PL414534A1 - Methylene bis (4,1-cyclohexane-diyl-nitril-dimethylene) tetrakis-phosphinic acid and its 2-methyl derivative, and method for producing them - Google Patents
Methylene bis (4,1-cyclohexane-diyl-nitril-dimethylene) tetrakis-phosphinic acid and its 2-methyl derivative, and method for producing themInfo
- Publication number
- PL414534A1 PL414534A1 PL414534A PL41453415A PL414534A1 PL 414534 A1 PL414534 A1 PL 414534A1 PL 414534 A PL414534 A PL 414534A PL 41453415 A PL41453415 A PL 41453415A PL 414534 A1 PL414534 A1 PL 414534A1
- Authority
- PL
- Poland
- Prior art keywords
- methylene bis
- acid
- methyl derivative
- dimethylene
- tetrakisphosphinic
- Prior art date
Links
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 title abstract 7
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 6
- 239000002253 acid Substances 0.000 abstract 4
- GXGJIOMUZAGVEH-UHFFFAOYSA-N Chamazulene Chemical group CCC1=CC=C(C)C2=CC=C(C)C2=C1 GXGJIOMUZAGVEH-UHFFFAOYSA-N 0.000 abstract 3
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- -1 dimethyldimethylene Chemical group 0.000 abstract 1
- GOJNABIZVJCYFL-UHFFFAOYSA-N dimethylphosphinic acid Chemical compound CP(C)(O)=O GOJNABIZVJCYFL-UHFFFAOYSA-N 0.000 abstract 1
- 239000012634 fragment Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229920002866 paraformaldehyde Polymers 0.000 abstract 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Wynalazek dotyczy kwasu metylenobis(4,1-cykloheksanodiylnitrilodimetyleno)tetrakisfosfinowego i jego 2-metylo pochodnej, przedstawionych wzorem ogólnym 1, w którym R oznacza atom wodoru lub grupę metylową. Kwas metylenobis(4,1-cykloheksanodiylnitrilodimetyleno)tetrakisfosfinowy i jego 2-metylo pochodna, są przeznaczone do stosowania jako substraty do syntez, zwłaszcza kwasu metylenobis(4,1-cykloheksanodiylnitrilodimetyleno)tetrakisfosfinowego i jego 2-metylo pochodnej, a także poliamfolitów zawierających fragmenty strukturalne metylenobis(4,1-cykloheksanoaminy) i kwasu dimetylofosfinowego. Ujawniono również sposób wytwarzania kwasu metylenobis(4,1-cykloheksanodiylnitrilodimetyleno)tetrakisfosfinowego i jego 2-metylo pochodnej, który polega na tym, że metylenobis(4,1-cykloheksanoaminę) (lub jej 2-metylo pochodną) poddaje się reakcji z co najmniej czterema częściami molowymi kwasu fosfinowego i co najmniej czterema częściami molowymi formaldehydu, zawartego w substancji wybranej z grupy formalina, trioksan, paraform, a reakcję prowadzi się w temperaturze poniżej 300 K, w wodzie, aż do przereagowania substratów i utworzenia się produktu.The invention relates to methylene bis (4,1-cyclohexanediylnitrile dimethylene) tetrakisphosphinic acid and its 2-methyl derivative represented by general formula 1, wherein R is a hydrogen atom or a methyl group. Methylene bis (4,1-cyclohexanediylnitrile dimethylene) tetrakisphosphinic acid and its 2-methyl derivative are intended to be used as synthesis substrates, in particular methylene bis (4,1-cyclohexanediylnitrile dimethyldimethylene) tetrakisphosphinic acid and its 2-methyl derivative, as well as polyamidolite fragments methylene bis (4,1-cyclohexanamine) and dimethylphosphinic acid. Also disclosed is a method for producing methylenebis (4,1-cyclohexanediylnitrile dimethylene) tetrakisphosphinic acid and its 2-methyl derivative, wherein the methylene bis (4,1-cyclohexanamine) (or its 2-methyl derivative) is reacted with at least four mole parts of phosphinic acid and at least four mole parts of formaldehyde contained in a substance selected from the group selected from formalin, trioxane, paraform, and the reaction is carried out at a temperature below 300 K in water until the reactants react and the product forms.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL414534A PL228889B1 (en) | 2015-10-28 | 2015-10-28 | Methylene bis (4,1-cyclohexane-diyl-nitril-dimethylene) tetrakis-phosphinic acid and its 2-methyl derivative, and method for producing them |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL414534A PL228889B1 (en) | 2015-10-28 | 2015-10-28 | Methylene bis (4,1-cyclohexane-diyl-nitril-dimethylene) tetrakis-phosphinic acid and its 2-methyl derivative, and method for producing them |
Publications (2)
Publication Number | Publication Date |
---|---|
PL414534A1 true PL414534A1 (en) | 2016-12-05 |
PL228889B1 PL228889B1 (en) | 2018-05-30 |
Family
ID=57405902
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PL414534A PL228889B1 (en) | 2015-10-28 | 2015-10-28 | Methylene bis (4,1-cyclohexane-diyl-nitril-dimethylene) tetrakis-phosphinic acid and its 2-methyl derivative, and method for producing them |
Country Status (1)
Country | Link |
---|---|
PL (1) | PL228889B1 (en) |
-
2015
- 2015-10-28 PL PL414534A patent/PL228889B1/en unknown
Also Published As
Publication number | Publication date |
---|---|
PL228889B1 (en) | 2018-05-30 |
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