia się na czas 3 h w temperaturze 23°C. Następnie na jeden z arkuszy blachy (1) ze stopu magnezu o grubości od 0,3 mm do 0,5 mm posiadający na obu powierzchniach warstwę ceramiczną (2) o grubości od 8 µm do 15 µm i warstwę żywicy polimerowej (3) o grubości od 10 µm do 30 µm nakłada się kolejno cztery jednakowe warstwy włókien szklanych wypełnionych roztworem dietylenotriaminy składającym się z wody w ilości 10% wagowo i dietylenotriaminy w ilości 90% wagowo o grubości od 0,25 mm do 1 mm każda.The subject of the application is a magnesium-glass laminate and a method for its manufacture. Magnesium-glass laminate, characterized by the fact that in the central part of the laminate there are four identical self-healing layers (4) with a thickness of 1.5 mm to 2.3 mm each, consisting of glass fibers filled with a solution of diethylenetriamine consisting of water in an amount of 10% by weight and diethylenetriamine in an amount of 90% by weight and combined with an epoxy resin. A layer of polymer resin (3) with a thickness of 10 µm to 30 µm adheres adhesively to the outer surfaces of the extreme self-healing layers (4), which is applied to a ceramic layer (2) with a thickness of 8 µm to 15 µm on a sheet of metal ( 1) Magnesium alloy with a thickness of 0.3mm to 0.5mm. The method of manufacturing the magnesium-glass laminate consists in the fact that two metal sheets (1) made of magnesium alloy with a thickness of 0.3 mm to 0.5 mm, having on both surfaces a ceramic layer (2) with a thickness of 8 µm to 15 µm, a layer of polymer resin (3) with a thickness of 10 µm to 30 µm is applied on both sides, and then left for 3 h at 23°C. Then onto one of the sheets (1) made of magnesium alloy with a thickness of 0.3 mm to 0.5 mm, having on both surfaces a ceramic layer (2) with a thickness of 8 µm to 15 µm and a layer of polymer resin (3) with a thickness of from 10 µm to 30 µm, four identical layers of glass fibers filled with a solution of diethylenetriamine consisting of water in the amount of 10% by weight and diethylenetriamine in the amount of 90% by weight are successively applied, with a thickness of 0.25 mm to 1 mm each.

PL441557A 2022-06-27 2022-06-27 Magnesium-glass laminate and method of its production PL243177B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL441557A PL243177B1 (en) 2022-06-27 2022-06-27 Magnesium-glass laminate and method of its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL441557A PL243177B1 (en) 2022-06-27 2022-06-27 Magnesium-glass laminate and method of its production

Publications (2)

Publication Number Publication Date
PL441557A1 true PL441557A1 (en) 2023-01-02
PL243177B1 PL243177B1 (en) 2023-07-10

Family

ID=84786793

Family Applications (1)

Application Number Title Priority Date Filing Date
PL441557A PL243177B1 (en) 2022-06-27 2022-06-27 Magnesium-glass laminate and method of its production

Country Status (1)

Country Link
PL (1) PL243177B1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL447530A1 (en) * 2024-01-17 2024-08-12 Politechnika Lubelska Metal-carbon laminate and its producing method
PL447528A1 (en) * 2024-01-17 2024-08-12 Politechnika Lubelska Metal-carbon laminate and its producing method
PL447526A1 (en) * 2024-01-17 2024-08-12 Politechnika Lubelska Metal-glass-carbon laminate and its producing method
PL447524A1 (en) * 2024-01-17 2024-07-29 Politechnika Lubelska Metal-glass laminate and method of producing it
PL447522A1 (en) * 2024-01-17 2024-07-29 Politechnika Lubelska Metal-glass laminate and method of producing it
PL447523A1 (en) * 2024-01-17 2024-07-29 Politechnika Lubelska Metal-glass laminate and method of producing it
PL447529A1 (en) * 2024-01-17 2024-08-12 Politechnika Lubelska Metal-carbon laminate and its producing method
PL447527A1 (en) * 2024-01-17 2024-08-12 Politechnika Lubelska Metal-carbon laminate and its producing method
PL447525A1 (en) * 2024-01-17 2024-07-29 Politechnika Lubelska Metal-glass laminate and method of producing it
PL447531A1 (en) * 2024-01-17 2024-08-12 Politechnika Lubelska Metal-carbon-glass laminate and its producing method

Also Published As

Publication number Publication date
PL243177B1 (en) 2023-07-10

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