PL400713A1 - Tebuconazole salts and processes for their preparation - Google Patents
Tebuconazole salts and processes for their preparationInfo
- Publication number
- PL400713A1 PL400713A1 PL400713A PL40071312A PL400713A1 PL 400713 A1 PL400713 A1 PL 400713A1 PL 400713 A PL400713 A PL 400713A PL 40071312 A PL40071312 A PL 40071312A PL 400713 A1 PL400713 A1 PL 400713A1
- Authority
- PL
- Poland
- Prior art keywords
- tebuconazole
- preparation
- salts
- solvent
- allyl
- Prior art date
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Przedmiotem wynalazku sa sole tebukonazolu majace zastosowanie jako zwiazki grzybobójcze oraz sposób ich wytwarzania. Czwartorzedowe sole tebukonazolu sa to zwiazki o wzorze ogólnym 1, w których X oznacza anion chlorkowy, jodkowy lub bromkowy, a R oznacza prostolancuchowy podstawnik alkilowy zawierajacy od 1 do 20 atomów wegla, lub podstawnik benzylowy lub allilowy lub cykloheksylowy. Sposób ich wytwarzania polega na tym, ze tebukonazol poddaje sie reakcji z czynnikiem czwartorzedu o wzorze ogólnym R-X, w którym R oznacza prostolancuchowy podstawnik alkilowy zawierajacy od 1 do 20 atomów wegla, lub podstawnik benzylowy lub allilowy lub cykloheksylowy, a X oznacza atom chloru lub bromu lub jodu, przy stosunku molowym tebukonazolu do czynnika czwartorzedujacego wynoszacym od 1:1 do 1:3 w rozpuszczalniku organicznym I, w temperaturze od 273 do 363K, w czasie co najmniej 20 godzin, po czym odparowuje sie rozpuszczalnik, a mieszanine poreakcyjna przemywa sie rozpuszczalnikiem organicznym II w celu usuniecia nieprzereagowanych substratów, a nastepnie produkt suszy sie pod zmniejszonym cisnieniem w temperaturze od 313 do 363K, przez co najmniej 8 godzin.The present invention relates to tebuconazole salts having use as fungicidal compounds and to a method for their preparation. The quaternary salts of tebuconazole are compounds of the general formula 1 in which X is a chloride, iodide or bromide anion, and R is a straight chain alkyl substituent containing from 1 to 20 carbon atoms, or a benzyl or allyl or cyclohexyl substituent. The method of their preparation is that tebuconazole is reacted with a quaternary agent of the general formula RX, in which R is a straight chain alkyl substituent containing from 1 to 20 carbon atoms, or a benzyl or allyl or cyclohexyl substituent, and X is a chlorine or bromine atom or iodine, with a molar ratio of tebuconazole to quaternizing agent of 1: 1 to 1: 3 in organic solvent I, at a temperature of 273 to 363K, for at least 20 hours, after which the solvent is evaporated and the reaction mixture is washed with solvent organic II to remove unreacted substrates, and then the product is dried under reduced pressure at a temperature of 313 to 363K for at least 8 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL400713A PL220854B1 (en) | 2012-09-10 | 2012-09-10 | Tebuconazole salts and processes for their preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL400713A PL220854B1 (en) | 2012-09-10 | 2012-09-10 | Tebuconazole salts and processes for their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL400713A1 true PL400713A1 (en) | 2014-03-17 |
| PL220854B1 PL220854B1 (en) | 2016-01-29 |
Family
ID=50240925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL400713A PL220854B1 (en) | 2012-09-10 | 2012-09-10 | Tebuconazole salts and processes for their preparation |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL220854B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL422979A1 (en) * | 2017-09-26 | 2019-04-08 | Instytut Ochrony Roślin - Państwowy Instytut Badawczy W Poznaniu | N-benzyltriticonazole salts, method for obtaining them and application as fungicides |
-
2012
- 2012-09-10 PL PL400713A patent/PL220854B1/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL422979A1 (en) * | 2017-09-26 | 2019-04-08 | Instytut Ochrony Roślin - Państwowy Instytut Badawczy W Poznaniu | N-benzyltriticonazole salts, method for obtaining them and application as fungicides |
Also Published As
| Publication number | Publication date |
|---|---|
| PL220854B1 (en) | 2016-01-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MY164776A (en) | Heterocyclic compound | |
| MY160785A (en) | Manufacturing process for pyrimidine derivatives | |
| MX2014015661A (en) | Fungicidal 4-methylanilino pyrazoles. | |
| MX2017017022A (en) | Method for the synthesis of rapamycin derivatives. | |
| MX2013007462A (en) | Process for preparing 3-alkylsulfinylbenzoyl derivatives. | |
| PL400713A1 (en) | Tebuconazole salts and processes for their preparation | |
| PL400714A1 (en) | Propiconazole salts and processes for their preparation | |
| PL431315A1 (en) | Alkyl(2-hydroxyethyl)dimethylammonium indole-3-butyrates, method of their preparation and use as rooting hormones | |
| UA114911C2 (en) | Arylethynyl derivatives | |
| Zhuravlev et al. | Effect of structure of nucleophile and substrate on the quaternization of heterocyclic amines | |
| PL400413A1 (en) | Methyl-imidazolium ionic liquids with the theophylline anion and a method for their preparation | |
| WO2012073038A3 (en) | Process comprising the reaction of cyclobutenone with alkynyl boronic acid or derivative thereof in the presence of transition metal olefin complex catalyst | |
| PL400411A1 (en) | Methyl Cyclohexyl ammonium ionic liquids with the theophylline anion and a method for their preparation | |
| PL400412A1 (en) | 1-methylpiperidinium ionic liquids with the theophylline anion and a method for their preparation | |
| PL398562A1 (en) | Tetraalkylammonium cyclamates and their preparation | |
| PL419451A1 (en) | Quaternary halides, containing a diphenoconasol cation, method for obtaining them and application as fungicides | |
| PL413493A1 (en) | Quaternary salts of diphenoconazol with inorganic anion, method for obtaining them and application as fungicides | |
| PL403782A1 (en) | Alkylcyclohexyldimethylammonium 4-chloro-2-methylphenoxyacetates and a method for their preparation | |
| PL411286A1 (en) | New alkoxymethyl di(2-hydroxyethyl)ethylammonium ionic liquids with sweet anions and method for producing them and application as a medium for the protection of surface against accumulation of electrostatic charges | |
| PL435466A1 (en) | New ionic liquids with alkyl (carboxymethyl) dimethylammonium cation and 1,4-bis (2-ethylhexoxy) -1,4-dioxobutane-2-sulfonate anion, method of preparation and use as degreasing agents for work surfaces | |
| WO2014153337A3 (en) | Small molecule inhibitors of pi3-kinase signaling | |
| PL406945A1 (en) | Alkoxymethyl cyclohexylo dimethylammonium 4-chloro-2-methylphenoxy acetates and method for obtaining them | |
| PL418890A1 (en) | Alkyl[2-(2-hydroxyethoxy)ethyl]dimethylammonium 3,6-dichloro-2-methoxybenzoates, method for obtaining them and application as herbicides | |
| PL213394B1 (en) | New ionic liquids, method for their production and use thereof | |
| PL410319A1 (en) | New quaternary alkoxymethyl tebuconazole chlorides, method for producing them and their application as growth inhibitors of mycelium |