PL26420B1 - - Google Patents
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- Publication number
- PL26420B1 PL26420B1 PL26420A PL2642036A PL26420B1 PL 26420 B1 PL26420 B1 PL 26420B1 PL 26420 A PL26420 A PL 26420A PL 2642036 A PL2642036 A PL 2642036A PL 26420 B1 PL26420 B1 PL 26420B1
- Authority
- PL
- Poland
- Prior art keywords
- gases
- chloride
- volatile substances
- vapors
- salts
- Prior art date
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- 239000007789 gas Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 231100000614 poison Toxicity 0.000 claims 1
- 230000007096 poisonous effect Effects 0.000 claims 1
- 239000000126 substance Substances 0.000 description 8
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 208000031872 Body Remains Diseases 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 2
- 235000013379 molasses Nutrition 0.000 description 2
- 150000007530 organic bases Chemical class 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 206010035148 Plague Diseases 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Description
Wiadomo, ze przy przeróbce fabrycznej materialów organicznych, zawierajacych ciala bialkowe, na przyklad przy spalaniu wywarów melasowych lub ich destylacji, przy zweglaniu krwi i szczatków zwierze¬ cych, na ogól przy kazdej przeróbce w pod¬ wyzszonej temperaturze, ciala te wydzie¬ laja substancje lotne, znajdujace sie w nich, a czesciowo ubocznie nowoutworzone, które uchodzac z komina zanieczyszczaja powie¬ trze i staja sie plaga okolic, w których wy¬ konywana jest taka przeróbka fabryczna.Próbowano w najrozmaitszy sposób uwolnic opary i gazy uchodzace przy wspomnianych fabrykacjach od tych bardzo szkodliwych substancji lotnych. Próbowano zatrzymy¬ wac znajdujace sie w gazach zasady or¬ ganiczne za pomoca kwasów lub usuwac won gazów przez utlenianie itd. W prakty¬ ce wszystkie te sposoby nie daja pozada¬ nych rezultatów.Obecnie -stwierdzono, ze uciazliwe dla otoczenia substancje lotne daja sie w znacz¬ nej czesci usunac w sposób prosty, a miano¬ wicie przez zwilzanie (przez zraszanie) wo¬ da oraz chlodzenie uchodzacych przy prze¬ róbce gazów i par roztworami wodnymi albo zawiesinami soli lub tlenków higro- skopijnych, na przyklad roztworem chlorku magnezu, chlorku wapnia wzglednie mle¬ kiem wapiennym lub roztworami niektó¬ rych soli glinu wzglednie zelaza. W takichwarunkach substancje lotne oparów zostaja zatrzymane w roztworze wodnym wzgled¬ nie okluldowane w zawiesinaich.Sposób niniejszy pozwala nie tylko na uwolnienie otoczenia od szkodliwych wy¬ ziewów, ale moze byc nadto zastosowany w celu otrzymywania substancji, które znaj¬ duja sie w oparach i gazach spalinowych.Substancje te moga byc wydzielane z roz¬ tworów przez stosowanie odczynników wia¬ zacych zasady organiczne, które znajduja sie w gazach spalinowych w postaci amin.Do roztworów stosowanych do plukania mozna równiez dodawac substancji wiaza¬ cych cyjan, na przyklad soli cynku, glinu, zelaza i metali ciezkich wzglednie ich tlen¬ ków. Substancje lotne mozna wreszcie o- trzymac przez oddestylowanie roiztworów.Przyklad I. Szczatki zwierzece, jak wysuszona krew i inne odpadki ciala zwie¬ rzecego, poddaje sie suchej destylacji w kolbie z trudno topliwego szkla, a powsta¬ jace opary skrapla sie przeprowadzajac je przez chlodnice. W celu zatrzymania nie- skroplonych substancji lotnych o przykrym zapachu gazy nieskroplone przepuszcza sie przez pluczki z roztworem chlorku wapnia.Tworzaca sie przy tym zawiesina wodoro¬ tlenku wapniowego' wzmaga wydatnie za¬ trzymywanie sie woniejacych gazów. Za¬ miast chlorku wapnia uzyc mozna chlorku magnezu, chlorków zelaza wzglednie mleka wapiennego.Przyklad II. Wywar melasowy o ste¬ zeniu okolo 15° Be po zageszczeniu spala sie w piecu w celu otrzymania potazu. U- chodzace gazy spalinowe przeprowadza sie przez komore, chlodzona zimna woda, prze¬ chodzaca przez wezownice wzglednie inny zespól rur umieszczonych w komorze. Jed¬ noczesnie zrasza sie chlodzone gazy na przyklad przez rozpylanie strumienia wody w przeciwpradzie, co powoduje zatrzymy¬ wanie sie gazów w umieszczonych w dal¬ szym ciagu pluczkach z roztworem chlorku wapnia, chlorku magnezu wzglednie chlor¬ ków zelaza, PLIt is known that during the factory processing of organic materials containing protein bodies, for example, the burning of molasses decoctions or their distillation, the carbonization of blood and animal remains, and, in general, each processing at elevated temperatures, these bodies release volatile substances. in them, and partly by-products, which when escaping from the chimney pollute the air and become a plague in the areas where such factory processing is carried out. Attempts have been made in various ways to free the fumes and gases escaping from the above-mentioned fabrications from those very harmful volatile substances. Attempts have been made to capture the organic bases in the gases with acids, or to remove the odor of gases by oxidation, etc. In practice, all these methods do not give the desired results. It has now been found that volatile substances that are harmful to the environment are to remove a significant part in a simple manner, for example by moistening (by sprinkling) water and cooling the gases and vapors escaping during processing with aqueous solutions or suspensions of hygroscopic salts or oxides, for example with a solution of magnesium chloride, chloride calcium or calcium milk or solutions of certain aluminum salts or iron. Under these conditions, the volatile substances of the vapors are retained in an aqueous solution or suspended in a suspension. The present method not only frees the environment from harmful vapors, but can also be used to obtain substances that are present in the vapors and gases. These substances can be separated from the solutions by the use of reagents that bind organic bases which are found in the flue gas in the form of amines. Cyan binders can also be added to the scrubbing solutions, for example zinc salts, aluminum , iron and heavy metals or their oxides. Volatile substances can finally be captured by distilling the solutions. Example I. Animal remains, such as dried blood and other animal debris, are subjected to dry distillation in a flame-retardant glass flask, and the resulting vapors condense by passing them through coolers . In order to retain non-condensable volatile substances with an unpleasant odor, non-condensable gases are passed through the scrubbers with a calcium chloride solution. The calcium hydroxide suspension thus formed increases the entrapment of the odorous gases considerably. Instead of calcium chloride, you can use magnesium chloride, iron chloride or milk of lime. Example II. The molasses decoction, at a concentration of about 15 ° B, is burnt in a furnace after it is concentrated to obtain the potassium. The incoming flue gas is led through the chamber, and cooled cold water is passed through coils or another set of pipes placed in the chamber. At the same time, the cooled gases are sprayed, for example by spraying a stream of water in a countercurrent, which causes the gases to be trapped in the downstream rinses with a solution of calcium chloride, magnesium chloride or iron chloride, PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL26420B1 true PL26420B1 (en) | 1938-04-30 |
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