PL2247B1 - The method of obtaining viscose. - Google Patents

The method of obtaining viscose. Download PDF

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Publication number
PL2247B1
PL2247B1 PL2247A PL224724A PL2247B1 PL 2247 B1 PL2247 B1 PL 2247B1 PL 2247 A PL2247 A PL 2247A PL 224724 A PL224724 A PL 224724A PL 2247 B1 PL2247 B1 PL 2247B1
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PL
Poland
Prior art keywords
xanthate
viscose
dissolved
carbon sulphide
obtaining viscose
Prior art date
Application number
PL2247A
Other languages
Polish (pl)
Filing date
Publication date
Application filed filed Critical
Publication of PL2247B1 publication Critical patent/PL2247B1/en

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Description

Przy przygotowywaniu wiskozy zosta¬ je uprzednie wytworzenie ksantatu wyko¬ nywane zwykle w ten sposób, ze w bebnie, w którym odbywa sie siarczkowanie, zo^ staje blonnik wysycony siarczkiem wegla, a nastepnie nadmiar siarczku wegla i lot¬ nych zwiazków jego odsysany z bebna, po- czem otrzymany ksantat w specjalnem lekkiem mieszadle rozpuszcza sie, przez dodanie rozrzedzonego lugu, na wiskoze o pozadanem zgeszczeniu. Doswiadczenie pokazalo, ze w ksantacie, który opuszcza beben w ksztalcie mniejszych lub wiekszych kawalków, znajduja sie w tych kawalkach stale obok przesyconych czastek blonnika równiez i takie czastki, które sa niedosta¬ tecznie nasyconle siarczkiem wegla. Te o- statnie, po usunieciu nadmiaru siarczku wegla, przy nastepujacym procesie rozpu¬ szczania, pozostaja nierozpuszczone i wy¬ wieraja na proces filtrowania, nastepujacy po rozpuszczeniu, bardzo szkodliwe dzia¬ lanie z powodu zatykania filtra. Z drugiej strony czastki blonnika, znajdlijace sie we wnetrzu wspomnianych kawalków ksanta¬ tu, posiadajace nadmiar siarczku wegla, oddaja go przy procesie rozpuszczania roz¬ tworowi wiskozy, co równiez jest bardzo niepozadane.Niniejszy sposób usuwa powyzsze wa¬ dy przez to, ze ksantat, przed usunieciem nadmiaru siarczku wegla, zostaje rozpu¬ szczony przy stalem energlcznem ugnia¬ taniu w odpowiedniej ugniatarce rozwod¬ nionym lugiem. Przy wytwarzajacej sie przytem ciagliwej, kitowatej masie, nad-miar siarczku wegla, wystepujacy w od¬ dzielnych czastkach blonnika, moze prze¬ chodzic do nienasyconych calkowicie cza¬ stek blonnika i doprowadzac je do zupel¬ nego rozpuszczenia i w ten sposób caly materjal moze byc rozpuszczony.Dopiero po dluzszem ugniataniu i osia¬ gnieciu odpowiedniego stopnia rozrzedze¬ nia zostaje pozostala reszta wolnego siarcz¬ ku wegla i lotnych zwiazków odessana przy ciaglem poruszaniu z otrzymanej wi¬ skozy i w ten sposób zostaje otrzymany roztwór wiskozy, prawie calkowicie wolnej od nierozpuszczonego blonnika i od nie- zwiazanego siarczku wegla.Do wykonania sposobu wskazane jest uzywanie odpowiednio silnego odsysania w prózni zapomoca ugniatarki, w której moze byc wykonany proces siarczkowania, rozpuszczania i odsysania. PLIn the preparation of viscose, xanthate is first produced in such a way that in the drum in which the sulphidation takes place, the fiber is saturated with carbon sulphide, and then the excess carbon sulphide and its volatile compounds are sucked off the drum, Then the obtained xanthate is dissolved in a special, light stirrer, by adding the thinned lye, to the viscose of the desired pressing. Experience has shown that in the xanthate that leaves the drum in the shape of smaller or larger pieces, in these pieces there are constantly, next to the supersaturated fiber particles, also those particles which are insufficiently saturated with carbon sulfide. These last, after removing excess carbon sulphide, remain undissolved in the following dissolution process and have a very detrimental effect on the filtration process following dissolution due to clogging of the filter. On the other hand, fiber particles inside said pieces of xanthate, which have an excess of carbon sulphide, give it up in the dissolving process to the viscose solution, which is also very undesirable. This method removes the above disadvantages by the fact that xanthate, before the excess carbon sulphide is removed, it is dissolved with high-carbon steel, kneaded in a suitable kneader with diluted lug. In the case of a coarse, putty mass produced by this, the excess carbon sulphide present in the separate fiber particles can pass into the completely unsaturated fiber particles and bring them to complete dissolution and thus all material can be dissolved Only after a longer kneading and reaching the appropriate degree of thinning, the remaining free carbon sulphide and volatile compounds are sucked out of the obtained tackifier with continuous agitation, and thus a viscose solution is obtained, almost completely free from undissolved fiber and from It is advisable to use a sufficiently strong suction in a vacuum with a kneader, in which the sulphiding, dissolving and suction process can be performed. PL

Claims (2)

Zastrzezenia patentowe. 1. Sposób otrzymywania wiskozy, zna¬ mienny tern, ze po wytworzeniu ksantatu pozostajacy w nim nadmiar siarczku we¬ gla zostaje usuniety (odessany) dopiero przy rozpuszczaniu ksantatu, albo po jego rozpuszczeniu zupelnem.Patent claims. 1. The method of obtaining viscose, the significant point is that after the production of xanthate, the excess carbon sulphide remaining in it is removed (sucked off) only when the xanthate is dissolved or when it is completely dissolved. 2. Sposób podlug zastrz. 1, znamienny tern, ze calkowity przebieg siarczkowania, rozpuszczania i odsysania zostaje przed¬ siewziety w jednej maszynie, Fritz Kempter. Zastepca: M. Brokman rzecznik patentowy. Druk L. Boguslawskiego, Warszawa. PL2. The method of claim The method of claim 1, characterized in that the entire course of sulphation, dissolution and suction is screened in one machine by Fritz Kempter. Deputy: M. Brokman, patent attorney. Print by L. Boguslawski, Warsaw. PL
PL2247A 1924-08-08 The method of obtaining viscose. PL2247B1 (en)

Publications (1)

Publication Number Publication Date
PL2247B1 true PL2247B1 (en) 1925-07-31

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